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Possible mechanisms for the HppE-catalysed epoxidation of ( S )- 2-HPP (4) involving C1 cation formation (route a, red arrow) or oxygenatom rebound (route b, blue arrows). W Chang et al. Nature 496 , 114-118 (2013) doi:10.1038/nature11998.
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Possible mechanisms for the HppE-catalysed epoxidation of (S)- 2-HPP (4) involving C1 cation formation (route a, red arrow) or oxygenatom rebound (route b, blue arrows). W Chang et al. Nature 496, 114-118 (2013) doi:10.1038/nature11998