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Application of Materials. Part II, Engineering materials. Structural strength. Strenth of Materials. Stiffness. Reliability. Lifetime. Strength of materials. Properties determined at tensile/compression tests. Permanent elongation. Total elongation. Criteria for materials selection.
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Application of Materials Part II, Engineering materials
Structural strength Strenth of Materials Stiffness Reliability Lifetime
Strength of materials Properties determined at tensile/compression tests Permanent elongation Total elongation
Criteria for materials selection • plastic materials – yield strength (yield limit) – Re, Rp (Rec, Rpc) • brittle materials – strength limit – Rm (Rmc), Rm/ Classification of materials (Re, Rp0,2) • low strength < 250 N/mm2 • medium strength 250...750 N/mm2 • high strength 750...1500 N/mm2 • super high strength > 1500 N/mm2
Stiffness Stiffness D = Ex K(geometric characteristic of cross-section) At tension K = S (cross-section area) At bending K = I (moment of inertia) I = bh3/3 Modulus of elasticity Normal Shear Volume
Reliability (1) Toughness – notch impact energy KU or KV, J – fracture toughness KC, N/mm2 m1/2 Ductile fracture % TDBT T’DBT TDBT T KU, KV – cold brittleness TDBT – ductile-to-brittle transition
Reliability (2) Influence of C, ordinary and alloying elements to KU TDBT TDBT TDBT el steel normal cold worked cold worked TDBTC TDBTC
Reliability (3) Ductile-to-brittle transition T50, C % of alloying elements
Reliability (4) Dependence of M toughness of A-grain size KU, J Dependence of KU/KV on temperature low strength KU, KV high strength Grain no. T
Fine and coarse grain steels 1 – killed steel 2 – rimmed steel
Influence of microalloying elements V Grain size of ferrite, m2 Ti Nb Alloying elements, %
Plane strain fracture toughness K1c At tension K1c Coefficient of stress intensity [MPam1/2]
Low-alloyed highly tempered steels Relationship between K1c and yield strength Superplastic steels Fracture toughness K1c, MPa m1/2 Maraging steels Precipitation hardened stainless steels Yield strength, MPa
Life time (1) R (R = min/max) -1 – symmetric loading Fatigue Impactors: - surface roughness - stress state - stress concentrations Steels N = 107 Nonferrous alloys N = 108
Life time (3) Creep = f(, T, t) • low temperature T/Tm < 0.5 • high temperature T/Tm > 0.5 Impactors • structure • alloying (super creep alloys) – • TMT
Corrosion Modes of corrosion in dry gases in organic liquids Chemical in water containing environments in melt electrolytes Electrochemical Biochemical
Types of corrosion Types of corrosion: a – uniform b – nonuniform c – selective d – spotted e – pitting f – dotted g – under surface h – intercrystal i - stress
Chemical corrosion of metals (1) 2 Mg + O2 = 2 MgO 2 Fe + 3 O2 = Fe2O3 For protection Voxide > Vmetal Kui Voxide/Vmetal> 1 – Cd, Al, Ti, Zr, Zn, Ni, Cr, Fe At high Voks / Vmet (1,2…2,0) cracking High temperature corrosion T 1000 C – oxide layer electroconductive
Chemical corrosion of metals (2) Corrosion influencing parameters • structure • surface treatment materials parameters • internal stresses • T • gas composition • velocity environmental parameters • heating parameters
Chemical corrosion of metals (3) Protection • alloying ( ) • coatings • protective atmosphere (at heat treatment) (H2 + N2 + H2O; CO + CO2 + N2; etc.)
Electrochemical corrosion of metals (1) Moisture + H2S, Co2, So2, NaCl electrolyte metals galvanic pair
Electrochemical corrosion of metals (2) Microgalvanic pairs at steels Atmosphere Moisture film Metal
Electrochemical corrosion of metals (3) Protection (1) • Selection of materials Table: Allowed contacts of metals
Protection (2) • Protective coatings - metallic (less active metals (Cu, Ni, Sn, Ag) – up to coating must be undamage; active (Zn, Co) – protection up to end) - paints, lubricants • other - cathodic protection - protector protection - anodic protection - corrosion inhibitors (high molecular matters)
Wear Modes of wear Mechanical Corrosive-mechanical Adhesive -abrasion -oxidizing wear -erosion -fretting corrosive wear -cavitation -fatigue wear
Method for wear protection • hardening, thermo-chemical treatment • overwelding • surface alloying • coating (chemical, thermo-chemical, thermally sprayed, PVD, CVD, mechanical) • selection of pairs (by adhesion)
Material groups Metals Cermets MCM Ceramics CCM Glass-ceramics Composites GCCM PCM FRG Polymers Glass MCM Metal composite materials CCM Ceramic composite material PCM Polymeric composite material GCCM Glass-ceramic composite material FRG Fiber-reinforced glass
Basic physical and mechanical properties of construction materials (1)
Basic physical and mechanical properties of construction materials (2)
Thank you for attention priit.kulu@ttu.ee