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Intermolecular Forces of Organic Molecules

Intermolecular Forces of Organic Molecules. Dr. C. Yau Spring 2014. 1. 1. Review of Organic Molecules. What are considered “organic compounds?” They are compounds containing C. What are hydrocarbons? They are compounds containing only C & H.

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Intermolecular Forces of Organic Molecules

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  1. Intermolecular Forcesof Organic Molecules Dr. C. Yau Spring 2014 1 1

  2. Review of Organic Molecules What are considered “organic compounds?” They are compounds containing C. What are hydrocarbons? They are compounds containing only C & H. In a previous lecture we talked about several of the classes of organic compounds: • hydrocarbons • alcohols • carboxylic acids • amines It would be wise to review what distinguish these classes of compounds from each other.

  3. Intermolecular Forces of Hydrocarbons Hydrocarbons are nonpolar. You should know why. Intermolecular forces of hydrocarbons can only be London forces, but don’t underestimate them! The larger the molecule, the stronger are the London forces (molecules become more polarizable). What is the significance of this fact?

  4. Intermolecular Forces of Hydrocarbons Hydrocarbons with 1 to 5 carbons are gases, 5 to 13 carbons are liquids, and >13 carbons are solids. You should be able to explain why. What does the number of carbon atoms have to do with the physical state of a hydrocarbon? Think about how intermolecular forces affect the physical state of a substance.

  5. Oil Refinery: Distillation Towers

  6. Alcohols Contain –OH: They are not hydroxides! What is the predominant IMF for alcohols? They contain O-H and C-O bonds, which are polar. They have STRONG H-bonding (due to the O-H bonds), as well as dipole forces (due to the C-O bonds) ANS. The predominant IMF is hydrogen bonding.

  7. Why are alcohols not hydroxides? This is methyl alcohol (methanol), with the formula CH3OH. The formula contains “OH” so why is it not classified as a hydroxide? How can you tell from the formula that it is not a hydroxide?

  8. Carboxylic Acids Formic acid HCOOH or HCO2H Acetic acid CH3COOH or CH3CO2H What intermolecular forces do carboxylic acids exhibit? STRONG H-bonding and dipole forces, and London forces. Predominant IMF is H-bonding.

  9. Amines Contain N What intermolecular forces do they exhibit? Mostly STRONG H-bonding (due to N-H bonds) Do ALL amines exhibit H-bonding?

  10. Amines Contain NDo they ALL exhibit H-bonding? Decide for yourself: One of the above does NOT exhibit H-bonding. Do you know which one, and why?

  11. also O-H bonds Note N-H bond here Trimethylamine exhibit only dipole forces and NOT H-bonding because it does not contain any N-H bonds.

  12. Acetone (fingernail polish remover) Acetone belongs in class called ketones. You should have already memorized the structure of acetone. It is a very common organic solvent. CH3COCH3 or (CH3)2CO Does it exhibit H-bonding? NO, because it does not contain any O-H bonds. It is polar and exhibits dipole forces (due to C=O).

  13. Benzene Benzene is another very common organic solvent. (You should have memorized its structure.) What intermolecular forces does it exhibit?

  14. This is a H bond, not H-bonding. NOTE: H-bonding does NOT refer to the actual N-H, O-H or H-F bonds themselves! We say water has H-bonding because it contains O-H bonds, but the actual H-bonding refers to the attraction between H of one molecule to the -of O in a DIFFERENT molecule. THIS is the H-bonding. Note that it is BETWEEN two DIFFERENT molecules. It is NOT a covalent bond.

  15. Why ethyl alcohol dissolves well in water.... They form strong H-bonding between each other. How? Where?

  16. H-bonding here H-bonding here There is NO H-bonding here! Why not? Be sure you know why not! H-bonding between ethyl alcohol and water

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