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Cellular respiration. Thursday, March 11. The Big Picture. Cellular respiration Harvesting energy from glucose using O 2 Use of O 2 = aerobic C 6 H 12 O 6 + O 2 6CO 2 + 6H 2 O + energy Accomplished via ~20 rxns (product of one is reactant for next, all catalyzed).
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Cellular respiration Thursday, March 11
The Big Picture • Cellular respiration • Harvesting energy from glucose using O2 • Use of O2 = aerobic • C6H12O6 + O2 6CO2 + 6H2O + energy • Accomplished via ~20 rxns (product of one is reactant for next, all catalyzed)
The Big Picture • “Glucose is oxidized to carbon dioxide and oxygen is reduced to water.” • C6H12O6 + O2 6CO2 + 6H2O + energy • Hydrogen atoms carry electrons away from carbon atoms in glucose to oxygen atoms
Redox Reactions • Loss of electrons = oxidation • Gain of electrons = reduction An electron transfer always involves an oxidation, reduction “redox”
How does this give us energy? LOGIC: • When the hydrogen atoms form covalent bonds with oxygen, the shared electron pairs are closer to the oxygen nucleus (oxygen is more electronegative than carbon is). • An electron occupying energy level closer to nucleus has less potential energy (similar to a skydiver closer to earth).
How does this give us energy? LOGIC: 3. So, electrons that move from less electronegative carbon to more electronegative oxygen lose potential energy and achieve a LESS ordered state (not intuitive but whatever). 4. The decrease in potential energy coupled with an increase in entropy (electrons being closer to nucleus) causes a decrease in free energy and an overall exergonic reaction.
2nd part • C6H12O6 + O2 6CO2 + 6H2O + energy • Also an oxidation reaction
2nd part • C6H12O6 + O2 6CO2 + 6H2O + energy • Overall change = decrease in potential energy = increase in entropy • “Downhill process” • Energy= heat + light
Why does this happen? • Glucose and O2 stable on their own • Presence of enzymes! • Lower EA • Obligate anaerobes • Obligate aerobes • Facultative anaerobes
Cut and Paste Activity • C6H12O6 + O26CO2 + 6H2O + energy