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Fossil Fuel Innovation. Professor Stephen Lawrence Leeds School of Business University of Colorado at Boulder. National Energy Technology Lab. “Only US National Laboratory Devoted to Fossil Fuel Energy Technology”
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Fossil Fuel Innovation Professor Stephen Lawrence Leeds School of Business University of Colorado at Boulder
National Energy Technology Lab • “Only US National Laboratory Devoted to Fossil Fuel Energy Technology” • Enabling domestic coal, natural gas, and oil to economically power our Nation’s homes, industries, businesses, and transportation … • While protecting our environment and enhancing our energy independence. • NETL has expertise in coal, natural gas, and oil technologies, contract and project management, analysis of energy systems, and international energy issues. http://www.netl.doe.gov
Types of Fossil Fuels • Petroleum (oil) • Natural Gas • Coal • Oil Shale • Tar Sands
Petroleum http://www.lakesoil.com.au/photo6.jpg
Drilling for Oil http://www.umich.edu/~gs265/society/fossilfuels.htm
Coal http://buildingsdatabook.eren.doe.gov/default.asp?id=fow&num=30
Coal Mining Underground Mine Open Pit Mine http://pubs.usgs.gov/fs/fs004-02/ http://www.ornl.gov/sci/fossil/
Sulfur in Coal http://www.fossil.energy.gov/education/energylessons/coal/coal_cct2.html
Natural Gas www.citypublicservice.com http://www.energy.gov.ab.ca/222.asp
Natural Gas Well, Storage, Pipeline http://www.call-adc.com/justiss/rig54pic.htm http://www.isgs.uiuc.edu/isgshome/gas_well.jpg http://www.dom.com/about/gas-transmission/imp/ngp.jsp
US Natural Gas Pipeline Network http://services.unitil.com/fge/bus_natural_gas_equipment.asp
North American Natural Gas Flows http://www2.nrcan.gc.ca/es/erb/prb/english/View.asp?x=447&oid=603
Tar Sands http://www.protectowire.com/applications/profiles/electric_shovels.htm http://www.aapg.org/explorer/2005/05may/dinning.cfm
Oil Shale http://nandotimes.nandomedia.com/ips_rich_content/896-shale_rock.jpg http://geosurvey.state.co.us/Default.aspx?tabid=104
Problems with Fossil Fuels/Coal • Large source of atmospheric pollution • Create carbon dioxide (CO2) when burned • Implicated in global warming • Nitrous oxides (NOx) – smog • Sulfur dioxide (SO2) – acid rain • Measurable amounts of radioactive material • Naturally present in coal • More than a nuclear power plant
Need forClean Coal http://www.enecho.meti.go.jp/english/policy/coal/images/81.gif
CO2 Mitigation Options http://www.netl.doe.gov
CO2 Mitigation Options http://www.netl.doe.gov
Basic Idea of a Power Plant Steam Spinning turbine blades and generator Boiling water
Conventional Coal Power Plant http://www.worldcoal.org/pages/content/index.asp?PageID=108
Modern Coal PP Waste Disposal http://www.ornl.gov/sci/fossil/NewFiles/feaz277.jpg
Fluidized Bed http://www.fossil.energy.gov/education/energylessons/coal/coal_cct4.html
Fluidized Bed Combustion Detail http://envfor.nic.in/cpcb/newsletter/coal/ccombs.html
Circulating Fluidized Bed Combustion http://envfor.nic.in/cpcb/newsletter/coal/ccombs.html
Integrated Gasification Combined Cycle http://envfor.nic.in/cpcb/newsletter/coal/ccombs.html
Pressurized Fluidized Bed Combustion Combined Cycle (PFBC) http://envfor.nic.in/cpcb/newsletter/coal/ccombs.html
Increasing Efficiency with Coal http://www.worldcoal.org/pages/content/index.asp?PageID=24
Carbon Capture and Sequestration http://www.ornl.gov/info/ornlreview/v33_2_00/research.htm
CO2 Mitigation Options http://www.netl.doe.gov
Carbon Capture & Storage • Capture and store emissions of carbon dioxide • Removed from the exhaust gases of the power station • Stored so as not to enter the atmosphere • thus reducing global warming. • Carbon storage is not yet cost-effective • Required technologies are already proven • Similar technologies used commercially in food and chemicals industry http://www.worldcoal.org
Goals of Carbon Sequestration • Effective and cost-competitive • Stable, long term storage • Environmentally benign http://www.fossil.energy.gov/programs/sequestration
Carbon Capture • Absorption (chemical and physical) • Adsorption (physical and chemical) • Low-temperature distillation • Gas separation membranes • Mineralization and biomineralization http://www.fossil.energy.gov/programs/sequestration
Carbon Sequestration Options http://www.whitehouse.gov/omb/budget/fy2006/energy.html
Types of Carbon Sequestration • Geologic Sequestration • Ocean Sequestration • Terrestrial Sequestration • Novel Sequestration Concepts http://www.fossil.energy.gov/programs/sequestration
Geologic Sequestration • Porous rock bodies surrounded by impermeable rock are ideal for CO2 storage • Oil and gas reservoirs • Inject CO2 to improve recovery • Coal bed methane • Inject CO2 into coal seams to extract methane • Inject into deep saline (salt) formations • No direct economic benefit http://www.fossil.energy.gov/programs/sequestration
Geologic Sequestration http://www.midcarb.org/Graphics/CO2flooding.gif
Ocean Sequestration • Ice-like CO2/H2O (water) hydrates • Form in the deep ocean at low temperatures and high pressures • Oceans will naturally absorb 80-90% of CO2 in atmosphere • Eventually transferred to deep ocean • Too slow to prevent CO2 spike in next 100s years • Research investigating direct injection of CO2 into the deep ocean http://www.fossil.energy.gov/programs/sequestration
Ocean Sequestration http://www.lbl.gov/Science-Articles/Archive/sea-carb-bish.html
Terrestrial Sequestration • Forest lands. • Below-ground carbon and long-term management and utilization of standing stocks, understory, ground cover, and litter. • Agricultural lands. • Crop lands, grasslands, and range lands • Emphasis on increasing long-lived soil carbon. • Biomass croplands • Increase soil carbon and value-added organic products • Complement to ongoing efforts related to biofuels,the • Deserts and degraded lands • Restoration of degraded lands significant benefits and carbon sequestration potential in both below-and above-ground systems. • Boreal wetlands and peatlands • Soil carbon pools • Limited conversion to forest or grassland where ecologically acceptable. http://www.netl.doe.gov/technologies/carbon_seq/core_rd/storage.html
Terrestrial Sequestration Click image for video clip http://earthobservatory.nasa.gov/Newsroom/MediaResources/Carbon/global_biosphere.mpeg
Novel CS Concepts • Biological systems; • Advanced catalysts for CO2 or CO conversion; • Novel solvents, sorbents, membranes, and thin films for gas separation; • Engineered photosynthesis systems; • Non-photosynthetic mechanisms for CO2 fixation (methanogenesis and acetogenesis); • Genetic manipulation of agricultural and tree to enhance CO2 sequestering potential; • Advanced decarbonization systems; and • Biomimetic systems. http://www.fossil.energy.gov/programs/sequestration
Carbon Sequestration http://www.fossil.energy.gov/programs/sequestration
DOE Vision 21 http://www.fossil.energy.gov/programs/powersystems/vision21/
DOE Vision 21 • By 2015, develop the core modules for a fleet of fuel-flexible, multi-product energy plants that boost power efficiencies to 60+ percent, emit virtually no pollutants, and with carbon sequestration release minimal or no carbon emissions. • Wide variety of fuels such as coal, natural gas, biomass, petroleum coke (from oil refineries), and municipal waste http://www.fossil.energy.gov/programs/powersystems/vision21/
Vision 21 Multidisciplinary http://www.netl.doe.gov/