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MS/MS of ions at m/z 376.15 from HP. MS/MS of ions at m/z 212.08 from CPHP. 358.13770. 100. 165.07127. 95. 90. 376.14819. 85. 80. 100. 75. 70. 95. 65. 60. Relative Abundance. 90. 55. 50. 85. 45. 40. 35. 80. 30. 25. 75. 20. 123.02409. 15. 70. 10. 5. 65. 0. 100.

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  1. MS/MS of ions at m/z 376.15 from HP MS/MS of ions at m/z 212.08 from CPHP 358.13770 100 165.07127 95 90 376.14819 85 80 100 75 70 95 65 60 Relative Abundance 90 55 50 85 45 40 35 80 30 25 75 20 123.02409 15 70 10 5 65 0 100 150 200 250 300 350 400 60 55 165.07132 360.13492 100 50 95 90 45 85 80 40 75 70 35 65 60 55 30 Relative Abundance 50 45 25 40 35 20 30 25 15 20 123.02410 15 378.14529 196.07062 10 10 5 0 5 100 150 200 250 300 350 400 MS3 of ions at m/z 378.14 and 360.15 from RHP 0 100 360.15390 95 90 85 80 342.14337 75 356.12091 70 65 60 Relative Abundance e 55 Relative Abundance 50 45 40 35 149.07654 149.07579 30 25 224.08463 20 194.07391 15 10 5 0 100 150 200 250 300 350 400 100 150 200 250 300 350 400 m/z 100 194.07385 95 90 85 T: FTMS + p ESI Full ms2 212.08@cid13.00 [55.00-400.00 80 T: FTMS + p ESI Full ms2 376.15@cid22.00 [100.00-400.00] 75 70 65 60 Relative Abundance 55 50 45 212.08461 40 35 30 25 20 15 10 5 0 100 150 200 250 300 350 400 MS/MS of ions at m/z 378.16 from RHP MS/MS from ions at m/z 354.11 from HPP* 100 95 165.07085 90 T: FTMS + p ESI Full ms2 378.16@cid22.00 [100.00-400.00] T: FTMS + p ESI Full ms2 354.11@cid22.00 [95.00-400.00 85 80 75 70 65 Relative Abundance 60 354.10541 55 50 45 40 35 30 25 20 123.02377 190.04172 15 10 5 0 100 150 200 250 300 350 400 MS/MS from ions at m/z 356.12 from RHPP* 190.04161 T: FTMS + p ESI sid=15.00 Full ms3 378.14@cid22.00 360.15@cid22.00 [95.00-400.00] T: FTMS + p ESI Full ms2 356.12@cid22.00 [95.00-400.00] m/z

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