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Chapter 3 Atomic Theory. Early Theories. 4 elements. Democritus (460 - 370 BC). Greek philosopher Atomos – indivisible particles Atoms are the smallest particle that retains the chemical identity. The Greeks Used Logic.
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Early Theories • 4 elements
Democritus(460 - 370 BC) • Greek philosopher • Atomos – indivisible particles • Atoms are the smallest particle that retains the chemical identity
The Greeks Used Logic • The Greeks also believed in a combination of elements to make new things. • For example: Water and Earth = Mud • Mud might just seem like a nuisance to us, but back then it was a building material. • Fire and Earth made Lava. • If you are curious check out the Little Alchemy app (game) that can be found in Google Apps. It is a fun game.
Jabir Ibn Haiyan(700? - 803 AD) • Father of Chemistry • Practiced Alchemy • Discovered metals
Antoine Lavoisier(1743 - 1794) • Law of Conservation of Matter
Joseph Louis Proust(1754-1826) • Law of Constant Composition
John Dalton (1766 - 1844) • Atomic Theory • This was the true start of our modern theory of matter.
Dalton’s Theory • Dalton’s ideas were a good start. • However, we need to look at one of his postulates more closely. • He stated that “All atoms of the same atom are identical…” • He didn’t know about isotopes. The neutron wasn’t discovered for another 130 years.
Atomic Theory • Elements made of atoms • Atoms are identical of a given type of element • Atoms neither created nor destroyed • Compounds have fixed ratio of atoms
Ben Franklin (1706-1790) • Two types of charge positive (+) and negative (-)
Michael Faraday(1791-1867) • Atoms are related to electricity
J.J. Thomson(1856 - 1940) • Cathode Ray Tube (CRT) stream of electrons • Plum Pudding Model
Thomson’s Model • This lead directly to the idea of electrons and was a major advancement in atomic theory. • Sometimes this theory is called “Raisins in a Plum Pudding.”
Robert Millikan(1838-1953) • Determined charge & mass of electron
Henri Becquerel(1852 - 1908) • Uranium exposes film
Marie (1867-1934) & Pierre Curie (1859-1906) • Discovered radioactivity elements • Radioactive decay
Earnest Rutherford(1871 - 1937) • Discovered radioactivity particles • Discovered Nucleus • Solar system model of atom
Rutherford’s Gold Foil Experiment • There are animations on the website so that you can get a better visual of the experiment. • Rutherford’s experiment was truly a marvel. • It answered a lot of questions and gave a good framework for future investigations. • Remember that it was still a theory – there is a long way to go in understanding an atom.
Early Atomic Theory • At this point, this completes our look at the early contributors into Atomic Theory and Structure. • You were given a lot of names, but here are the ones I want you to focus on: • Democritus, Dalton, Thompson, Rutherford • When we get to other topics, we will explore a few more of them in detail such as Becquerel and the Curies.
Study Guide Help • To assist you in your preparation, take note that I will not be asking much if anything about the following scientists: • Ben Franklin, Joseph Proust, Michael Faraday • Robert Millikan, Jabir Ibn Haiyan, and Antoine Lavoisier might get a short question or two on a test or quiz.
Niels Bohr (1885 – 1962) • Electrons do not orbit like planets • Described shells or energy levels • Quantum theory
H.G.J. Moseley (1887 - 1915) • Discovered protons (+) in the nucleus • Rearranged periodic table
Sir James Chadwick (1891-1974) • Discovered neutrons (0) in the nucleus
Quarks, Quarks, Quarks (1950s – present) • 6 quarks have been discovered that make up protons and neutrons
Protons • Make up the nucleus • Charge +1.602 x 10 -19C • Mass = 1.673 x 10 -24g • Charge +1 • Mass = 1 amu
Neutrons • Make up the nucleus • Charge 0 • Mass = 1.675 x 10 -24g • Mass = 1 amu
Electrons • Occur in electron Clouds • Charge -1.602 x 10 -19C • Mass = 9.109 x 10 -28g • Charge = -1 • Mass = 0 amu
Atoms are small but nuclei are smaller • Diameter of a penny has 810 million copper atoms
Atomic Number • Number of protons in an atom • Electrically neutral atoms have the same number of electrons as protons • Ions are formed by gaining or losing electrons
Isotopes • Same number of Protons but different numbers of neutrons • Mass number is the sum of the protons and the neutrons • Isotopes have the same chemical properties • Violates Dalton’s atomic theory
Masses of Atoms • 1 amu = 1/12 mass of a 12C atom • 99% Carbon 12C • 1% Carbon 13C • Average atomic mass of C is 12.01 amu • Mass number is for one atom • Listed as a decimal on the periodic table
Nuclear Reactions • Nuclear reactions involve the nucleus of the atom • Radioactivity is the spontaneous emission of radiation from an atom • Nuclear reactions change elements involved
Alpha particle Helium nucleus with no electrons Will bounce off of paper and skin +2 charge Alpha Particle
Beta particle High energy electron Come from the decay of a neutrons Will penetrate skin Blocked by aluminum and Plexiglass -1 charge Beta Particle
Gamma Rays High energy wave No charge No mass Penetrates skin, damages cells and mutates DNA Blocked by lead Gamma Radiation