1 / 12

MOF overview

MOF overview. MOF recent review issue . http://newsroom.ucla.edu/portal/ucla/srp-view.aspx?id=105680. http://pubs.acs.org/toc/chreay/112/2. Nets derived from the net of the primitive cubic lattice ( pcu ).

tekla
Download Presentation

MOF overview

An Image/Link below is provided (as is) to download presentation Download Policy: Content on the Website is provided to you AS IS for your information and personal use and may not be sold / licensed / shared on other websites without getting consent from its author. Content is provided to you AS IS for your information and personal use only. Download presentation by click this link. While downloading, if for some reason you are not able to download a presentation, the publisher may have deleted the file from their server. During download, if you can't get a presentation, the file might be deleted by the publisher.

E N D

Presentation Transcript


  1. MOF overview

  2. MOF recent review issue http://newsroom.ucla.edu/portal/ucla/srp-view.aspx?id=105680 http://pubs.acs.org/toc/chreay/112/2

  3. Nets derived from the net of the primitive cubic lattice (pcu). Deconstructing the Crystal Structures of Metal–Organic Frameworks and Related Materials into Their Underlying Nets Michael O’Keeffe*†‡ and Omar M. Yaghi*‡§ Chem. Rev., 2012, 112 (2), pp 675–702 DOI: 10.1021/cr200205j

  4. SBUs Figure 5. (a) The Re6Se8(CN)6 unit. (b) The same abstracted as an octahedral SBU. • Chem. Rev., 2012, 112 (2), pp 675–702

  5. Linkers • Chem. Rev., 2012, 112 (2), pp 675–702

  6. Science 18 January 2002: Vol. 295 no. 5554 pp. 469-472 DOI: 10.1126/science.1067208

  7. Intergrown nets Figure 4: Catenation of rings in nets intergrown with their dual structures. The nets are shown augmented with triangles at the three-coordinated vertices and octahedra at the six-coordinated vertices. a, A pair of identical rings in the self-dual pyr net of MOF-150 (ref. 11). b, A six-membered ring of the qom net (red) of MOF-177 catenated with a ring of the dual net (blue). A pair of three-coordinated vertices are directly linked, as are pairs of six-coordinated vertices. Nature427, 523-527 (5 February 2004) | doi:10.1038/nature02311; Received 9 September 2003; Accepted 16 December 2003

  8. Microstructures http://www.mf.mpg.de/de/abteilungen/schuetz/ Figure 14. (a) Top- and (b) cross-sectional view the ZIF-8 membrane synthesized by secondary growth technique. Reproduced with permission from ref 278 Chem. Rev., 2012, 112 (2), pp 933–969

  9. Properties Nature Communications 3(604), 2012; DOI: 10.1038/ncomms1618  Crystal structure of zinc-adeninate MOF. ZN2+, dark blue tetrahedra; C, gray spheres; O, red spheres; N, blue spheres; H, omitted for clarity. I …exhibits a high surface area (4,300 m2 g−1), one of the lowest crystal densities (0.302 g cm−3) and the largest metal-organic framework pore volume reported to date (4.3 cm3 g−1).

  10. CO2 adsorption Figure 12. A portion of the crystallographic structure of Ni2(dobdc) following dosing with CO2. Green, gray, and red spheres represent Ni, C, and O atoms, respectively; H atoms are omitted for clarity.(193) http://www.sigmaaldrich.com/technical-documents/articles/materials-science/metal-organic-frameworks/ni-mof-74.html

  11. Separations Table 10. Components of the Shifted Products of Steam Methane Reformation(417) Chem. Rev., 2012, 112 (2), pp 724–781

  12. Ferroelectric MOFs Figure 9. Structures of [(NH4)Li(C4H4O6)]·H2O in the paraelectric phase (293 K): (a) unit cell along the c axis and (b) layer structure in the ab plane. Green dotted lines represent hydrogen bonds. Chem. Rev., 2012, 112 (2), pp 1163–1195 Temperature dependence of dielectric constant of (a) [(NH4)Li(C4H4O6)]·H2O

More Related