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tudi. Thermal studies on barium sulphate in a pilot scale, rotary kiln. Ruto S. , Maree J.P., Kolesnikov A., Zvinowanda C.M., Louw W.J. OUTLINE. Background Materials and Methods Results and Discussion Conclusions. Background.
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tudi Thermal studies on barium sulphate in a pilot scale, rotary kiln Ruto S., Maree J.P., Kolesnikov A., Zvinowanda C.M., Louw W.J.
OUTLINE Background Materials and Methods Results and Discussion Conclusions
Background • Sulphate removal from mine wastewater results in the buildup of large amounts of wastes, mainly barium sulphate and gypsum. • This sludge disposal is an environmental problem and a cost burden. • Thermal reduction of barium sulphate to BaS for starting production BaCO3 and sulphur.
Objectives • Thermal reduction of barium sulphate to BaS • To optimization of the rotary kiln
Thermal studies on barium sulphate in a pilot scale, rotary kiln.
Materials and methods Barium sulphate Coal Argon gas The effect of several operating variables such as, rotation speed, feed-rate, inclination angle, and temperature were investigated.
Figure 1. Effect of drum rotation speed on the yield of BaS. Rotation speed (1.8 rpm, 2.4 rpm, 3.3 rpm, 3.8 rpm, 4.2 rpm, 5 rpm), feed-rate (1 kg/min), inclination angle (2.3°), temperature 1,180°C,
Figure 2. Effect of mixture feed-rate on the yield of BaS. Feed-rate (0.8, 1, 1.6, 3.3 and 5 kg/min), rotation speed (1.8 rpm), inclination angle (2.3°), temperature 1,180°C
Figure 3. Effect of drum angle of inclination on the yield of BaS. Angle of inclination 2.3°, 3.2°, and 4.2° ,feed-rate (0.8 kg/min), rotation speed (1.8 rpm), temperature 1,180°C,
Figure 4. Effect of of drum temperature on the yield of BaS Temperature 900°C - 1180°C, feed-rate (0.8 kg/min), rotation speed (1.8 rpm), inclination angle (2.3°).
Table 1. XRD analysis results for the thermal reduction of barium sulphate to BaS .Feed-rate (0.8 kg/min), rotation speed (1.8 rpm), inclination angle (2.3°), temperature 1,180°C
Conclusions The optimum conditions for different parameters were established. Thermal reduction of Barium sulphate to Bas was achieved. .
Acknowledgements Thanks are due to the following organizations: • THRIP • Tshwane university of technology • Thermopower furnaces