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Large-Scale Hydrogen Deflagration and Detonations. M. Groethe E. Merilo J. Colton S. Chiba Y. Sato H. Iwabuchi. International Conference on Hydrogen Safety 8-10 September 2005 Pisa, Italy. Objectives 300 m 3 Open-Space Tests 1/5 Scale Tunnel Tests Partial Confinement Test
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Large-Scale Hydrogen Deflagration and Detonations M. Groethe E. Merilo J. Colton S. Chiba Y. Sato H. Iwabuchi International Conference on Hydrogen Safety 8-10 September 2005 Pisa, Italy
Objectives 300 m3 Open-Space Tests 1/5 Scale Tunnel Tests Partial Confinement Test Protective Blast Wall Test Large-Scale release (300 Nm3 H2) Summary Outline
Objective • Acquire basic data on hydrogen deflagrations and detonations. • Acquire hydrogen deflagration/detonation data for validation of computer simulations. Studies were performed for IAE and administered through NEDO as part of the “Development for Safe Production and Utilization and Infrastructure of Hydrogen” program.
300 m3 Open-Space Tests Obstacle-induced enhancement, scaling, free-field blast data. • Deflagration tests with obstacles. • Deflagration tests without obstacles. • Detonation tests without obstacles. Obstacle Test 0.46 m-diam X 3 m-tall 300 m3 5.7 m Volume Blockage ratio: ~11%
Obstacle Test • Standard and infrared video frames ~67 ms ~67 ms ~100 ms
Deflagration Data Overpressure Heat Flux Scaled Overpressure Scaled Impulse
Stoichiometric Detonation • High-Speed Video Frames
Detonation Data • Detonation data consistent with previous smaller scale tests Overpressure Heat flux Scaled Impulse Scaled Overpressure
Tunnel Experiments Deflagration, H2 release, Obstacle-induced enhancement. • Homogeneous deflagration tests. • Tests with and without scaled vehicles as obstacles. • Scaled release and ventilation rates. ~ 1/5 scale
Tunnel with Vehicle Models Obstacles representing scaled vehicles. Blockage ratio: 0.03
Pressure and Impulse Overpressure • Overpressure and impulse unchanged by presence of vehicle models. Impulse Overpressure
H2 Release Tests • Ventilation significantly reduces H2 concentration • Test 14 and Test 15: 0.1 kg H2 in 20 sec, no ventilation. • Test 16: 0.1 kg H2 in 20 sec, 1.6 m3/sec ventilation rate. • Test 17: 2.2 kg H2 in in 420 sec, 1.6 m3/sec ventilation rate. H2 concentration H2 concentration
Partial Confinement Test Deflagration enhancement from partial confinement. • Narrow gap between two plates provides partial confinement • Flame position measured by ionization pins. • Overpressure measured inside and outside the source.
Standard Video Frame IR Video Frame ~33 ms ~33 ms Scaled Overpressure Scaled Impulse Partial Confinement Test • Confinement between plates does not enhance deflagration
Protective Wall Tests Assess overpressure reduction by using a protective blast wall. • 4 m-tall by 10 m-wide wall, 4 m from edge of the 5.3 m3 source • Stoichiometric deflagration (bottom, center spark ignition) • Pressure measured inside the source and in the free-field. Test Layout
Protective Wall Test Setup Blast sensors 10 m 4 m Wall 5.3 m3 Source
Scaled Overpressure and Impulse • Deflagration data suggests a reduction in overpressure and impulse. • Previous tests with a 2 m-tall wall show reductions up to 30%. Scaled Overpressure Scaled Impulse
Large-Release Test Rapid release of a large quantity of hydrogen that is ignited. • 300 Nm3 H2 (27 kg) released in about 30 seconds. • Spontaneous ignition occurred at ~360 milliseconds. Sample station 18-m tower Estimated Flame Jet Tower Sample station Sample station Table with drywall insert Nozzle Igniters (15mJ) Nozzle Release valve Pressure and heat flux
Large-Release Test • High-Speed Video Frames
Overpressure Heat Flux Flame Speed Large-Release Test
Summary • Large-scale 300 m3 open space deflagrations and detonations. • - Large obstacles do not enhance the deflagration. • - Detonation data consistent with smaller scale tests and analytic expressions. • Partial confinement of mixture between two plates. • - Deflagration was not enhanced for this geometry. • 1/5 scale tunnel tests. • - Homogeneous deflagrations show near constant overpressure and impulse • - 30% H2 blast is much higher than the free-field case. • - Vehicle models do not enhance deflagration (BR = 0.03, which is small) • - Ventilation of the tunnel significantly reduces the H2 concentration. • 4 m-tall protective blast wall. • - Blast reduction is suggested to over twice the wall height. • - Previous tests and calculations show a reduction that diminishes with range1. • Large-scale release of hydrogen. • - Release spontaneously ignite producing a blast followed by a flame jet. • - Ignited release produced a higher blast pressure and lower impulse than a • static homogeneous deflagration. 1 M. Groethe, J. Colton, S. Chiba, and Y. Sato, “ Hydrogen Deflagrations at Large Scale,” 15th World Hydrogen Energy Conference, Yokohama, Japan, 27 June - 2 July, 2004.