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Isomerism: Understanding Chirality and Structural Symmetry in Coordination Chemistry

Explore the concepts of isomerism, chirality, and structural symmetry in coordination chemistry using key examples like cis/trans forms and fac/mer configurations. Learn about the Nobel Prize-winning development of the metathesis method in organic synthesis in 2001.

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Isomerism: Understanding Chirality and Structural Symmetry in Coordination Chemistry

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  1. Chapter 7Isomerism

  2. [PtCl2(NH3)2] Cis-form trans-form

  3. cis-[CoCl2(NH3)4]+

  4. [IrCl3(PMe3)3] fac-form mer-form

  5. [Ru(bipy)3]2+

  6. Chirality 掌性

  7. 丙胺酸 Chirality 掌性 莞烯 http://nobelprize.org/chemistry/laureates/2001/public.html

  8. Lacking of perpendicular C2 symmetry

  9. Lacking of mirror plane or center of inversion

  10. for the development of the metathesis method in organic synthesis 2001 Ryoji Noyori 1938 Nagoya University Nagoya, Japan K. Barry Sharpless 1941 The Scripps Research Institute La Jolla, CA, USA William S. Knowles 1917 St. Louis, MO, USA

  11. Catalysts & Ligands for Olefin Hydrogenation Knowles work

  12. Catalysts & Ligands for Olefin Hydrogenation Noyori’s work

  13. Sharpless’s work

  14. Asymmetric bidentate ligands

  15. For an octahedral complex that has six different ligands

  16. Structure versus number of isomers

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