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Writing Formulas of Ionic Compounds. By Sharon Mace, West Stanly HS, NC. Binary Ionic Compounds:. Binary Ionic Compounds:. Have only two types of elements. Are made of monatomic ions only. The name always ends in “-ide ”. The first ion is always positive.
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Writing Formulas of Ionic Compounds By Sharon Mace, West Stanly HS, NC
Binary Ionic Compounds: • Have only two types of elements. • Are made of monatomic ions only. • The name always ends in “-ide”. • The first ion is always positive. • The second ion is always negative. • They DO NOT have an overall charge. • They NEVER have ( )’s. (Parentheses are only used with more than oneof a polyatomic ion, never with a monatomic ion.)
Example:Sodium Chloride Na+1 Cl-1
Example:Sodium Chloride Na+1 Cl-1 It takes one of each ion to make a neutral compound.
Example:Sodium Chloride Na+1 Cl-1 It takes one of each ion to make a neutral compound. NaCl • NaCl
OR… Use the criss-cross method:
Example:Sodium Chloride Na+1 Cl-1
Example:Sodium Chloride Na+1 Cl-1 Take the 1 from the Na and put it as the invisible subscript on Cl.
Example:Sodium Chloride Na+1 Cl-1 Take the 1 from the Na and put it as the invisible subscript on Cl. Take the 1 from Cl and put it as the invisible subscript on Na.
Example:Sodium Chloride Na+1 Cl-1 Take the 1 from the Na and put it as the invisible subscript on Cl. Take the 1 from Cl and put it as the invisible subscript on Na. NaCl • NaCl
Example:Magnesium Chloride Mg+2 Cl-1
Example:Magnesium Chloride Mg+2 Cl-1 It takes one magnesium and two chlorides to make a neutral compound.
Example:Magnesium Chloride Mg+2 Cl-1 It takes one magnesium and two chlorides to make a neutral compound. Mg+2 + Cl-1 + Cl-1 = No charge
Example:Magnesium Chloride Mg+2 Cl-1 It takes one magnesium and two chlorides to make a neutral compound. Mg+2 + Cl-1 + Cl-1 = No charge MgCl2 • MgCl2
OR… Use the criss-cross method:
Example:Magnesium Chloride Mg+2 Cl-1
Example:Magnesium Chloride Mg+2 Cl-1 Take the 2 from the Mg and put it as the subscript on Cl.
Example:Magnesium Chloride Mg+2 Cl-1 Take the 2 from the Mg and put it as the subscript on Cl. MgCl2
Example:Magnesium Chloride Mg+2 Cl-1 Take the 2 from the Mg and put it as the subscript on Cl. MgCl2 Take the 1 from Cl and put it as the invisible subscript on Mg.
Example:Magnesium Chloride Mg+2 Cl-1 Take the 2 from the Mg and put it as the subscript on Cl. MgCl2 Take the 1 from Cl and put it as the invisible subscript on Mg. MgCl2 • MgCl2
Example:Aluminum Sulfide Al+3 S-2
Example:Aluminum Sulfide Al+3 S-2 It takes two aluminum ions and three sulfide ions to make a neutral compound.
Example:Aluminum Sulfide Al+3 S-2 It takes two aluminum ions and three sulfide ions to make a neutral compound. Al+3 + Al+3 + S-2 + S-2 + S-2 = No Charge
Example:Aluminum Sulfide Al+3 S-2 It takes two aluminum ions and three sulfide ions to make a neutral compound. Al+3 + Al+3 + S-2 + S-2 + S-2 = No Charge Al2S3 • Al2S3
OR… Use the criss-cross method:
Example:Aluminum Sulfide Al+3 S-2
Example:Aluminum Sulfide Al+3 S-2 Take the 3 from the Al and put it as the subscript on S.
Example:Aluminum Sulfide Al+3 S-2 Take the 3 from the Al and put it as the subscript on S. AlS3
Example:Aluminum Sulfide Al+3 S-2 Take the 3 from the Al and put it as the subscript on S. AlS3 Take the 2 from S and put it as the subscript on Al.
Example:Aluminum Sulfide Al+3 S-2 Take the 3 from the Al and put it as the subscript on S. AlS3 Take the 2 from S and put it as the subscript on Al. Al2S3 • Al2S3
Example:Magnesium Oxide Mg+2 O-2
Example:Magnesium Oxide Mg+2 O-2 It only takes ONE of each ion to make a neutral compound.
Example:Magnesium Oxide Mg+2 O-2 It only takes ONE of each ion to make a neutral compound. Mg+2 + O-2 = No charge
Example:Magnesium Oxide Mg+2 O-2 It only takes ONE of each ion to make a neutral compound. Mg+2 + O-2 = No charge MgCl2 • MgO
OR… Use the criss-cross method:
Example:Magnesium Oxide Mg+2 O-2 First, you must reduce the charge ratio! A +2 to -2 ratio cancels to +1 to -1:
Example:Magnesium Oxide Mg+2 O-2 First, you must reduce the charge ratio! A +2 to -2 ratio cancels to +1 to -1: Mg+1 O-1 NOW you can criss-cross:
Example:Magnesium Oxide Mg+2 O-2 First, you must reduce the charge ratio! A +2 to -2 ratio cancels to +1 to -1: Mg+1 O-1 NOW you can criss-cross: • MgO
Now you try it: Question answer • Potassium selenide • Aluminum phosphide • Beryllium carbide ________ ________ ________ Watch out for canceling!
Now you try it: Question answer • Potassium selenide • Aluminum phosphide • Beryllium carbide K2S AlP Be2C
Adding Transition Metal Ions: When the name of a compound contains a transition metal ion, the Roman numeral or the classical name refers to the charge on the ion BEFORE you figure out the formula of the compound.
Example:Manganese (II) BromideORManganous Bromide: Mn+2 Br-1
Example:Manganese (II) BromideORManganous Bromide: Mn+2 Br-1 • MnBr2