50 likes | 205 Views
HCl, V<-<-X, v´=14, j’=7,8, Q line, from VHW Agust,www, ..../remi/hcl/HCl,agust07-/HCl VQ7,8,PvsI-210907vhwak.ppt Agust,heima, ..../REMPI/HCl/HCl,agust07-/HCl VQ7,8,PvsI-210907vhwak.pxp. Conclusion from calibration based on H+, C+ and C2+ masses. ?, possibly H 2 35 Cl +. i.e.
E N D
HCl, V<-<-X, v´=14, j’=7,8, Q line, from VHW Agust,www, ..../remi/hcl/HCl,agust07-/HCl VQ7,8,PvsI-210907vhwak.ppt Agust,heima, ..../REMPI/HCl/HCl,agust07-/HCl VQ7,8,PvsI-210907vhwak.pxp
Conclusion from calibration based on H+, C+ and C2+ masses ?, possibly H235Cl+ i.e NB!: It is hard to believe that This could be 37Cl+ since hardly no H37Cl+ signal is observed and the ratio of H37Cl+ to 37Cl+ should be comparable to that For H35Cl+ to 35Cl+ For no window H35Cl+ 35Cl+
Conclusion from calibration based on H+, C+ and C2+ masses It looks as if there are big high speed components and small low speed components, both for 35Cl+ and H35Cl+ 35Cl+ H35Cl+ Repeated Mass spectra vs power for HCl V´=14, j´=7, Q lines E=0.2 mJ at 21345.65 cm\S-1\M Used 0-5 windows respectively. Scope set up: 1 \F'Symbol'm\F'Arial'S/20 mV/div 19/09/2007, Wang For no window
H35Cl+ Repeated Mass spectra vs power for HCl V´=14, j´=7, Q lines E=0.2 mJ at 21345.65 cm\S-1\M Used 0-5 windows respectively. Scope set up: 1 \F'Symbol'm\F'Arial'S/20 mV/div 19/09/2007, Wang 35Cl+ H+
It looks as if I(H+), I(35Cl+) and I(H35Cl+) from the last data is constant with power