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290708 HCl, f 3 D 2 <-<- X Agust, heima,..July08/II for f3D2-290708vhw.pxp

290708 HCl, f 3 D 2 <-<- X Agust, heima,..July08/II for f3D2-290708vhw.pxp Agust, heima,..July08/II for f3D2-290708vhwak.ppt Agust, heima,..July08/II for f3D2-290708vhwak.xls. 230708 / e-mail from ÁK:

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290708 HCl, f 3 D 2 <-<- X Agust, heima,..July08/II for f3D2-290708vhw.pxp

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  1. 290708 HCl, f3D2 <-<- X Agust, heima,..July08/II for f3D2-290708vhw.pxp Agust, heima,..July08/II for f3D2-290708vhwak.ppt Agust, heima,..July08/II for f3D2-290708vhwak.xls

  2. 230708 / e-mail from ÁK: The ”Thorey´s-system” needs to be remeasured and checked in terms of reproducibility. Furthermore, it is very important to make sure that the measurements used to derive I(35Cl+)/I(H35Cl+) for that system are not saturated with respect to the I(H35Cl+) signal, which is much stronger than I(35Cl+). Below (slide 3) you see relevant figure and Thorey´s analysis. It could be that all the ratios which she derived from the experiments are too high because of saturation effects. Hence I suggest that you do new measurements and make sure that neither the 35Cl+ or H37Cl+ signals are saturated and derive I(35Cl+)/I(H37Cl+) to compare with the theory (instead of I(35Cl+)/I(H35Cl+)).

  3. I(35Cl+)/I(H35Cl+) Thorey´s thesis p: 6 VHW(250708) J´ => It looks as if there is some saturation effect in Thorey´s data compared to the data by VHW

  4. I(35Cl+)/I(H35Cl+) I(35Cl+)/I(H37Cl+) VHW 250708 J´

  5. I(35Cl+)/I(H35Cl+) Thorey Thesis p: 6 Increasing Saturation(?) VHW(250708) VHW(280708) J´ => looks like some saturation effect in the 250708 data compared to the 280708 data for J´= 3-6 (?)

  6. I(35Cl+)/I(H35Cl+) I(35Cl+)/I(H37Cl+) VHW J´ • Probably no saturation in J’ = 2-5; Possibly some saturation effect in 35Cl+/H35Cl+ for J´= 6-7 (judging from comparison of the two data)

  7. Above data: NB!: expectation value is: 100 * I(H37Cl)/I(H35Cl) = 100*25/75 = 33.3 The data in column H37Cl+/H35Cl+ could mean that there are still some saturation effects in J´= 3-6 (??) since The ratio is found to be significantly less than 33.3 (i.e. 19.2-24.2). However there is slight relative shift of mass peaks for H35Cl+ and H37Cl+, hence the ratios might deviate from the expectation value. VHW will try to Evaluate relative intensity values by integration over excitation wavelengths as well as mass

  8. VHW remeasured peak intensities: NB: since the Cl+ peak is very weak one needs to take great care in the integration procedure. After remeasuring the data from 280708, the following curve was obtained: I(35Cl+)/ I(H37Cl+) I(35Cl+)/ I(H35Cl+) J´

  9. Above data: J´ 35Cl+ H35Cl+ H37Cl+ 35Cl+/H35Cl+ 35Cl+/H37Cl+ • 126 22915 7599 0.00549858 0.0165811 • 240 25096 5518 0.00956328 0.043494 • 233 15868 3014 0.0146836 0.0773059 • 177.5 61416 12662 0.00289013 0.0140183 • 36 108110 26201 0.000332994 0.00137399 • 157400 48839 0.000254129 0.000819017

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