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Bell-Ringer. Why is accuracy so important in science? What is the difference between accuracy and precision? What is meant by the term “significance?”. Section 2-3 Using Scientific Measurements. Coach Kelsoe Chemistry Pages 44-57. Accuracy vs. Precision.
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Bell-Ringer • Why is accuracy so important in science? • What is the difference between accuracy and precision? • What is meant by the term “significance?”
Section 2-3Using Scientific Measurements Coach Kelsoe Chemistry Pages 44-57
Accuracy vs. Precision • Accuracy refers to the closeness of measurements to the correct or accepted value of the quantity measured. • Precision refers to the closeness of a set of measurements of the same quantity made in the same way
High Accuracy, High Precision • The arrows on the drawing have high accuracy, because they are on the bullseye, and are close to each other.
Low Accuracy, Low Precision • The arrows on the drawing have low accuracy, because they are not near the bullseye, and are not precise because they are not near each other.
Low Accuracy, High Precision • The arrows on the drawing have low accuracy, because they are not near the bullseye, but are close to each other.
High Accuracy, Low Precision • The arrows on the drawing have high accuracy (on average), because they are near the bullseye, but are not close to each other.
Percent Error • Percent error is calculated by subtracting the experimental value from the accepted value, dividing the difference by the accepted value, and then multiplying by 100. Percent Error = Valueaccepted-Valueexperimental x 100 ______________________ Valueaccepted
Percent Error % • Percent error has a negative value if it is greater than the experimental value, and a positive value if the accepted value is less than the experimental value.
Significant Figures • Significant figures in measurement consist of all the digits known with certainty plus one final digit, which is somewhat uncertain or is estimated. • For example, if I asked you to measure the length of a paper clip to one hundredths of a centimeter, and you measured 5.78 cm, the 8 would be uncertain. • “Significant” does not necessarily mean “certain.”
Rules for Significant FiguresKNOW THESE!!! • 37 has two • 92116 has five • 80.4 has three • 50019 has five • 0.01265 has four • 0.0000038 has 2 • All nonzero numbers ARE significant. • Zeros appearing between nonzero digits ARE significant. • Zeros appearing in front of all nonzero digits ARE NOT significant.
Rules for Significant FiguresKNOW THESE!!! • 85.0000 has six • 72.000000 has 8 • 46.0 has three • 2000 has one, but.. • 2000. has four • For our purposes, if it has a decimal, the zeros count! • Zeros at the end of a number and to the right of a decimal point ARE significant. • Zeros at the end of a number but to the left of a decimal point may or may not be significant.
Bellringer • Which number is the only number that we question its “significance?” • What is the difference between accuracy and precision? • How do WE calculate percent error?
Rounding Significant Figures • The only time you round up is when: • Greater than 5 • 42.68 g 42.7 g • 5, followed by nonzero digit(s) • 2.7851 cm 2.79 cm • 5, not followed by nonzero digit(s), and preceded by an odd digit • 4.635 kg 4.64 kg (because 3 is odd)
Rounding Significant Figures • The last number will stay the same when the digit following the last digit to be retained is: • Less than 5 • 17.32 m 17.3 m • 5, not followed by nonzero digit(s), and the preceding significant digit is even • 78.65 mL 78.6 mL (because 6 is even)
Using Significant Figures Rounding Addition or Subtraction – the answer should have the same number of decimals places as the measurement used with the fewest decimal places Multiplication and Division – the answer should have the same number of significant figures as the measurement used with the fewest significant figures. Conversion factors are NOT used to determine significant figures!
Scientific Notation • Scientific Notation - method of expressing numbers using exponential notation; a measurement is expressed as a number between 1 and 10 multiplied by a whole-number power of ten • M x 10n 1 M < 10 • n is an integer (whole number)
Relationships • Two quantities (x and y) are directly related if dividing one by the other gives a constant value • x / y = k or x = yk • Graph would be a straight line • Two quantities (x and y) are inversely related to each other if their product is constant • y = k / x or yx = k • Graph would be a hyperbola