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Enhancing Pipeline Integrity with Early Detection of Internal Corrosion. Drew Hevle NACE Houston Section Principal Corrosion Engineer June 9, 2009 El Paso Corporation. Disclaimer.
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Enhancing Pipeline Integrity with Early Detection of Internal Corrosion Drew Hevle NACE Houston SectionPrincipal Corrosion Engineer June 9, 2009El Paso Corporation
Disclaimer • This presentation discusses components of an internal corrosion control program for natural gas and hazardous liquid pipeline systems • It is not a discussion of the policies and practices of any particular pipeline operator
Internal Corrosion • Four things are necessary in order for a corrosion cell to form: • Anode • Cathode • Electrolyte • Metallic path • For internal corrosion to occur, an electrolyte (usually liquid water) must be present
Internal Corrosion Cell Electrolyte Cathode Anode Metallic path
Sources of Water • Natural gas transmission pipelines typically transport tariff-quality gas, or “dry gas” • Gas quality specifications designate a maximum moisture vapor content at a level where liquid water will not condense in the pipeline system under normal operating conditions • Natural gas pipelines that transport hydrocarbon liquids and hazardous liquids pipelines typically allow BS&W including liquid water
Sources of Water • Water accidentally introduced into the pipeline • Upsets of liquid water at system inputs from production or storage • High water vapor that allows liquid water to condense under operating conditions • Failures to dehydration equipment can introduce water, water vapor, and glycol, which is hygroscopic • Maintenance pigging and gas flow can move water to unexpected places
Sources of Water • Water intentionally introduced into the pipeline • Hydrotesting (long exposures, water quality, dewatering effectiveness) • Water used to carry chemical treatments • Self-inflicted (cleaning, management of pyrophoric materials, maintenance of dehydration equipment) • Methanol injection to prevent freezing
Testing for water • Product quality monitoring at system inputs • Automated testing at inputs and in flow stream • Liquid sampling (drips, pigging operations, vessels, sample pots) • Testing for increases in water vapor content can identify areas of liquid holdup
Prevention • Facilities design (filter/separators) • Appropriate product quality standards • Product quality enforcement actions • Customer quality assurance valves • Tracing the source and correcting problems • Dehydration and liquid removal • Effective de-watering following hydrotesting
Removing Water • Re-absorption into gas stream • Maintenance pigging • Flow velocity • Line sweeping (increased velocities [but not too high]) • Liquid removal devices such as pipeline drips, filters, separators, slug catchers • If these devices aren’t properly maintained, then you are simply moving the corrosion from the pipeline to the liquid removal device
Removing Water • Conditions that may prevent water removal • Repeated upsets • Biomass • Glycol can absorb water from low levels of water vapor • Low/no flow • Poor design, such as crevices, dead legs and diameter changes • Sediment accumulation
If You Find Water • Determine if it is an upset or persistent condition • Determine the extent of pipeline affected • Remove the water, if practical • Gas and hydrocarbon liquids are not corrosive. Water may not be corrosive; pure condensed water has a very low conductivity • Corrosive constituents in gas and liquids can accelerate corrosion rates
If You Find Water • Perform testing on water to determine corrosivity • Monitor with coupons/probes/other technology to determine if it is corrosive • If the condition is persistent and the water is corrosive, implement a mitigation program • Use chemical analysis to trace possible offenders (e.g. glycol)
Liquid and Solid Sampling • Onsite testing • Test for water • pH • Temperature • Alkalinity • Dissolved H2S • Bacteria culture
Liquid and Solid Sampling • Laboratory testing • Test for water • Compositional analysis • Alkalinity • pH • Conductivity • Salts • Corrosion products • Other tests
Gas sampling • Water vapor • Oxygen • Carbon dioxide • Hydrogen sulfide • Other tests
Internal Corrosion Mitigation • Remove water/corrosive constituents • Chemical treatment (batch or injection) • Internally coat (not a great option without cathodic protection, in many cases) • Cathodic protection (usually not practical except for vessels/tanks) • Material selection (usually not practical)
Internal Corrosion Mitigation • Mitigation systems have to be monitored. For example, for a chemical injection system: • Check pumps periodically to ensure proper operation • Compare specified chemical injection rates with actual chemical consumption • Test the chemical periodically to ensure that you are receiving the proper chemical at the specified concentration • Monitor downstream for residuals to ensure proper distribution of chemical • Monitor with coupons to ensure that the chemical is effective
Measuring Corrosion Rates • In dry gas transmission pipelines, it is difficult to identify areas likely to have measurable corrosion rates, since the presence of water is extremely rare • If likely locations for internal corrosion can be identified, they can be monitored with coupons, probes, ultrasonic thickness measurements, ultrasonic thickness arrays, hydrogen permeation, electrochemical noise, etc. • Advancements in ILI data technologies allow calculation of internal corrosion rates across more significant intervals
Integrity Assessment Trust everyone, but cut the cards. - W. C. Fields
Integrity Assessments • Ultrasonic thickness measurements at key locations • Inspection of internal surface of the pipe when the pipe is open • Repairs • Pig launchers/receivers • Meter tubes • Vessels • Tanks
Integrity Assessments • Inspection for internal corrosion where historical accumulations of liquid water may have occurred: • PHMSA Advisory Bulletin ADB-00-02 • Drips, deadlegs, and sags, fittings and/or "stabbed" connections, operating temperature and pressure, water content, carbon dioxide and hydrogen sulfide content, carbon dioxide partial pressure, presence of oxygen and/or bacteria, and sediment deposits, low spots, sharp bends, sudden diameter changes, and fittings that restrict flow or velocity.
Integrity Assessments • Periodic integrity assessments • ILI • ICDA • Pressure testing • Most effective prediction models for pipelines are incorporated into the ICDA standards (DG-ICDA, LP-ICDA, WG-ICDA)
Integrated programs • An internal corrosion control program is part of integrity management • The internal corrosion control program should prevent internal corrosion from occurring, and give the operator an idea of where and how much internal corrosion may have occurred • Feedback of the results of integrity inspections to the internal corrosion control program is essential to ensure that the program is effective
Summary • An internal corrosion control program consists of many components, including monitoring, prevention, maintenance, mitigation, and integrity assessment. • Each component is necessary to a varying degree depending on the product being carried, operating history, operating conditions, risk, and expected life. • An internal corrosion control program must be tailored to specific pipeline conditions
Summary • The best solution is to keep the water out of the pipe
Enhancing Pipeline Integrity with Early Detection of Internal Corrosion Pipeline Integrity Management Conference March 30th – April 1st 2009, Houston, Texas