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The Distribution of a Hydrocarbon System. K.Potsch, C.Zach, OMV E&P. IEA Workshop and Symposium 2009 Canberra, 21.09.2014. Overview. Problem: How to discribe the „Plus-Fraction“ of a hydrocarbon system Medium and long distributions Chromatograms
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The Distribution of a Hydrocarbon System K.Potsch, C.Zach, OMV E&P IEA Workshop and Symposium 2009 Canberra, 21.09.2014
Overview • Problem: How to discribe the „Plus-Fraction“ of a hydrocarbon system • Medium and long distributions • Chromatograms • Mathematical treatment of distributions • Various examples • Way ahead, summary
Problem = Plus-Fraction • Plus-Fraction = last component
Problem = Plus-Fraction • Plus-Fraction = last component, long distributions
Chromatograms • How to get the scn-distribution
Chromatograms • Tail end
Analytical method 2 GC runs, bridging compound = n-alkane between C10 and C15. Lower boiling components: • Agilent 6890 GC + HP ChemStation • fused silica capillary column (CP Sil 8.25m x 0.32mm, 0.25µm) • carrier gas = He high molecular weight compounds (up to C120) with HTGC • Agilent 6890 GC + AC SimDis Software • Column HP-1 (5m x 0.53mm, 0.09µm film thickness) + programmable temperature vaporizer (PTV injector). • Samples diluted in carbon disulfide.
Mathematical treatment of distributions • G-function [Whitson] Simpler form (x=snc)
Mathematical treatment of distributions • Gaussian log-normal distribution
Mathematical treatment of distributions • Multiple Gaussian log-normal distribution
Individual HCD functions • Turned hyperbola, 3 constant equation
Individual HCD functions • Another 3-constant function, exponential type
Application • Extend the distribution to fulfill • Find functions for r and M • Calculate the pseudo porperties
The End Questions?