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Inclusions in gemstones: Gems in Gems. Egor Gavrilenko Instituto Gemológico Español. Inclusions in gemstones: Gems in Gems. Introduction Types of inclusions Importance of inclusions: In Geology In Gemology Methods of inclusion’s studies The artistic side of inclusions: Photomicrography
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Inclusions in gemstones:Gems in Gems Egor Gavrilenko Instituto Gemológico Español
Inclusions in gemstones:Gems in Gems • Introduction • Types of inclusions • Importance of inclusions: • In Geology • In Gemology • Methods of inclusion’s studies • The artistic side of inclusions: • Photomicrography • Special cuts and jewelry
Introduction • Inclusions: Particles of other minerals or cavities found inside crystals, trapped during crystal’s growth or formed inside after the host mineral formation. • In gemology, are also considered mechanical inclusions (fissures, growth lines, etc.) and color zoning, described together as “internal characteristics” of gems.
Introduction • Negative impact on quality of gemstones (Clarity) • Photos Anthony Cáceres
Types of inclusions: By type of trapped material • Single phase: • Solid • Liquid • Gaseous • Two phases: • Liquid-vapor • Liquid-liquid • Liquid-solid • Solid-gaseous • Three phases… • Multiphase …. • Photo Juan S. Cózar
Types of inclusions: By time of their formation • For solid inclusions • Protogenetic • Syngenetic • Epigenetic • For fluid inclusions • Primary • Secondary • Pseudo-secondary
Applications in Geology • Sequence of mineral formation in mineral deposits • P-T conditions of mineral formation (fluid inclusions study, thermodynamic stability diagrams for syngenetic minerals) • Development of genetic models for mineral deposits (mineralization fluids origin, age, relation with magmatic and tectonic events, etc.).
Importance for Gemology • Aesthetic importance • Importance for gem’s identification • Special collections
Importance for Gemology • Aesthetic importance: • Color of some gems • Special phenomena: • Aventurescence • Chatoyancy • Asterism • Special gemological varieties • Photo Marco Campos Venuti • Photo Marco Campos Venuti
Importance for Gemology • Importance for gem identification: • Type of gem • Natural or synthetic • Treatments • Geographic origin • Photo Juan S. Cózar • Photo José María Alonso • Photo José María Alonso
Methods of inclusions studies • Microscopic observation + photomicrography • Electron microscopy + EDX or WDX (punctual) • X-ray Fluorescence Spectroscopy (global) • Raman Spectroscopy (punctual or global) • FTIR Spectroscopy (punctual or global) • Fluid inclusions microthermometry
Methods of inclusions studies • Microscopic observation + photomicrography • Electron microscopy + EDX or WDX (punctual) • X-ray Fluorescence Spectroscopy (global) • Raman Spectroscopy (punctual or global) • FTIR Spectroscopy (punctual or global) • Fluid inclusions microthermometry
Emeralds from the Urals T = 350-450 oC, P = 2,5-3 kb,8 wt % NaCl H2Oliq - 70-80 vol % CO2liq ~ 5-7 vol % Vapor - 25-30 vol % TmCO2= -56.6-57.2Tmice= -3.8-6.8Tmclatr= 6.2-9.4Th(LV)CO2= 16-29Th(VL)liq 250-330
The artistic side of inclusions • Photomicrography • Special cut gems to highlight the beauty of inclusions • Designer jewelry focused on gems with inclusions
Special cut gems • John Bailey, www.gemstoneartist.com • “The Sword In the Stone” - quartz with single brookite inclusion • John Bailey, www.gemstoneartist.com • Red Hematite flake in Quartz. Flake oriented to give color to the gem. • Richard P. Homer, Gems by Design, Inc., Kent, OH, USA • 30.95 ct. rutilated Quartz with a single natural needle in the center. • AGTA Spectrum Awards Winners 2012 • Honorable Mention, Innovative Faceting • John Bailey, www.gemstoneartist.com • Quartz with phantom planes oriented to reflect as "angel wings" • John Bailey, www.gemstoneartist.com • Oregon Sunstone using copper schiller to highlight concave faceting
Custom made jewelry • Quartzwithtourmalineneedles, cutbyMunsteiner, whitegoldpendantby Laura Márquez • White goldpendantwithquartzwithepidoteinclusions and greentourmalines, by Laura Márquez • White goldpendantwithrutilatedquartz and citrines, by Laura Márquez • Pendantwithrutilatedquartz in whitegold, by Laura Márquez • Goldneclacewithrutilatedquartz, by Xisco Clapés Triviño