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Explore the sonoluminescence phenomenon in water and sulfuric acid, from history to hydrodynamics modeling, chemical reactions, and physical properties, with simulation results and experimental calculations.
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Comparison of sonoluminescence in Water and Sulfuric Acid Kh. Imani, M. Silatani, R. Rezaei-Nasirabad, A. Moshaii, R. Sadighi-Bonabi,
History: • 1934Bath Ultrasound by H. Frenzel &H. Schultes(MBSL) • 1989 F. Gaitan (SBSL) • 2005 F. Flannigan & S. Suslick ( H2SO4)
Why sulfuric acid ? Higher intensity Appearance of line emission in spectrum
Hydrodynamicsmodel: Bubble dynamics: boundary condition of pressureand Van der waals equation of gas:
Mass transfer at the bubble wall: The bubble contents is assumed to be: ( Nobel gas+H2O+ Reaction products ) 14/17
Heat transfer at the bubble wall: Conductivity coefficient : Heat Conduction
Instability conditions of bubble: Diffusion Instability (D-S) Shape Instability (Sh-S) Bjerknes Instability (Bj.thr.)
With regard to computed phase diagrams, we chose the junction point (Pa, R0) of D-S curve with other stability curves
Calculation Experimental • Troia, et. al, Ultrasonic • sonochemistry—13(2006-)278