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THE OZONE LAYER. A. OZONE in the Atmosphere. Tropospheric Ozone = “BAD” Stratosphere Ozone = “GOOD” defense against UV radiation Contains 97% of O3 Essential to life as we know it Mainly formed at Tropics BUT majority is carried to poles by convection currents. B. The Chemistry.
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A. OZONE in the Atmosphere • Tropospheric Ozone = “BAD” • Stratosphere Ozone = “GOOD” • defense against UV radiation • Contains 97% of O3 • Essential to life as we know it • Mainly formed at Tropics BUT majority is carried to poles by convection currents
B. The Chemistry • Formation: • O2 + UV (sunlight) --> O + O (atomic oxygen) • O (atomic) + O2 (molecular) --> O3 (ozone) • Reverse reaction also occurs UV hitting ozone causing it to form O + O2
C. Causes of Ozone Depletion • Major contributors are compounds that release: • Chlorine • Bromine • Flourine • Measurements indicate that over antarctica ozone has decreased about 60% since late 70’s
3. Main Culprits • Chlorofluorocarbons - CFC’s • First made in 1920’s as refrigerants, coolants, aerosol propellants, industrial solvents, foam and insulation products, cans of hair spray • Largest source is leakage from air conditioning • Average resident time in environment = 200 years (100 in stratosphere) • Chlorofluorocarbons are also greenhouse gases • 1970s, Roland & Molina research showed the negative effects of CFCs on stratospheric ozone
CFCs released into atmosphere make there way to atmosphere • Intense UV radiation breaks the CFC molecules apart and releases chlorine atoms • Cl + O3 --> ClO + O2 • ClO also reacts with Ozone and becomes a chain reaction...(ClO + O3 --> Cl + 2O2)
Bromine • 50x more effective then Cl in destroying ozone • Responsible for 20% of problem • Found in Halons (type of CFCs) which are used in fire extinguishers • Methyl bromide used in fumigation and agriculture • Naturally released from phytoplankton and biomass burning
D. Seasonal Effects • In winter months, ClO is concentrated in ice crystals that form in and around the antarctic polar vortex • In early Spring, returning warmth frees the Cl from the ClO where it destroys more Ozone • ClO + O --> Cl + O2 • Ozone Loss is greatest in SPRING • Chlorine acts as catalysts to help break down more O3
E. Health and Environmental Effects • Excess UV in lower atmosphere causes great damage to cells of living organisms • Sunburns and damage to skin • Skin Cancer • Eye cataracts • Weakening Immune System • Mutations in DNA structure • Plant photosynthesis is greatly reduced due to cellular damage • Reduction in crop production • Reduction in phytoplankton and thus effects on food webs • Animals (fish, amphibians) lacking protective fur or scaly skin are also harmed directly
F. Reduction • Most developing countries have already phased out ozone-destroying • Alternatives to CFCs and Halons • Replace Chlorine with Hydrogen • He, Ammonia, propane, & butane can be used as coolant • Use pump sprays vs. Aerosol • Support legislation that reduces destroying products
G. Legislation • The Montreal Protocol in 1987 • Greatest environmental success stories and signed by 146 nations • Proof that global problems can be solved by combination of international cooperation and scientific advances • Require nations to phase out the use of ozone-depleting chemicals (i.e. CFCs) in favor of less harmful alternatives • Since Protocol depleting chemicals have decreased 95%, however, still several nations rely on CFCs
H. Test Tips • Students often confuse issues of Ozone Depletion and Global Climate Change • Mainly because ozone-depleting chemicals are also greenhouse gases • MAKE SURE TO KEEP SEPARATE: • Ozone-depletion DOES NOT CAUSE WARMING... • Increases UV radiation resulting in increased rates of cancer for humans & loss of photosynthetic productivity....