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e -. Barrier. -·. -·. +·. Donor. Bridge. Acceptor 2. Acceptor 1. e -. ·. -·. ·. +·. Radical 1. Donor. Bridge. Radical 2. Acceptor . e -. h 1. h 2. /2-mw. D-B-A 1 -A 2 → D + -B-A 1 - -A 2 → D + -B-A 1 - -A 2 → D + -B-A 1 -A 2 - . /2-mw. h .
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e- Barrier -· -· +· Donor Bridge Acceptor 2 Acceptor 1 e-
· -· · +· Radical 1 Donor Bridge Radical 2 Acceptor e-
h1 h2 /2-mw D-B-A1-A2→ D+-B-A1--A2→ D+-B-A1--A2→ D+-B-A1-A2 - /2-mw h R1-D-A-R2→ R1-D-A-R2→ R1-D+-A--R2 R1-D+-A--R2 Figure 5. Electron transfer pathway (top) and pulse sequence for SCRP gated spin information transfer experiment. . Figure 3. Electron transfer pathway (top) and pulse sequence for “J-Jump” experiment. π/2 8 ns 416 nm 7 ns 480 nm 7 ns π 16ns Time