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Drill

Drill. Draw & name 5 isomers of: C 3 H 5 OF. Test 6 is attached to the Poly website. Complete it & turn it in tomorrow. Aldehydes and Ketones. Aldehydes. Organic compounds with carbonyl groups on the end carbon. Aldehydes. O R-C H. Ketones.

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Drill

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  1. Drill Draw & name 5 isomers of: C3H5OF

  2. Test 6 is attached to the Poly website. Complete it & turn it in tomorrow.

  3. Aldehydes and Ketones

  4. Aldehydes • Organic compounds with carbonyl groups on the end carbon

  5. Aldehydes • O • R-C • H

  6. Ketones • Organic compounds with carbonyl groups within carbon chains

  7. Ketones • O • C • R R

  8. Common Aldehydes

  9. Formaldehyde • O • H-C • H Methanal

  10. Acetaldehyde • O • CH3-C • H Ethanal

  11. Propionaldehyde • O • CH3-CH2-C • H Propanal

  12. Butyraldehyde • O • CH3CH2CH2C • H Butanal

  13. Benzaldehyde • O • C • H Almond Extract

  14. Cinnamaldehyde O

  15. 4-hydroxy-3-methoxy benzaldehyde H3C-O O C HO H Vanillin (Vanilla)

  16. all-trans-retinal H C=O

  17. all-trans-retinol H C-OH H

  18. Draw: acetaldehyde & benzaldehyde

  19. Common Ketones

  20. Acetone • O • CH3-C • CH3 Propanone

  21. Methyl ethyl ketone • O • CH3CH2C • CH3 Butanone

  22. Cyclohexanone O

  23. Benzophenone O C Diphenylmethanone

  24. Muscone O

  25. General Properties

  26. Polarity Alcohols > Aldehydes > Ketones

  27. Solubility in Water Alcohols > Aldehydes > Ketones

  28. Boiling Points Alcohols > Aldehydes > Ketones

  29. Melting Points Alcohols > Aldehydes > Ketones

  30. Oxidation State Acids > Aldehydes > Alcohols > hydrocarbons

  31. Show all the oxidation steps in converting butane to 3-butenoic acid

  32. Energy State Acids < Aldehydes < Alcohols < hydrocarbons

  33. Chm PE Gradient Methane: CH4 > Methanol: CH3OH > Methanal CH2O > Methanoic A: HCOOH

  34. Chm PE Gradient Reduced Compounds > Less reduced compounds > Oxidized compounds

  35. Organic HW Draw & name 3 different aldehydes & 3 ketones that are isomers of the aldehydes.

  36. Determine MP order CH3-CH3 CH3-CH2OH CH3-CHO CH3-COOH

  37. Drill: Draw & name 5 isomers of: C3H9NO

  38. Making Aldehydes & Ketones

  39. Making Aldehydes • Oxidation of primary alcohols

  40. Making Aldehydes • To oxidize alcohols, Hs must be removed from the OH & the adjacent carbon

  41. Making Aldehydes • OH • R-C-H • H ox

  42. Making Aldehydes • OH • R-C-H • H ox

  43. Making Aldehydes • OH O • R-C-H R-C • H H ox

  44. Common Oxidizing Agents Cr2O7-2 MnO4-1

  45. Examples: K2Cr2O7 KMnO4

  46. Making Ketones • Oxidation of secondary alcohols

  47. Making Ketones • OH • R-C-R ox H

  48. Making Ketones • OH O • R-C-R R-C • R ox H

  49. t-Alcohol Ox • OH • R-C-R • R ox

  50. t-Alcohol Ox • OH • R-C-R NR ox R

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