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1. Liquids and SolidsReview Game Honors Chemistry
2. Hydrogen bonding is not important in ice formation
the liquid properties of water
dissolving ammonia to water
liquid CH4
liquid HF
3. For the reaction A + B ? C ?Ho = +30 kJ; ?So = +50 J/K.Therefore the reaction is: spontaneous at all temperatures
nonspontaneous at all temperatures
spontaneous at temperatures less than 600 K
spontaneous at temperatures greater than 600K
spontaneous only at 25oC.
4. Which one of the following statements is incorrect? Dispersion (London) forces are the weakest type of intermolecular interactions
The strong intermolecular attractions in H2O result from hydrogen bonding
The boiling point of H2S is lower than H2O
The boiling point of non-polar substances tends to decrease with increasing molecular weight
None of the above is incorrect
5. A white substance melts with some decomposition at 730oC. As a solid, it is a nonconductor of electricity but it dissolves in water to form a conducting solution. The white substance is: a covalent network solid
an ionic solid
a molecular solid
a metallic solid
solid Ar
6. Drops of water and ethanol are placed on a warm stove, and the ethanol drop is seen to evaporate more rapidly. The graph below includes the vapor pressure of ethanol and water. Which curve corresponds to ethanol? A
B
C
D
none of the above
7. The triple point is: the point in a phase diagram where the solid, liquid, and gas phases of a substance coexist at equilibrium
the point where all three phases are unstable
three places in a phase diagram where the solid, liquid and gas can coexist
a three-dimensional phase diagram
a rare play in baseball
8. What happens to molecules in a liquid when the liquid is heated and vapor starts to form? the intramolecular forces between liquid molecules are disrupted
the intermolecular forces between liquid molecules are disrupted
kinetic energy is removed from the system
London forces become stronger
surface tension increases, which causes beading up, then boiling
9. Calculate ?S0 for the reaction below at 25C. S0 for SiH4 = 204.5 J/molK, for O2(g) = 205.0 J/molK, for SiO2 (s) =41.84 J/molK, for H2O(l) = 69.91 J/molK SiH4 (g) + 2O2(g) ? SiO2(s) + 2H2O(l) -353.5 J/K
- 432.8 J/K
595.0 J/K
-677.0 J/K
-880.3 J/K
10. Which of the following has the strongest intermolecular forces? O2
Ar
CH2
HF
HBr
11. What pressure would be required to liquify (or condense) a sample of water vapor at 500oC? 0.0060 atm
1.00 atm
218 atm
some pressure higher than 218 atm but which cannot be determined from the phase diagram
no amount of pressure can bring about the change of H2O vapor to liquid at 500oC
12. When a liquid vaporizes, all but one of the following changes occur. Which one does NOT occur? Distance between molecules increases
Attractive forces between molecules become less important
Density decreases
Composition of molecules changes
13. Which one of the following quantities would you expect to be largest for a given substance? Heat of vaporization per mole
Heat of fusion per mole
Heat of vaporization per gram
Heat of fusion per gram
14. A solid with a high melting point but no electrical conductivity is: Ionic
Molecular
Metallic
Covalent network
15. As the pressure increases, the melting point of compound X will: decrease and then increase
increase and then decrease
decrease
increase
stay the same
16. Which of the following is NOT characteristic of a metal? High conductivity
High water solubility
Low ionization energy
Forms positive ions
17. Which of the following molecules would NOT show hydrogen bonding? CH3NH2
(CH3) 2NH
CH3CH2NH2
(CH3) 3N
18. What is the specific heat of iron if 45.0g of iron metal at 95.0C are dropped into 200.g of water at 25.0C and the temperature of water rises to 28.0C? 0.199 cal/gC
1.99 J/gC
0.199 kJ/gC
1.99 cal/gC
None of the above
19. Which of the following reactions is likely to have the most positive change in entropy? N2(g) + 3H2(g) ? 2NH3(g)
CaO(s)+CO2(g) ? CaCO3(s)
N2(g)+2O2(g) ? 2NO2 (g)
C(s)+)O2(g) ? CO2(g)
2C(s)+O2(g) ? 2CO(g)
20. The cooling curve below shows how the temperature of a sample varies with time as the sample goes through phase changes. The sample starts as a gas, and heat is removed at a constant rate. At which time does the sample contain the most liquid? t1
t2
t3
t4
t5
21. How much energy is needed to convert 50.0 g of ice at -5.00C to water at 25C? Specific heat (ice) = 2.10 J/(gC) Specific heat (water) = 4.18 J/(gC) Heat of fusion = 333 J/g Heat of vaporization = 2258 J/g 175 J
22.4 kJ
21.9 kJ
37.3 kJ
18.0 J
22. Which of the following statements are false? 1. Liquids with large intermolecular forces tend to have very low boiling points
2. Liquids with large intermolecular forces tend to have considerable surface tension
3. When a substance changes from a solid to a liquid, the molecules remain intact
4. The hardness of diamond is due to strong dipole-dipole attraction
1 and 4
1 and 3
2 and 3
2 and 4
3 and 4
23. Answers D
D
D
B
A
A
B
B
D
E
D
A
D
D
B
D
A
E
D
B
A