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Chapter 22 Notes II. Balancing Redox Reactions. Steps to balancing a Redox reaction:. Lets balance the following equation to show the steps: HNO 3 + I 2 a HIO 3 + NO 2 + H 2 O. 1) Write the oxidation number above each element in the equation. HNO 3 + I 2 a HIO 3 + NO 2 + H 2 O.
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Chapter 22 Notes II Balancing Redox Reactions
Steps to balancing a Redox reaction: Lets balance the following equation to show the steps: HNO3 + I2a HIO3 + NO2 + H2O
1) Write the oxidation number above each element in the equation. HNO3 + I2a HIO3 + NO2 + H2O +1 +5 -2 0 +1 +5 -2+4 -2 +1 -2
2) Draw a line connecting elements whose oxidation numbers change. HNO3 + I2a HIO3 + NO2 + H2O +1 +5 -2 0 +1 +5 -2+4 -2 +1 -2
+1e- -5e- 3) Determine how much the oxidation number changed for each and write this number on the connecting line. HNO3 + I2a HIO3 + NO2 + H2O +1 +5 -2 0 +1 +5 -2+4 -2 +1 -2 The positive in front of the 1 means it is gaining 1 electron and the negative in front of the 5 means it is losing electrons.
x 1 x 2 4) Multiply the number on the connecting line by the highest subscript on the element changing. HNO3 + I2a HIO3 + NO2 + H2O +1e- +1e- +1 +5 -2 0 +1 +5 -2+4 -2 +1 -2 -5e-
x 1 x 2 5) Multiply the top and bottom line by numbers so that the electrons gained equal electrons lost. HNO3 + I2a HIO3 + NO2 + H2O +1e- +1e- +1 +5 -2 0 +1 +5 -2+4 -2 +1 -2 -5e- Right now, the top line multiplies to equal 1 and the bottom line multiplies to equal 10. What is the least common multiple of 1 and 10?
x 1 x 2 5) Multiply the top and bottom line by numbers so that the electrons gained equal electrons lost. HNO3 + I2a HIO3 + NO2 + H2O x 10 +1e- +1e- +1 +5 -2 0 +1 +5 -2+4 -2 +1 -2 10! -5e- x 1 So we’ll need to multiply each line by a number that makes it equal to ten (the two numbers don’t have to be the same).
x 1 x 2 6) Circle the last two numbers on each line. The product represents how many atoms of that element you need on each side. HNO3 + I2a HIO3 + NO2 + H2O x 10 +1e- +1e- =10 +1 +5 -2 0 +1 +5 -2+4 -2 +1 -2 -5e- x 1 =2 So we’ll need 10 nitrogens and 2 iodines on each side of the equation.
x 1 x 2 7) Place the coefficients in the equation which will give you the determined number of atoms. HNO3 + I2a HIO3 + NO2 + H2O x 10 +1e- +1e- =10 +1 +5 -2 0 +1 +5 -2+4 -2 +1 -2 10 2 10 -5e- x 1 =2 Since there is already a two subscript on I2, it gets a one coefficient to bring the total number to two.
8) Check all atoms to see if everything is balanced. If hydrogen and oxygen are both unbalanced, try hydrogen first. HNO3 + I2a HIO3 + NO2 + H2O 10 2 10 4 Make sure not to disturb the ratio of elements oxidized to elements reduced that you just set up!
Balancing the following using the steps: I2 + HClO + H2O a HIO3 + HCl 5 2 5