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Aston University Bioenergy Research Group (BERG) Dr Daniel J. Nowakowski pp. Prof. Anthony V. Bridgwater NEPIC Innovation Day Ramside Hall Hotel – Carrville , County Durham, 15.11.2011 . Objective of BERG.
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Aston University Bioenergy Research Group(BERG)Dr Daniel J. Nowakowski pp. Prof. Anthony V. BridgwaterNEPIC Innovation DayRamsideHall Hotel – Carrville, County Durham, 15.11.2011
Objective of BERG • To apply chemical engineering science and technology to help provide sufficient energy, fuels and chemicals from renewable and sustainable resources for the needs of today and tomorrow.
Achievements * • International leader in thermal biomass conversion research • Funding of more than £22 million • Operational since 1979 • Collaborators in 33 countries • Partners in 14 countries * * * * * * * * * * * * * * * * * * * * * * * *
BERGscope and activities Wood, Energy crops, Residues, Wastes Biomass production & processing Prepare and pretreat Biological conversion Hydrolyse Ferment Thermal conversion Pyrolyse Gasify Processing Upgrade Refine Synthesis Refine Biorefinery Products & Markets Chemicals Biofuels Electricity, Heat System Integrated bioenergy system
Focus • The main focus of our research is fast pyrolysis • This is an advanced thermal process that produces up to 75% wt. liquid (bio-oil) from biomass with some byproduct char and gas • The liquid can be used for: • Power generation in engines and turbines • Heat in boilers and co-firing • Chemicals directly or via upgrading and separation • Energy carrier to reduce handling & storage of biomass • Biofuels by upgrading
5-7 kg/h fast pyrolysis fluid bed Continuous bubbling fluid bed with full computer control Liquid collection by quench and ESP Gas recycle for fluidisation
100 and 300 g/h fluid bed • 4 continuous fluid beds : 100 g/h to 5-7 kg/h • 2 continuous ablative reactors : 4kg/h and ~20kg/h, • Hot vapour filter • Microwave micro-reactor, • Synthesis micro-reactor • TGA and Py-GC-MS/FID
20 kg/h ablative pyrolysis reactor Heat • Biomass in Heat Heat • Char out Heat • Vapoursout
Bio-oil blends with bio-diesel • Results • Three phase chart for blends with bio-butanol • Initial Newtonian behaviour • Long term stability pending
Other facilities Micro-reactors • CDS high pressure and catalystreactor system • Microwave • Pressurised synthesis and upgrading reactor • Autoclave Analysis and characterisation • Extensive facilities for analysis and characterisation of: • feedstocks • intermediates • products
Our contributions to fast pyrolysis • Biomass pretreatment and preparation • Fast pyrolysis in fluid beds (4 units) and ablative (2 units) • Reactor design and modelling • Analytical pyrolysis • Catalytic pyrolysis • Liquid collection and upgrading • Extensive liquid analysis and characterisation facilities • Chemicals recovery and refining • Nitrogenolysis for fertiliserproduction • Biofuel production by Fischer-Tropsch synthesis, zeolites and hydrotreating upgrading of fast pyrolysis products • Technical and economic assessment of bioenergy chains for electricity, biofuels, chemicals, biorefineries
Bioenergy chain Power Heat Biofuels Chemicals Power & heat generation Thermal conversion Combustion, Gasification, Pyrolysis Biomass Preparation & Pretreatment Products Biofuelchain Biofuel production & refining Chemicals production
Biofuel chains Biomass Liquid bio-oil Fast pyrolysis Zeolite cracking Utilities Gasification Syngas Fischer Tropsch synthesis Methanol synthesis Bio-oil Hydro- treating MTG , MOGD, Tigas Mt-Synfuels Refining Gasoline, diesel, kerosene, SNG
Fertilisers Biomass as energy crops or residues Nitrogenolysis to Slow Release Fertiliser Pyrolysis Bio-oil Nitrogen source Gasification External fertiliser applications Ammonia synthesis Fertiliser production Fuel cell Ammonia based hydrogen storage
Esters from bio-oil Distillation product after esterification with WD catalyst Raw bio-oil
SUPERGEN Bioenergy II 8 Newsletter Website Bioenergy Research Forum Showcase 2 Characterisation & Pretreatment 1 Resources Nitrogen 3 Thermal conversion Marine biomass 5 Biofuels & Biorefinery 4 Power & Heat Ammonia 6 Systems analysis 7 Innovation
Process modelling • Processes are being modelled in terms of: • Performance • Capital cost; Product cost • Environment; Socio-economics • Variability is considered in terms of: • Scale • Uncertainty; Learning • Process design; System design • Objectives include: • Impact of pyrolysis as pretreatment method • Process route to hydrocarbons • Integration with refineries • Fertiliser production as Ammonia and Slow release fertiliser
European Bioenergy Research Institute • BERG is a founder member of EBRI – the European Bioenergy Research Institute • EBRI will create a unique platform for the development and implementation of bioenergy systems in local, national and European contexts as well as reaching for International community