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Chemical Energy and Enzymes. All Energy Comes from the Sun.
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All Energy Comes from the Sun http://www.google.com/imgres?imgurl=http://water.me.vccs.edu/concepts/oxcycle.jpg&imgrefurl=http://water.me.vccs.edu/concepts/oxycycle.html&usg=__TWl99eJyOyBSlNL6B6MFXlBUf-c=&h=277&w=354&sz=21&hl=en&start=2&zoom=1&tbnid=epfLkYKHCfE7cM:&tbnh=95&tbnw=121&ei=Pg-DUOGPDej22QWG24GYAg&prev=/search%3Fq%3Dphotosynthesis%2Boxygen%2Brespiration%2Bcarbon%2Bdioxide%26hl%3Den%26gbv%3D2%26tbm%3Disch&itbs=1
Energy can be neither created nor destroyed BUT it can change form! First Law of Thermodynamics
Potential vs. Kinetic Energy • Activity: • Paper drop
Discussion • What are some other examples of potential kinetic energy? • How might we use these in our day-to-day lives? • What are some types of energy (not potential or kinetic)?
Chemical Energy • Activities • “Encouraging” cellulose/glucose breakdown • Chemical energy • Energy of activation • Energy diagram – “happy” state • Exothermic • Endothermic http://www.google.com/imgres?imgurl=http://bioweb.uwlax.edu/bio203/s2012/disrud_sama/templates/photosynthesis1.gif&imgrefurl=http://bioweb.uwlax.edu/bio203/s2012/disrud_sama/nutrition.htm&usg=__8k5LXmT-5KYHFAQa4c7NapVTGxw=&h=248&w=288&sz=16&hl=en&start=42&zoom=1&tbnid=uNmSBJq5mn0rGM:&tbnh=99&tbnw=115&ei=kw-DUOHTHcHq2AW72IC4Bg&prev=/search%3Fq%3Dphotosynthesis%26start%3D40%26hl%3Den%26sa%3DN%26gbv%3D2%26tbm%3Disch&itbs=1 420chopshop.com
Cellulose/Glucose CO2 + H2O gcserevision101.wordpress.com
Glucose 6CO2 + 6H2O Pearson Benjamin Cummins
Sugar Metabolism: The Quickest Route to Cellular Chemical Energy
Cellulose Breakdown for Food Energy en.wikipedia.org turon.com thinnertimes.com
Enzymes catalyze cellulose breakdown engj.org
Enzymes are our cells’ catalysts Pearson Benjamin Cummins g11-bioa-2011-12.wikispaces.com
Catalysts increase the number of activated molecules Glucose 6CO2 + 6H2O Pearson Benjamin Cummins
Enzymes are proteins that Have a particular 3D shape Enzyme active site is where catalysis occurs blobs.org
Garland Scientific As proteins, enzymes are “strings” of many amino acids. Each amino acid has its own physical/chemical properties. All proteins fold to particular shapes; enzymes fold to have active sites of particular shape/size/chemical properties.
Cellular Polymers Are Macromolecules • Biological • Polysaccharides • Cellulose • Amylose, amylopectin • Nucleic acids • DNA • RNA • Proteins • Consider proteins as substrates for proteases
Enzyme Demonstration • Protease activity • Protein in gelatin • Bromelain = protease • Fresh vs. canned pineapple healthyself19.wordpress.com thenakedscientists.com
Let’s Recap… • Chemical energy • Spontaneous reactions are exothermic • Measured by Gibb’s free energy (DG) • Activation energy (“spark” starts cellulose breakdown) • Enzymes lower activation energy • Bromelain protease (pineapple in gelatin) • Active site holds substrate(s) in high energy transition state • Enzymes must be in proper 3D structure to catalyze a reaction
Discussion • What you know: • Jello contains gelatin, a protein (polymer) • Pineapple contains bromelain (a protease) • Some jello contains canned pineapple • Some jello contains fresh pineapple • What happened in the samples w/ fresh pineapple? Why? • What happened in the samples w/ canned pineapple? • Why the difference?
What controls were used? • Why were these controls used? • What comparisons could you make between your controls and your “treated” samples? • What information is useful for your introduction? Methods? • What observations will you describe? • How will you state your conclusions?