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Air Pollution. Chapter 18. Core Case Study: South Asia’s Massive Brown Cloud. Asian Brown Cloud Causes Chemical composition Areas impacted Air pollution connects the world Steps taken in China and India to reduce air pollution. Core Case Study: South Asia’s Massive Brown Cloud. Causes
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Air Pollution Chapter 18
Core Case Study: South Asia’s Massive Brown Cloud • Asian Brown Cloud • Causes • Chemical composition • Areas impacted • Air pollution connects the world • Steps taken in China and India to reduce air pollution
Core Case Study: South Asia’s Massive Brown Cloud • Causes • Drought • Clearing of forests • Chemical composition • Dust, smoke, ash • Acidic compounds, soot, toxic metals • Fly ash from burning fossil fuels
Core Case Study: South Asia’s Massive Brown Cloud Areas impacted • Does not stay put • Northern China to Seoul South Korea across the Pacific to the United States
Core Case Study: South Asia’s Massive Brown Cloud • Beneath the cloud • Photosynthesis reduced by ~7% • Cooling Effect • Above the cloud • Warming
18-1 What Is the Nature of the Atmosphere? • Concept 18-1 The atmosphere is structured in layers, including the troposphere, which supports life, and the stratosphere, which contains the protective ozone layer.
The Atmosphere Consists of Several Layers • Atmosphere varies in • Density • Atmospheric pressure
Air Movements in the Troposphere Play a Key Role in Earth’s Weather and Climate • Troposphere • 75–80% of the earth’s air mass • Closet to the earth's surface • Chemical composition of air • Rising and falling air currents: weather and climate • Involved in chemical cycling
The Stratosphere Is Our Global Sunscreen • Stratosphere • Similar composition to the troposphere, with 2 exceptions • Much less water • O3, ozone layer, filters UV • Formation • Location
Atmospheric pressure (millibars) 1,000 200 0 400 600 800 120 75 Temperature 110 65 Thermosphere 100 90 55 Mesopause 80 Mesosphere 45 70 Altitude (kilometers) Altitude (miles) 60 Stratopause 35 50 Stratosphere 40 25 30 Tropopause 15 Ozone layer 20 10 Pressure Troposphere 5 (Sea level) 0 Pressure = 1,000 millibars at ground level –80 80 40 120 –40 0 Temperature (˚C) Fig. 18-3, p. 470
Section 18-2 What are the Major Outdoor Air Pollution Problems?
18-2 What Are the Major Outdoor Pollution Problems? • Concept 18-2 Pollutants mix in the air to form industrial smog, mostly the result of burning coal, and photochemical smog, caused by motor vehicle, industrial, and power plant emissions.
Air Pollution Comes from Natural and Human Sources (1) • Air pollution • Natural sources • Dust blown by wind • Pollutants from wildfires and volcanoes • Volatile organics released by plants • Withdrawing groundwater
Air Pollution Comes from Natural and Human Sources (2) • Human sources: mostly in industrialized and/or urban areas • Stationary sources • Mobile sources
Case Study: Air Pollution in the Past: The Bad Old Days • Discovery of fire • Middle Ages • Burning of wood • Industrial Revolution • Burning of fossil fuels
Case Study: Air Pollution in the Past: The Bad Old Days • London, England • 1850s • 1880 2200 killed • 1911 1100 killed • 1952: yellow fog; 4,000-12,000 killed
Case Study: Air Pollution in the Past: The Bad Old Days • United States • 1948: Donora, PA; first U.S. air pollution disaster – 6, 000 sick, 20 dead • 1963: New York City • Killed 300 • Global problem
Some Pollutants in the Atmosphere Combine to Form Other Pollutants • Primary pollutants • Secondary pollutants • Air quality improving in developed countries • Air pollution control laws • Much more needs to be done in developing countries • Indoor pollution: big threat to the poor
What Are the Major Outdoor Air Pollutants? • Carbon oxides • Carbon monoxide (CO) • Carbon dioxide (CO2) • Sources • Human health and environmental impact
What Are the Major Outdoor Air Pollutants? • Nitrogen oxides (NO) and nitric acid (HNO3) • Sources • Acid deposition • Photochemical smog • Human health and environmental impact • Sulfur dioxide (SO2) and sulfuric acid (H2SO4) • Sources • Human health and environmental impact
What Are the Major Outdoor Air Pollutants? • Particulates • Suspended particulate matter (SPM) • Fine • Ultrafine • Sources • Human health and environmental impact
What Are the Major Outdoor Air Pollutants? • Ozone (O3) • Sources • Human and environmental impact • Volatile organic compounds (VOCs) • Hydrocarbons and terpenes • Sources • Human and environmental impact
Statue Corroded by Acid Deposition and Other Forms of Air Pollution, RI, U.S.
Burning Coal Produces Industrial Smog • Chemical composition of industrial smog • Reduction of this smog in urban cities of the United States • China and smog • Human deaths
How Pollutants Are Formed from Burning Coal and Oil, Leading to Industrial Smog
Sunlight Plus Cars Equals Photochemical Smog • Photochemical Smog • Chemical composition • Sources • VOCs + NO2 + Heat + Sunlight yields • Ground level O3 and other photochemical oxidants • Aldehydes • Other secondary pollutants • Human health and environmental impact
A Model of How Pollutants That Make Up Photochemicals Are Formed
Several Factors Can Decrease or Increase Outdoor Air Pollution • Outdoor air pollution may be decreased by • Settling of particles due to gravity • Rain and snow • Salty sea spray from the ocean • Winds • Chemical reactions
Several Factors Can Decrease or Increase Outdoor Air Pollution (2) • Outdoor air pollution may be increased by • Urban buildings • Hills and mountains • High temperatures • Emissions of VOCs from certain trees and plants • Grasshopper effect • Temperature inversions
18-3 What Is Acid Deposition and Why Is It a Problem? • Concept 18-3 Acid deposition is caused mainly by coal-burning power plant and motor vehicle emissions, and in some regions, threatens human health, aquatic life and ecosystems, forests, and human-built structures.