Chemical Reaction Engineering

1. Chemical Reaction Engineering Chapter 3, Part 2: Reaction Stoichiometry: Batch

2. Why Stoichiometry? • If we have • Then we can size a number of CSTR and PFR reaction systems • To find -rA= f(X) • Need the rate law, -rA=f(CA, CB) • Need the reaction stoichiometry, CA=CA0(1-X) [Liquid Phase] X !!

3. Batch Stoichiometric Table Species Symbol Initial Change Remaining A A ____________ ________

4. Batch Stoichiometric Table Species Symbol Initial Change Remaining A A B B ____________ ________

5. Batch Stoichiometric Table Species Symbol Initial Change Remaining A A B B C C ____________ ________

6. Batch Stoichiometric Table Species Symbol Initial Change Remaining A A B B C C D D ____________ ________

7. Batch Stoichiometric Table Species Symbol Initial Change Remaining A A B B C C D D Inert I ------- ____________ ________

8. Batch Stoichiometric Table Species Symbol Initial Change Remaining A A B B C C D D Inert I ------- ____________ ________

9. Batch Stoichiometric Table Species Symbol Initial Change Remaining A A B B C C D D Inert I ------- ____________ ________ and where

10. Concentration: Batch Systems Constant Volume Batch:

11. Concentration: Batch Systems Constant Volume Batch: Note:              if the reaction occurs in the liquid phase                                                or       if a gas phase reaction occurs in a rigid (e.g., steel) batch reactor Then

12. Concentration: Batch Systems Constant Volume Batch: Note:              if the reaction occurs in the liquid phase                                                or       if a gas phase reaction occurs in a rigid (e.g., steel) batch reactor Then etc.

13. Concentration: Batch Systems Constant Volume Batch: Note:              if the reaction occurs in the liquid phase                                                or       if a gas phase reaction occurs in a rigid (e.g., steel) batch reactor Then etc. If then And we have –rA=f(X)