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Periodic Table Trends. Tips when comparing elements. When you are looking at different elements in the same period , the difference between them has to do with the attraction of valence electrons to the nucleus
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Tips when comparing elements • When you are looking at different elements in the same period, the difference between them has to do with the attraction of valence electrons to the nucleus • When you are looking at different elements in the same family/group, the difference between them has to do with the number of orbitals
Key Trends-Valence Electrons • The greater number of valence electrons, the stronger the attraction between the electrons and the nucleus • The lower the number of valence electrons, the weaker the attraction between the electrons and the nucleus
Key Trends-Orbitals • The greater the number of orbitals, the weaker the attraction between it and the nucleus • The lower the number of orbitals, the stronger the attraction between it and the nucleus
Review • More valence electrons→ more attraction to nucleus • Less valence electrons → less attraction to the nucleus • More electron orbitals → less attraction to the nucleus • Less electron orbitals → more attraction to nucleus
Periodic Table Trends • Patterns re-appear in the periodic table, from one period to the next! • Trends either go : • From high at the beginning of the period to low at the end of the period • From low at the beginning of the period to high at the end of the period • Four mains trends • Atomic Radius • Reactivity • Ionization • Electronegativity
Electronegtivity Electronegtivity
Atomic Radius • Definition: Distance between the nucleus and the outermost energy level • As one goes from the left of the table to the right, the net positive charge from the nucleus increases • More protons are in the nucleus • The radius therefore is biggest on the left and smallest on the right • This leads to electrons being attracted more to the nucleus, and reducing the radius • As one goes down a period, the atomic radius increases with the addition of more electron shells
Smallest Radius Biggest Radius
Metallic Reactivity • Metallic reactivity decreases as go left to right • More valence electrons lead to greater attraction to nucleus, reducing metallic reactivity • Metallic reactivity increases as go down the periods • Metals donate electrons to gain full octet, therefore the further the valence shell is from the nucleus, the easier it looses its electrons
Least Metallic Character Most Metallic Character
Non-Metallic Reactivity • Non-Metallic reactivity increases as go left to right • More valence electrons lead to greater attraction to nucleus, increasing non-metallic reactivity • The will to fill complete shell by adding electrons is greater • Metallic reactivity decreases as go down the periods • Less orbitals you have, closer the electrons are to the nucleus, creating the stronger pull to accept missing electrons to complete orbital
Most Non-Metallic Character Least Non-Metallic Character
Ionization energy • Def: Energy required to remove an electron from an atom • I.E activity increases as go left to right • Greater net positive charge in nucleus creating a stronger pull, resulting in it being harder to separate • I.E. activity decreases as go down the periods • More orbitals, resulting in less attraction between valence electrons and nucleus, making it easier to separate
Highest ionization energy Lowest ionization energy
Electronegativity • Def: Energy with which an atom holds on to its electrons • Electroneg. increases as go left to right • Greater net positive charge in nucleus creating a stronger pull, resulting in smaller atom radius holding on to electrons more • Electroneg. decreases as go down the periods • More orbitals, resulting in less attraction between valence electrons and nucleus, resulting in less hold on electrons
Electronegtivity Highest electronegtivity Electronegtivity Lowest electronegtivity