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HBr , V(m+i), i = 4-8,10 https://notendur.hi.is/~ agust/rannsoknir/Crete/PPT-131205x

HBr , V(m+i), i = 4-8,10 https://notendur.hi.is/~ agust/rannsoknir/Crete/PPT-131205.pptx. Potential curve diagram for HBr and HBr + ( See next slide ):. [ (3) 2 P ] .. superexcited state. H + + Br +e. H * + Br. HBr + *(A). [B 2 S + ] .. superexcited state. H+ Br + + e. H + Br **.

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HBr , V(m+i), i = 4-8,10 https://notendur.hi.is/~ agust/rannsoknir/Crete/PPT-131205x

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  1. HBr, V(m+i), i = 4-8,10 https://notendur.hi.is/~agust/rannsoknir/Crete/PPT-131205.pptx Potentialcurve diagram for HBr and HBr+ (Seenextslide):

  2. [(3)2P] ..superexcitedstate H++Br+e H*+Br HBr+*(A) [B2S+] ..superexcitedstate H+Br+ + e H + Br** v+=14 v+=12 H+ + Br- HBr+*(X(1/2)) H*(n=2)+Br HBr+(X(3/2)) [4P,5s] Rydb. H + Br**(5s) H V F E Photoexcitationvia V(m+7) https://notendur.hi.is/~agust/rannsoknir/Crete/PXP-131203.pxp

  3. Bycomparing 3hnenergies and v+energies for theHBr+(3/2) and HBr+*(1/2) statesthemaximum acessable v+levels (v+max) canbedetermined, -and comparedwiththeexperimentallyobservedv+max (for HBr+(3/2)) (seenextslides and summary in slide 10)

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  7. a: uncertainduetopeakoverlaps ERGO: Theobserved v+maxpeaksarethemaximum accessable v+levels in theHBr +(3/2) state Thepredictedv+max´s for HBr+*(1/2) correspondto „intensityenhanced“ spectralpeaks.

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