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Bellringer 9/20. How many protons does mercury have? Electrons? Neutrons? Which subatomic particle determines the kind of element? Which subatomic particles determine a element’s chemical properties? What are valence electrons?. Bellringer 9/21. What is a saturated solution?
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Bellringer 9/20 • How many protons does mercury have? Electrons? Neutrons? • Which subatomic particle determines the kind of element? • Which subatomic particles determine a element’s chemical properties? • What are valence electrons?
Bellringer 9/21 • What is a saturated solution? • How are unsaturated solutions different from supersaturated solutions? • What are 3 ways to speed up the rate of dissolving a solute in a solvent?
Core Concepts 1&2Solutions • A homogeneous mixture of two or more substances. • Can be separated by physical means. • Can occur in the solid, liquid, or gas phase. • Solute – the part of the solution that is dissolved and usually present in the lesser amount. (salt-solute, water-solvent) • Solvent – the part of the solution doing the dissolving and usually present in the greater amount.
Solutions are classified as unsaturated, saturated, and supersaturated. • A saturate solution has the maximum dissolved solute for the amount of solvent used at a specific temperature and pressure. • Electrolyte – an aqueous solution that conducts electricity. Pure water does not conduct electricity well.
Aqueous solution – solution where water is the solvent. Water is a polar solvent. That means it is a molecule which has a (+) and (-) side. • Like dissolves like – This means that a solute will dissolve best in a solvent that has the same or similar polarity. • Solubility and Temperature Gizmo | ExploreLearning
Factors that affect dissolving rate • Surface area – greater surface area dissolves faster. • Higher temperatures dissolve faster because the particles move faster. • Stirring dissolve faster because the particles spread out faster in the solvent. Pg 238 1 - 5
Bellringer 9/22 • Why does stirring increase the dissolving rate of a solute in a solvent? • Why does heating increase the dissolving rate of a solute in a solvent? • Why does increasing surface area of a solute increase the dissolving rate? List one way to increase the surface area of a solute.
Solutions • Concentration – the quantity of solute dissolved in a certain amount of solvent. Concentrated has a large amount of solute – diluted has a small amount. • Concentration is expressed as molarity or moles per liter of solution.
Bellringer 9/23 A solution of sodium sulfide (Na2S) has a solubility of 26.3g/100g of H2O at 200C. • What is this solution know as? • About how much sodium sulfide would be needed for the solution to be unsaturated? • About how much would be need to be supersaturated? • If the temperature was raised to 600C, would you expect more or less than 26.3g to dissolve in the 100g of water?
Ionic and Covalent Bonding • Bonded atoms form many kinds of substance. Example: sodium (Na) and chlorine (Cl) bond to form NaCl (table salt). • Atoms bond when their valence electrons interact. • Atoms join to form bonds so that each atom has a stable electron configuration like those of the Noble Gases.
Ionic Bonding • Formed between oppositely charged ions. • An ion is a charged atom with either more or less electrons than protons. • Formed by the transfer of electrons. Example: sodium (Na) transfers its one valence electron to chlorine (Cl) so that Na now has 8 outer level electrons and Cl with 7 before the transfer, has 8 outer electrons. Na is now positive (+) or cation, and Cl negative (-) anion.
Calcium can combine with chlorine to form calcium chloride. Calcium (Ca+2) has 2 valence electrons and so it takes 2 chlorine ions (Cl-) to balance with it. Cl- + Ca+2 + Cl- The chemical formula is CaCl2. • Electron dot diagrams. • Electron Dot Diagram – YouTube Draw electron dot diagrams for the following elements: Na, Ca, O, F, Ne, Kr, Al, and N. Will they be cations or anions?
Writing formulas for Ionic Compounds What is the chemical formula for aluminum fluoride? Look up symbol for aluminum ion: Al+3 Look up symbol for fluoride ion: F- Al+3 F- It will take 3(-) to balance with +3 or 3F to balance with 1 Al. AlF3
Write the chemical formula for the following: • Iron (II) Iodide (hint: the roman numeral indicates the cation’s charge) • Potassium Nitrate • Aluminum Chloride • Magnesium Oxide • Lithium Sulfide • Titanium (IV) oxide
Dot Diagrams of Selected Elements Formulas Lesson 3: Transition Metals Part 1 – YouTube Formulas Lesson 4: Transition Metals Part 2 - YouTube
Polyatomic ions • Ions made up of 2 or more atoms. • They act the same as elemental ions. Example: (NH4)+ is the ammonium ion. (NO3)- is the nitrate ion. Since one is + and the other is (-) then ammonium nitrate’s chemical formula is NH4NO3 • Anions end in –ite or –ate for most of them.
.Polyatomic Ion Charge = +1ammonium - NH4+ Polyatomic Ion Charge = -2carbonate - CO32-chromate - CrO42-dichromate - Cr2O72-hydrogen phosphate - HPO42-peroxide - O22-sulfate - SO42-sulfite - SO32-thiosulfate - S2O32- Polyatomic Ion Charge = -1 acetate - C2H3O2-bicarbonate (or hydrogen carbonate) - HCO3-bisulfate (or hydrogen sulfate) - HSO4-chlorate - ClO3-chlorite - ClO2-cyanate - OCN-cyanide - CN-dihydrogen phosphate - H2PO4-hydroxide - OH-nitrate - NO3-nitrite - NO2-perchlorate - ClO4-permanganate - MnO4-thiocyanate - SCN- Polyatomic Ion Charge = -3borate - BO33-phosphate - PO43-
Using the chart to write chemical formulas. Example: What is the chemical formula for sodium hydroxide? Na+ is paired with (OH)-. Since they both have a single charge then combine them and drop the signs. NaOH Example: ammonium sulfate? Ammonium is (NH4)+ and sulfate is (SO4)-2. It takes 2 (NH4)+ to pair with one (SO4)-2. The formula is (NH4)2SO4. Notice that there are 2N and 2H4 so counting atoms there are
(NH4)2SO4 8 – hydrogen (H) atoms 2 – nitrogen (N) atoms 1 – sulfur (S) atom 4 – oxygen (O) atoms Naming and Formulas of SOME Polyatomic Ions: Chemistry Lesson - YouTube
Write the chemical formulas for the following: Use the chart on page 158 and the periodic table. • hydrogen phosphate • hydrogen carbonate • Potassium hydroxide • Calcium chlorate • Calcium carbonate • Sodium phosphate • Sodium cyanide • Aluminum sulfate
Chemical Reactions • Chemical reactions change substances. • Reactants – the substances that are used in the chemical reactions. • Products – the new substances formed from the reactants in the chemical reactions. • Endothermic reaction – reactions that absorb energy during the reaction. (Cold packs) • Exothermic reaction – reaction that releases energy during the reaction. (heat packs)
Classifying Reactions • Synthesis reactions – reactions where two or more substances combine to form a new compound. 2Na + Cl2 2NaCl (notice that 2 Na on both sides of arrow and 2 Cl also) • Decomposition reaction – a reaction where a compound breaks apart into 2 or more substances. 2H20 2H2 + 02
Chemical Reactions • Combustion reaction – The oxidation reaction of an organic compound in which heat is released. 2CH4 + 4O2 2CO2 + 4H2O Methane gas reacting with oxygen producing carbon dioxide and water.
Chemical reactions • Single-displacement reaction – A reaction in which one element or radical takes the place of another element or radical in a compound. 3CuCl2 + 2Al 2AlCl3 + 3Cu Copper is replaced with aluminum A more reactive element takes the place of a less reactive one. A radical is an organic group that has one or more electrons available for bonding.
Chemical reactions • Double-displacement reactions – a reaction in which a gas, a solid precipitate, or a molecular compound forms from an apparent exchange of atoms or ions between two compounds. Pb(NO3)2 + K2CrO4 PbCrO4 + 2KNO3 Lead nitrate reacting with potassium chromate to produce lead chromate and potassium nitrate.
Chemical Reactions • Oxidation-reduction reaction – any chemical change in which one species is oxidized (loses electrons) and another species in reduced (gains electrons). Referred to as redox reaction. Respiration (breathing) is a redox reaction. Oxygen gas reacts with carbon compounds to form carbon dioxide. Carbon atoms in CO2 are oxidized (lose electrons) and Oxygen atoms are reduced (gain electrons). Elements_of_Chemistry__Compounds_and_Reactions.asf
Classify the following reactions • La2O3 + H2O La(OH)3 • NH4NO3 N2O + H2O • C3H8 + O2 CO2 + H2O • Mg + HCl MgCl2 + H2 • Mg(OH)2 + HCl MgCl2 + H2O Put yes behind those equations that are balanced.
Bell RingerIdentify the following reactions 1. CaSO4+ Mg(OH)2 --> Ca(OH)2 + MgSO4 2. Cl2O5 Cl2 + O2 3. Al + Fe2O3 Al2 O3 + Fe 4. H2+ N2 NH3 Synthesis Decomposition Single-displacement Double replacement
Balancing Chemical Equations Mg + HCl MgCl2 + H2 Is this equation balanced? No since there are 2 Hs and 2 Cls on the right side and only one each on the left side. Suppose we put a 2 in front of HCl. Mg + 2HCl MgCl2 + H2 Is it now balanced?
Balance these equations 1) ____ N2 + ____ H2 ____ NH3 2) ____ KClO3 ____ KCl + ____ O2 3) ____ NaCl + ____ F2 ____ NaF + ____ Cl2 4) ____ H2 + ____ O2 ____ H2O 5) ____ Pb(OH)2 + ____ HCl ____ H2O + ____ PbCl2 6) ____ AlBr3 + ____ K2SO4 ____ KBr + ____ Al2(SO4)3 7) ____ CH4 + ____ O2 ____ CO2 + ____ H2O 8) ____ C3H8 + ____ O2 ____ CO2 + ____ H2O
Check your work 1) 1 N2 + 3 H22 NH3 2) 2 KClO32KCl + 3 O2 3) 2NaCl + 1 F22NaF + 1 Cl2 4) 2 H2 + 1 O22 H2O 5) 1Pb(OH)2 + 2HCl2 H2O + 1 PbCl2 6) 2 AlBr3 + 3 K2SO46KBr + 1 Al2(SO4)3 7) 1 CH4 + 2 O21 CO2 + 2 H2O 8) 1 C3H8 + 5 O23 CO2 + 4 H2O