380 likes | 480 Views
CAP publications. Th er mal Oxi dat ion. Destroys VOC with the three T's of combustion: Time Temperature Turbulence Achieves 75-99% reduction in the emissions entering the device. Direct Flame vs. Catalytic. Capital Costs Operating Cost (auxiliary fuel) Operating Temperature.
E N D
Thermal Oxidation • Destroys VOC with the three T's of combustion: • Time • Temperature • Turbulence • Achieves 75-99% reduction in the • emissions entering the device
Direct Flame vs. Catalytic • Capital Costs • Operating Cost (auxiliary fuel) • Operating Temperature
Slow Catalyst Poisons Iron Tin Silicon I bought the equipment. Why does it still smell? Reversible Catalyst Inhibitors Fast Acting Catalyst Poisons Halogens Sulfur Zinc Phosphorous Lead Arsenic Antimony Mercury Bismuth
Thermal Aging - Heat Cycles Cause the Metal to Recrystallize in an Ineffective Form Burnout - Excessive Heat "Boils" the Metal off the Substrate Gumming - Surface Area is Covered by Heavy Organics From Paint or Fuel Oil Catalysts are Subject to:
Auxiliary Fuel Flow Gas Flow from Booth to Stack Outlet Temp. Higher than Inlet Temp. Inlet VOC Concentration Higher than Outlet VOC Concentration Bypass Stack Emissions Check Incinerators For:
Carbon Adsorption Electromagnetically attracts VOC onto activated carbon Achieves 40 to 65% reduction
Data Collection Requirements grams of VOC/ltr of coating Auto Ref grams of VOC / gram of solids applied Wood finishing Reactivity based rule Aerosols Architectural (planned)
Cup Liners • Two manufacturers • Disposable • Save gun cleaning emissions (1.5 Pints reduced to 2 ozs) • Not yet required by anyone.
Specific Low ROC Limits for: Group I Vehicle Coatings Group II Vehicle Coatings Automotive Requirements
Passenger Cars, Light and Medium Sized Trucks and Vans, Large/Heavy Duty Truck Cabs and Chassis, and Motorcycles Group I Vehicles Means
Public Transit Buses and Mobile Equipment Group II Vehicles Means:
Specific District Approval Required for "Extreme Performance" Exemption Spray Equipment Must be Cleaned in an Enclosed System ROC Contaminated Waste Stored in Closed Containers Automotive Requirements
Districts With Auto Refinishing Rules Bay Area AQMD 8-45 Santa Barbara Co. APCD 339 South Coast AQMD 1151 San Joaquin Unified APCD 4602 Yolo-Solano 2.26 Placer 234 Sacramento 459 (p300-1)
Final ROC Limits for Group II Coatings WhereColor Match is not Required Coating ROC (gm/ltr (lb/gal)) Pretreatment Wash Primers 780 (6.5)Precoat 600 (6.0)Primer 250 (2.1)TopCoat 420 (3.5)Metallic TopCoat 420 (3.5)Extreme Performance 420 (3.5)Camouflage 420 (3.5)
Final ROC Limits for Group I Coatingsand Group II Color Matches ROC SCAQMDCoating gm/ltr (lb/gal) 1998 Pretreatment Wash Primers 780 (6.5)Precoat 600 (5.0)Primer/ Primer Surfacer 250 (2.1)Primer Sealer 420 (3.5) 250TopCoat 420 (3.5) 340Metallic TopCoat 520 (4.3) 340Multi stage 540 (5.4) 340
Air Toxic Control Measure Adopted in 2002 to remove Cr6 and Cadmium from all formulations
For information on Waterborne solutions: Waterweb: http:/www.waterweb.com or call (602) 948-3555
Federal MACT due in 2000 Alternative Control Techniques Document available April 1994 EPA 453/R-94-031
Federal Register: September 11, 1998 (Volume 63, Number 176) Page 48806-48819 Federal Register Online via GPO [wais.access.gpo.gov] [DOCID:fr11se98-23] ----------------------------------------------------------------------- ENVIRONMENTAL PROTECTION AGENCY 40 CFR Parts 9 and 59 National Volatile Organic Compound Emission Standards for Automobile Refinish EPA Final rule. ----------------------------------------------------------------------- SUMMARY: pursuant to section 183(e) of the Clean Air Act (Act) The final rule is estimated to reduce VOC emissions by 31,900 tpy EFFECTIVE DATE: The effective date is September 11, 1998. Federal VOC Rule Table 1.--VOC Content Standards for Automobile Refinish Coatings ------------------------------------------------------------------------ VOC Content Coating category grams/liter (pounds/gallon) ------------------------------------------------------------------------ Pretreatment Wash Primer................................... 780 (6.5) Primer/Primer Surfacer..................................... 580 (4.8) Primer Sealer.............................................. 550 (4.6) Single/2-Stage Topcoats.................................... 600 (5.0) Topcoats of 3 or more stages............................... 630 (5.2) Multi-colored topcoats..................................... 680 (5.7) Specialty Coatings ......................................... 840 (7.0) ------------------------------------------------------------------------
Squeegee Prime by Sherwin-Williams http://www.sherwin-automotive.com/products/ppt/squeegeePrime/index_files/frame.htm
Henry V on Air Pollution Control Here, at the turn of the century, air control is entering a new time.. Years from now your young colleagues will ask about oh- nine That time before things were so clear. As you speak, they will lean forward, straining to hear. You’ll tell them how things wound up this way. And they will hold their careers as cheap, those who were not here, To fight with us this day.
Flip/flop an angle sensitive characteristic of metallic coatings and a color match challenge
Clearcoat: • A Colorless Binder Strong Enough to Serve as a Topcoat Without the Reinforcement of a Pigment Providing a Wet Look to an Earlier Colorcoat • Today More Than 60% of Factory Finishes are Color/Clear (p200-20)
Advantages of Color/Clear Technology • Maximum Luster and Strength • Clearcoat Now Available in Low VOC Water-Borne Formulation