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MATERIALE PE BAZA DE POLIMERI AROMATICI CU CICLURI CONDENSATE

MATERIALE PE BAZA DE POLIMERI AROMATICI CU CICLURI CONDENSATE PENTRU APLICATII IN NANOTEHNOLOGII ELECTRONICE SI OPTOELECTRONICE. DIRECTOR PROIECT : DR. MARIANA-DANA DAMACEANU. Program PN II RESURSE UMANE proiecte de cercetare pentru stimularea constituirii de

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MATERIALE PE BAZA DE POLIMERI AROMATICI CU CICLURI CONDENSATE

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  1. MATERIALE PE BAZA DE POLIMERI AROMATICI CU CICLURI CONDENSATE PENTRU APLICATII IN NANOTEHNOLOGII ELECTRONICE SI OPTOELECTRONICE DIRECTOR PROIECT: DR. MARIANA-DANA DAMACEANU

  2. Program PN II RESURSE UMANE proiecte de cercetare pentru stimularea constituirii de tinere echipe de cercetare independente Contractnr. 31 / PNII_RU - TE_221 / 10.08.2010 Titlulproiectului: Materiale pe baza de polimeri aromatici cu cicluri condensate pentru aplicatii in nanotehnologii electronice si optoelectronice Autoritateacontractanta: Unitatea Executiva pentru Finantarea Invatamantului Superior si a Cercetarii Stiintifice Universitare Contractor: Institutul de ChimieMacromolecularaPetruPoni Iasi Valoarea contractului: 578312 RON Durataproiectului: 2010 – 2013 (36 luni)

  3. ECHIPA DE CERCETARE • Dr. Mariana-Dana DAMACEANU • damaceanu@icmpp.ro • Dr.Andreea Irina COSUTCHI • cosutchi.irina@icmpp.ro • Drd.Radu-Dan RUSU • radu.rusu@icmpp.ro • Drd.Stefan CHISCA • stefan.chisca@icmpp.ro • Drd. Paul-Catalin CONSTANTIN • constantin.catalin@icmpp.ro

  4. REZUMATUL PROIECTULUI • Proiectul are drept obiectiv principal formarea unei echipe tinere de cercetare in domeniul materialelor pe baza de polimeri aromatici cu cicluri condensate, incadrandu-se, conform PC7 al UE, in aria tematica S&T, prioritatea nr. 4: <Nanostiinte si nanotehnologii, materiale si noi procese de productie> • Ideea de baza a proiectului este designul unor polimeri care sa posede o combinatie optima de cicluri aromatice cu caracter electronodonor si electronoacceptor in aceeasi unitate structurala a polimerului, pentru a asigura un transport eficient de sarcini electrice, si, drept urmare, un set de proprietati electronice si optoelectronice necesare unor aplicatii ulterioare in nanotehnologii • Polimerii vor fi astfel proiectati incat sa posede solubilitate si prelucrabilitate satisfacatoare, proprietati termice, fizico-mecanice, optice si electrice superioare polimerilor conventionali • Se vor selecta acei polimeri care au combinatia optima de proprietati si prelucrabilitate pentru a experimenta utilizarea lor in dispozitive electronice ca OLED-uri si OFET-uri • Termenicheie: materiale polimerice proprietati dielectrice, semiconductoare filme nanometrice polimeri inalt performanti nanotehnologii electronice

  5. OBIECTIVE GENERALE • Initierea unor activitati de cercetare complexe avand ca scop dezvoltarea unor noi materiale polimere pentru aplicatii in nanotehnologii electronice si optoelectronice, care sa contina in lantul principal atat segmente aromatice rigide, cu cicluri condensate, cat si segmente flexibile • Ideea centrala a proiectului este descoperirea combinatiei optime de unitati aromatice sau heteroaromatice cu caracter electronodonor si electronoacceptor in aceeasi unitate structurala a polimerului, astfel incat sa se asigure un transport eficient de sarcini electrice si, ca urmare, proprietati electronice si optoelectronice semnificative pentru viitoare aplicatii de inalta performanta • Activitati de formare a resursei umane prin abordarea simultana a elementelor stiintifice cu cele de formare si specializare a resurselor umane

  6. BUGETULPROIECTULUI

  7. ETAPA 1 august – decembrie 2010

  8. ETAPA 1. august - decembrie 2010 • OBIECTIVE REALIZATE • Sinteza, caracterizarea si identificarea structurala a unor monomeri de tip diamina si dianhidrida • Sinteza poliimidelor cu cicluri naftalenice prin reactii de policondensare • Identificarea structurala si evaluarea proprietatilor polinaftalen-imidelor sub forma de pulbere sau solutie • Sustinerea si promovarea activitatilor si rezultatelor

  9. ETAPA 1. august - decembrie 2010 • REPARTIZAREACHELTUIELILOR

  10. ETAPA 1. august - decembrie 2010 • VALORIFICAREAREZULTATELOR • 3 lucrari publicate sau acceptate • 2 lucrari publicate in volume de manifestari stiintifice • 6 lucrari prezentate la manifestari stiintifice • 3 conferinte prezentate in seminarii la institutii din strainatate

  11. ETAPA 1. august - decembrie 2010 • Lucrari publicate • 1. Photo-optical properties of poly(oxadiazole-imide)s containing naphthalene rings • M. D. Damaceanu, R. D. Rusu, M. Bruma, B. Jarzabek • Polymer Journal, 42(8), 663–669 (2010). • 2. Copoly(peryleneimide)s containing 1,3,4-oxadiazole rings: synthesis and properties • R. D. Rusu, M. D. Damaceanu, L. Marin, M. Bruma • Journal of Polymer Science Part A: Polymer Chemistry, 48(19), 4230–4242 (2010). • 3. Polymers containing 1,3,4-oxadiazole ring for advanced materials • M. D. Damaceanu, R. D. Rusu, M. Bruma • Memoirs of the Scientific Section of the Romanian Academy, XXXIV, 105–125 (2011). • (acceptata in 2010, publicata in 2011)

  12. ETAPA 1. august - decembrie 2010 • Lucrari publicate in volume de manifestari stiintifice • 1. Study of dielectric behaviour of aromatic polyimide films • S. Chisca, V. Musteata, I. Sava, M. Bruma • Proceedings of 33rd International Semiconductor Conference, vol. 2. p. 325-328(2010). • 2. Dielectric properties of thin polyimide films • R. D. Rusu, M. D. Damaceanu, M. B., A. Muller • Proceedings of 33rd International Semiconductor Conference, vol. 2. p. 363-366(2010).

  13. ETAPA 1. august - decembrie 2010 • Lucrari prezentate la manifestari stiintifice • 1.Study of thin films made from aromatic polymers containing six-member imide rings(poster) • M. Bruma,M. D. Damaceanu, R. D. Rusu • Polycondensation 2010 Meeting, Rolduc Abbey, Olanda, 5-8 septembrie 2010, • Program p. 7, P1, Book of abstracts p. 103. • 2.Poli(perilen-imide) heterociclice: sinteza si caracterizare (poster) • R. D. Rusu, M. D. Damaceanu, M. Bruma • A XXXI-A Conferinta Nationala de Chimie, 6-8 octombrie 2010, Ramnicu Valcea, Program p. 55,P.S.III.-20, Cartea de rezumate p. 159. • 3.Efectul tratamentului termic asupra proprietatilor filmelor de poliimida (poster) • S. Chisca, I. Sava, M. Bruma • A XXXI-A Conferinta Nationala de Chimie, 6-8 octombrie 2010, Ramnicu Valcea, Program p. 56, P.S.III.-23, Cartea de rezumate p. 162.

  14. ETAPA 1. august - decembrie 2010 • Lucrari prezentate la manifestari stiintifice • 4.Studiul proprietatilor dielectrice si a mobilitatii moleculare prin spectroscopie dielectrica • a unor filme de poliimida (poster) • V. E. Musteata, S. Chisca, I. Sava, V. Barboiu • A XXXI-A Conferinta Nationala de Chimie, 6-8 octombrie 2010, Ramnicu Valcea, • Programp. 56, P.S.III.-24, Cartea de rezumate p. 163. • 5.Study of dielectric behaviour of aromatic polyimide films (poster) • S. Chisca, V. E. Musteata, I. Sava, M. Bruma • 33rd Edition of International Semiconductor Conference, October 11-13, 2010, Sinaia, • Program p. 37, AM1.7. • 6.Dielectric properties of thin polyimide films (oral presentation) • R. D. Rusu, M. D. Damaceanu, M. Bruma, A. Muller • 33rd Edition of International Semiconductor Conference, October 11-13, 2010, Sinaia, • Program p. 45, AM2.2.

  15. ETAPA 1. august - decembrie 2010 • Conferinte prezentate in seminarii la institutii din strainatate • 1.Copolymers containing 1,3,4-oxadiazole and fluorene moieties for optoelectronic applications • M. D. Damaceanu • Center of Polymer and Carbon Materials, Zabrze, Poland • 2. Heterocyclic copoly(peryleneimide)s. Synthesis and characterization • R. D. Rusu • Center of Polymer and Carbon Materials, Zabrze, Poland • 3. Thermal and dielectric properties of some aromatic polyimides • S. Chisca • Center of Polymer and Carbon Materials, Zabrze, Poland

  16. ETAPA 2 Anul 2011

  17. ETAPA 2. Anul 2011 • OBIECTIVE REALIZATE • Prepararea unor filme subtiri de sine statatoaresi a unor filme foarte subtiridin polinaftalenimidele sintetizate in Etapa I • Studiul proprietatilor mecanice ale filmelor polinaftalenimidice • Studiul comportarii dielectrice a filmelor polimerice • Studiul comportarii la umezire si umflarea in CO2 supercritic • Studiul proprietatilor foto-optice ale poliimidelor cu cicluri naftalenice in stare solida (filme foarte subtiri) • Studiul comportarii la ablatie laser a unor filme polinaftalenimidice

  18. ETAPA 2. Anul 2011 • OBIECTIVE REALIZATE • Sinteza si identificarea structurala a unui monomer de tip diamina continand ciclul 1,3,4-oxadiazolic • Sinteza si identificarea structurala a unui monomer de tip dianhidrida continand unitatea de fluoren • Sinteza si identificarea structurala a unor poliimide cu cicluri perilenice • Sustinerea si promovarea activitatilor si rezultatelor

  19. ETAPA 2. Anul 2011 • REPARTIZAREACHELTUIELILOR

  20. ETAPA 2. Anul 2011 • VALORIFICAREAREZULTATELOR • 3 lucrari publicate in reviste cotate ISI • 6 lucrari publicate in volume de manifestari stiintifice (3 indexate ISI si BDI) • 16 lucrari prezentate la manifestari stiintifice • 1teza de doctorat care a primit sprijin financiar in cadrul prroiectului – Radu-Dan RUSU

  21. ETAPA 2. Anul 2011 • Lucrari publicate • 1.Copoly(1,3,4-oxadiazole-naphthylimide)s containing siloxane units in the main chain: synthesis and properties • High Performance Polymers, 23(5), 384–393 (2011) • R. D. Rusu, M. D. Damaceanu, M. Bruma. • 2.Effect of conformational parameters on thermal properties of some poly(oxadiazole- • naphthylimide)s • Iranian Polymer Journal, 20(1), 29–40 (2011) • R. D. Rusu, M. D. Damaceanu, M. Bruma, I. A Ronova. • 3.Dielectric behaviour of thin films made from poly(oxadiazole-naphthylimide)s • Soft Materials, 9(1), 44–63 (2011) • M. D. Damaceanu, R. D. Rusu, V. E. Musteata, M. Bruma.

  22. ETAPA 2. Anul 2011 • Lucrari publicate publicate in volume de manifestari stiintifice 1. Dielectric behaviour of polyperyleneimide films • M. D. Damaceanu, R. D. Rusu, M. Bruma • Proceedings of 34rd International Semiconductor Conference, vol 2, p. 291-294 (2011). • 2.Blue light-emitting polynaphthaleneimides • R. D. Rusu, M. D. Damaceanu, M. Bruma • Proceedings of 34rd International Semiconductor Conference, vol 1, p. 71-74 (2011). • 3.Dielectric and conduction properties of polyimide films • S. Chisca, I. Sava, V. E. Musteata, M. Bruma • Proceedings of 34rd International Semiconductor Conference, vol 2, p. 253-256 (2011).

  23. ETAPA 2. Anul 2011 • Lucrari publicate publicate in volume de manifestari stiintifice 4.New copolyimides containing cycloaliphatic segments • S. Chisca, I. Sava, M. Bruma; CO-04, p. 25 • Actes du Xème Colloque Franco Roumain sur les Polymères, p. 25-27 (2011). • 5. Studies on the thermal, optical and electrochemical behaviour of polyperyleneimides • M. D. Damaceanu, R. D. Rusu, M. Bruma • Actes du Xème Colloque Franco Roumain sur les Polymères, p. 57-60 (2011). • 6.Thin films made from heterocyclic polynaphtylimides • R. D. Rusu, M. D. Damaceanu, M. Bruma • Actes du Xème Colloque Franco Roumain sur les Polymères, p. 69-72 (2011).

  24. ETAPA 2. Anul 2011 • Lucrari prezentate la manifestari stiintifice 1.Physical surface properties of aromatic polymer film during thermal treatment (comunicare) • I. Sava, S. Chisca • 10th International Conference on Colloids and Surface Chemistry, Galati, 9-11 iunie2011, Program p. 35, Book of abstracts p. 65. • 2. Self-organised films of polyimides containing perylene discotic mesogenes (comunicare) • M. D. Damaceanu, R. D. Rusu, M. Bruma, L. Marin • 10th International Conference on Colloids and Surface Chemistry, Galati, 9-11 iunie 2011, Program p. 32, Book of abstracts p.43. • 3.Solid state properties of fluorinated polyimides containing perylene and oxadiazolemoieties (comunicare) • M. D. Damaceanu, R. D. Rusu, M. Bruma • European Polymer Congress, Granada, Spania, 26 iunie-1 iulie 2011, Program T4 - OP37,p. 39, Book of Abstracts p. 352.

  25. ETAPA 2. Anul 2011 • Lucrari prezentate la manifestari stiintifice 4.Heterocyclic polynaphthaleneimides containing siloxane groups in the main chain (poster) • R. Rusu,M. Damaceanu, M. Bruma • European Polymer Congress, Granada, Spania, 26 iunie-1 iulie 2011, Program T4-253, p. 74, Book of Abstracts p. 994. • 5. Aromatic polyimides containing methyl substituents and study of their physical properties • (poster) • S. Chisca, I. Sava, V. Musteata, M. Bruma • European Polymer Congress, Granada, Spania, 26 iunie-1 iulie 2011, Program T4 - 247,p. 73,Book of Abstracts p. 988. • 6.Conformational aspects of some poly(oxadiazole-imide) solutions subjected to a share field • (poster) • A. I. Cosutchi, R. D. Rusu, M. D. Damaceanu, M. Bruma • 12th International Balcan Workshop on Applied Physiscs, Constanta, 6-8 iulie 2011, Program S1-PO-5, p.9, Book of Abstracts p. 51.

  26. ETAPA 2. Anul 2011 • Lucrari prezentate la manifestari stiintifice 7.Polyimides with low dielectric constants for microelectronic applications (poster) • S. Chisca, I. Sava, M. Bruma • 12th International Balcan Workshop on Applied Physiscs, Constanta , 6-8 iulie 2011, • Program S1-PO-6 p.9, Book of Abstracts p. 52. • 8.New copolyimides containing cycloaliphatic segments (comunicare) • S. Chisca, I. Sava, M. Bruma • Xème Colloque Franco Roumain sur les Polymères, Douai, Franta, 6-8 septembrie 2011, • Program CO-04 p. 9. • 9. Studies on the thermal, optical and electrochemical behaviour of polyperyleneimides (comunicare) • M. D. Damaceanu, R. D. Rusu, M. Bruma • Xème Colloque Franco Roumain sur les Polymères, Douai, Franta, 6-8 septembrie 2011, • Program CO-16 p. 10.

  27. ETAPA 2. Anul 2011 • Lucrari prezentate la manifestari stiintifice • 10.Thin films made from heterocyclic polynaphtylimides (comunicare) • R. D. Rusu, M. D. Damaceanu, M. Bruma • Xème Colloque Franco Roumain sur les Polymères, Douai, Franta, 6-8 septembrie 2011, • Program CO-21 p. 10. • 11. Photo-optical and electrochemical behavior of polyimides containing perylene and • oxadiazole chromophores (comunicare) • M. D. Damaceanu, R. D. Rusu, M. Bruma • Polymers for Advanced Technologies International Conference, Lodz, Polonia, 2-5 octombrie 2011, Program L-57, p. 17, Book ofAbstracts p. 52. • 12. Low dielectric constant thin films based on poly(oxadiazole-imide)s for advanced • applications (poster) • R. D. Rusu, M. D. Damaceanu, M. Bruma • Polymers for Advanced Technologies International Conference, Lodz, Polonia, 2-5 octombrie 2011, Program P-78, Book of Abstracts, p. 78.

  28. ETAPA 2. Anul 2011 • Lucrari prezentate la manifestari stiintifice 13. Nano-and-micro-porous polyimides films for advanced dielectric materials (poster) • S. Chisca, I. Sava, M. Bruma • Polymers for Advanced Technologies International Conference, Lodz, Polonia, 2-5 octombrie 2011, Program P-89, Book of Abstracts p. 81. • 14. Dielectric behaviour of polyperyleneimide films (comunicare) • M. D. Damaceanu, R. D. Rusu, M. Bruma • 34rd Edition of International Semiconductor Conference, 17-19 octombrie 2011, Sinaia, • Program. AM.4, p. XIV.

  29. ETAPA 2. Anul 2011 • Lucrari prezentate la manifestari stiintifice • 15. Blue light-emitting polynaphthaleneimides (poster) • R. D. Rusu, M. D. Damaceanu, M. Bruma • 34rd Edition of International Semiconductor Conference, October 17-19, 2011, Sinaia, • Program. O.1, p. VIII. • 16. Dielectric and conduction properties of polyimide films (poster) • S. Chisca, I. Sava, V. E. Musteata, M. Bruma; NA9, p. XIII • 34rd Edition of International Semiconductor Conference, October 17-19, 2011, Sinaia, • Program. NA9, p. XIII. • Teza de doctorat sustinuta • Radu-Dan RUSU • “Noi polimeri si copolimeri continad cicluri 1,3,4-oxadiazolice pentru • materiale avansate” • Conducator stiintific: Dr. Maria Bruma

  30. ETAPA 3 Anul2012

  31. ECHIPA DE CERCETARE • Dr. Mariana-Dana DAMACEANU • damaceanu@icmpp.ro • Dr.Andreea Irina COSUTCHI (BARZIC) • cosutchi.irina@icmpp.ro • Dr.Radu-Dan RUSU (1 ianuarie - 30 aprilie 2012) • radu.rusu@icmpp.ro • Dr.Stefan CHISCA • stefan.chisca@icmpp.ro • Drd.Catalin –Paul CONSTANTIN (1 mai 2012 - 25 iulie 2013) • constantin.catalin@icmpp.ro

  32. ETAPA 3. Anul2012 • OBIECTIVE REALIZATE • Prepararea unor filme subtiri de sine statatoare, si a unor filme foarte subtiri din poliperilenimidele sintetizate in Etapa 2, precum si studiul compozitiei si a morfologiei acestora • Studiul cristalinitatii polimerilor cu cicluri perilenimidice si a capacitatii de autoasmablare • Studiul proprietatilor lichid cristaline ale poliperilenimidelor • Studiul proprietatilor dinamo-mecanice ale filmelor de poliperilenimide • Studiul comportarii dielectrice a filmelor poliimidice • Studiul proprietatilor foto-optice ale poliimidelor cu cicluri perilenice in solutie si in stare solida (filme foarte subtiri) • Studiul proprietatilor electrochimice, iar pe baza lor stabilirea nivelelor energetice si a capacitatii de transport de electroni

  33. ETAPA 3. Anul 2012 • OBIECTIVE REALIZATE • Sinteza si identificarea structurala a doi monomeri de tip imid-amina continand ciclul condensate naftalenice si perilenice • Sinteza si identificarea structurala a unui monomer de tip diamina continand unitati metilenice • Sinteza si identificarea structurala a trei monomeri de tip diclorura acida care contin diferite punti flexibile • Sinteza unor poliamid-naftilimide cu cicluri naftalenice • Sinteza unor polimeri cu cicluri condensate de tip imida si studiul obtinerii de fibre din acestia • Identificarea structurii polimerilor prin spectroscopie RMN, FTIR, determinarea solubilitatii, maselor moleculare si a vascozitatii. • Sustinerea si promovarea activitatilor si rezultatelor

  34. ETAPA 3. Anul 2012 • REPARTIZAREACHELTUIELILOR

  35. ETAPA 3. Anul 2012 • VALORIFICAREAREZULTATELOR • 5 lucrari publicate in reviste cotate ISI • 2 lucrari publicate in volume de manifestari stiintifice (1 indexata ISI) • 13 lucrari prezentate la manifestari stiintifice • 3conferinte prezentate in seminarii cu ocazia deplasarilor la institutii din strainatate • 1 teza de doctorat sustinuta – Stefan CHISCA

  36. ETAPA 3. Anul 2012 • Lucrari publicate • 1.KrF pulsed laser ablation of thin films made from fluorinated heterocyclic • poly(naphthyl-imide)s. • Microscopy & Microanalysis., 18(3), 545-557 (2012). • M. D. Damaceanu, R. D. Rusu, M. Olaru, D. Timpu, M. Bruma • 2.Study of thin films made from aromatic polymers containing six-member imide rings. • High PerformancePolymers, 24(1), 31-39 (2012) • M. Bruma, M. D. Damaceanu, R. D. Rusu • 3.Six-member polyimides incorporating redox chromophores. • Journal of Materials Science, 47(16), 6179-6188 (2012) • M. D. Damaceanu, R. D. Rusu, M. Bruma

  37. ETAPA 3. Anul 2012 • Lucrari publicate • 4.Insulating polyimide films containing n-type perylenediimide moiety • Polymer International, 61(10), 1582–1591(2012) • M. D. Damaceanu, R. D. Rusu, V. E. Musteata, M. Bruma • 5.Morphological and rheological insights on polyimide chain entanglements for • electrospinning produced fibers • Journal of Physical Chemistry Part B, 116 (30), 9082–9088 (2012). • S. Chisca, A. I. Barzic (Cosutchi), I. Sava, N. Olaru, M. Bruma

  38. ETAPA 3. Anul 2012 • Lucrari publicate publicate in volume de manifestari stiintifice • 1. Polyperyleneimide-based materials for optoelectronic devices. • Proceedings of the 35rd International Semiconductor Conference, vol. 1, p. 135- 138 (2012) • M. D. Damaceanu, C. P. Constantin, R. D. Rusu, M. Bruma • 2.High Performance Perylenediimide-Based Copolymers and Thin Films Made Therefrom • Proceedings of the International Conference Nanomaterials: Applications and Properties, • Vol. 1, No 1, 01NDLCN09(4pp) (2012) • M. D. Damaceanu, S. Chisca, C. P. Constantin, M. Bruma

  39. ETAPA 3. Anul 2012 • Lucrari prezentate la manifestari stiintifice • 1.Copolymer architectures containing perylenediimide and oxadiazole donor and fluorene acceptor units for optoelectronic applications(comunicare) • M. D. Damaceanu, S. Chisca, R. D. Rusu, M. Bruma • 7th International conference on advanced materials, ROCAM 2012, Brasov, 28-31 august • 2012, Program p.8 • 2.High performance perylenediimide-based copolymers and thin films made therefrom • (comunicare) • M. D. Damaceanu, S. Chisca, C. P. Constantin, M. Bruma • 2-nd International conference nanomaterials: applications & properties - NAP 2012, • Alushta, the Crimea, Ukraine, Sept. 17-22, 2012, Program O7.8, p. 27 • 3.Sinteza si studiul proprietatilor unor noi copoliimide continand diferiti cromofori • (comunicare). • M. D. Damaceanu, S. Chisca, R. D. Rusu, M. Bruma:, • Conferinta Nationala de Chimie, Calimanesti-Caciulata, 3-5 Oct. 2012,Program C.S.III.-14, p.23.

  40. ETAPA 3. Anul 2012 • Lucrari prezentate la manifestari stiintifice • 4.Poliimide fluorurate cu cicluri aromatice condensate (comunicare). • C. P. Constantin, M. Bruma, M. D. Damaceanu, N. M. Belomoina • Conferinta Nationala de Chimie, Calimanesti-Caciulata, 3-5 Oct. 2012, Program C.S.III.-13, • p.23 • 5. Polyperyleneimide-based materials for optoelectronic devices (comunicare). • M. D. Damaceanu, C. P. Constantin, R. D. Rusu, M. Bruma  • International Semiconductor Conference,15-17 Octombrie 2012, Sinaia, Romania, • Program O.4, p. 32 • 6. Viscoelastic properties of some polyimides containing oxadiazole units (comunicare). • A. I. Barzic (Cosutchi), R. D. Rusu, M. D. Damaceanu, M. Bruma • International Conference CHIMIA 2012 "New Trends in Applied Chemistry", May 24-26, • Constanta, Romania, Program OC4., p. 16.

  41. ETAPA 3. Anul 2012 • Lucrari prezentate la manifestari stiintifice • 7.From blending polyamidic acids with lithium chloride (LiCl) to porous polyimides • structures (poster) • S. Chisca, I. Sava, G. Hitruc, M. Bruma • International Symposium on sustainable polymer materials, 20-23 Mai 2012, Kerkrade, • Olanda; Program p. 4, P 18. • 8.Polymers blends based on fluorinated polyimides (poster) • C. P. Constantin, M. D. Damaceanu, M. Bruma • International Symposium on sustainable polymer materials, 20-23 Mai 2012,Kerkrade, • Olanda;Program p. 4, P-19. • 9. An easy method for preparation of porous polyimide films (poster) • S. Chisca, I. Sava, M. Bruma • Europolymer Conference on porous polymer-based systems from design to application, • 3-7 iunie 2012, Gargnano, Italia; Program p. 11, P-11.

  42. ETAPA 3. Anul 2012 • Lucrari prezentate la manifestari stiintifice • 10.Polyperylene imides containing oxadiazole and siloxane units for light-emitting diodes (poster) • C. P. Constantin, M. D. Damaceanu, R. D. Rusu, M. Bruma • Europolymer Conference on porous polymer-based systems from design to application, • 3-7 iunie 2012, Gargnano, Italia;Program p.11, P-14. • 11. Optical properties of polyimides containing various cromophore units (poster) • S. Chisca, R. D. Rusu, M. D. Damaceanu, M. Bruma • 5th International conference on molecular materials, 3-6Iulie 2012, Barcelona, Spania; • Program p. 48, PO-185. • 12. Polymers containing oxadiazole and naphtylimide units as flourophores and redox • chromophores (poster) • M. D. Damaceanu, R. D. Rusu, M. Bruma • 5th International conference on molecular materials, 3-6 Iulie 2012, Barcelona, Spania; • Programp. 49, PO-175 • 13.Effect of Rubbing Material Texture on Poly(Oxadiazole-Imide) Films Morphology (poster) • Andreea Irina Barzic, Radu-Dan Rusu, Iuliana Stoica and Maria-Dana Damaceanu • 7th International conference on advanced materials, ROCAM 2012, Brasov, 28-31 august, • Program p.9.

  43. ETAPA 3. Anul 2012 • Conferinte prezentate in seminarii cu ocazia deplasarilor la institutii din strainatate • 1.Oxadiazole-functionalized maleic copolymers for optoelectronic applications • Center of Polymer and Carbon Materials, Zabrze, Poland, 5 nov. 2012; • M. D. Damaceanu • 2. From polyamide to polyimide film. The evolution of properties during thermal treatment • Center of Polymer and Carbon Materials, Zabrze, Poland, 5 nov. 2012 • S. Chisca • 3. Study of polynaphthylimides and polyperyleneimides containing triflouromethyl groups • Center of Polymer and Carbon Materials, Zabrze, Poland, 5 nov. 2012 • C. P. Constantin • Teza de doctorat sustinuta • Stefan CHISCA • “Noi polimeri cu cicluri imidice pentru materiale avansate” • Conducator stiintific: Dr. Maria Bruma

  44. ETAPA 4 Ianuarie - Iulie 2013

  45. ECHIPA DE CERCETARE • Dr. Mariana-Dana DAMACEANU • damaceanu@icmpp.ro • Dr.Andreea Irina COSUTCHI (BARZIC) • cosutchi.irina@icmpp.ro • Dr.Stefan CHISCA • stefan.chisca@icmpp.ro • Drd.Catalin –Paul CONSTANTIN • constantin.catalin@icmpp.ro

  46. ETAPA 4. Ianuarie - Iulie 2013 • OBIECTIVE REALIZATE • Evaluarea proprietatilor de stabilitate termica si a cristalinitatii poliamidelor cu cicluri naftilimidice • Prepararea de filme de grosimi micrometrice si de acoperiri pe diferite suporturi de grosimi nanometrice folosind solutii de polimeri in diferiti solventi si studiul morfologiei • Studiul filmelor de polimeri in privinta adezivitatii la diferite suporturi, calitatii si omogenitatii, caracterului hidrofil sau hidrofob al suprafetei, prin masurarea unghiului de contact • Evaluarea proprietatilor electrice ale poli(amid-naftilimidelor) • Masurarea proprietatilor electrochimice ale filmelor de polimeri si stabilirea nivelelor energetice HOMO si LUMO • Studiul proprietatilor foto-optice ale poli(amid-naftilimidelor) in solutie si in stare solida (filme foarte subtiri) • Elaborarea concluziilor asupra studiilor efectuate. • De asemenea, in aceasta etapa a proiectului s-a efectuat un studiu comparativ al proprietatilor tuturor polimerilor sintetizati pe parcursul derularii intregului proiect si a materialelor obtinute din acestia, iar pe baza acestui studiu s-au selectat polimerii cu cele mai bune proprietati. O parte din acestia au fost testati in dispozitive ca OFET-uri sau celule de aliniere a cristalelor lichide, iar pentru altii s-au evidentiat aplicatiile potentiale in dispozitive electronice sau optoelectronice, ca dielectrici interstrat, suporturi flexibile si transparente, materiale transportoare de electroni sau materiale emitatoare de lumina.

  47. ETAPA 4. Anul 2013 • REPARTIZAREACHELTUIELILOR

  48. ETAPA 4. Ianuarie - Iulie 2013 • VALORIFICAREAREZULTATELOR • 4 lucrari publicate in reviste cotate ISI • 2 lucrari trimise la publicat • 5 lucrari prezentate la manifestari stiintifice • 1conferinta prezentata in seminarii cu ocazia deplasarilor la institutii din strainatate

  49. ETAPA 4. Ianuarie - Iulie 2013 • Lucrari publicate • 1. Porous polyimide films obtained by using lithium chloride as pore-forming agent • Polymer International., DOI: 10.1002/pi.4460(2013). • S. Chisca, I. Sava, M. Bruma • 2.Tuning of the color of the emitted light from new polyperyleneimidescontainingoxadiazole and siloxane moieties • Dyes and Pigments 99, 228-239 (2013) • M. D. Damaceanu, C. P. Constantin, M. Bruma, M. Pinteala • 3.Self-organised films of polyimides containing perylene discotic mesogens • Revue Roumaine de Chimie, 57(9-10), 791-797 (2012) – numar aparut in 2013 • M. D.Damaceanu, R. D. Rusu, M. Bruma, L. Marin • 4.Effect of the chemical structure of aromatic-cycloaliphatic copolyimide films on their • surface morphology, relaxation behavior and dielectric properties • Journal of Polymer Research 20, 111-122 (2013). • S. Chisca, V. E. Musteata, I. Stoica, I. Sava, M. Bruma

  50. ETAPA 4. Ianuarie - Iulie 2013 • Lucrari prezentate la manifestari stiintifice • 1. Polyoxadiazoles containing six-member imide rings (oral presentation) • 9th European Technical Symposium on Polyimides & High Performance Functional • Polymers - STEPI 9, Montpellier-France, 3-5 June 2013, Program II.C12, p. 10 • M. D. Damaceanu, M. Bruma • 2.Synthesis and study of fluorinated polyimides containing fused aromatic rings (oral presentation) • 9th European Technical Symposium on Polyimides & High Performance Functional • Polymers - STEPI 9, Montpellier-France, 3-5 June 2013, Program I.C7, p. 8 • C. P. Constantin, M. Bruma,M. D. Damaceanu, N. M. Belomoina • 3. Thermal treatment and changes of surface properties of aromatic polymer films (oral presentation) • 9th European Technical Symposium on Polyimides & High Performance Functional • Polymers - STEPI 9, Montpellier-France, 3-5 June 2013, Program II.C9, p. 10 • S. Chisca,I. Sava, M. Bruma

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