Real Precision Real Solutions Real Results

1. Real Precision Real Solutions Real Results Rosemount Analytical Gas Chromatographs

2. Emerson Online Gas Chromatographs • 80 years of experience • Beckman/Rosemount/Emerson (1956/1983/1976) • Honeywell/Daniel/Emerson (1968/1978/2000) • Emerson Process Management Focused Channels • Daniel — Oil & Gas • Rosemount Analytical — Hydrocarbon Processing • Over 11,000 online gas chromatographs installed worldwide • Worldwide service and support • Three GC Application/Support Centers • Houston, Texas, USA • Stirling, United Kingdom • Hasselroth, Germany

3. 10,000 Gas Chromatographs Installed in the Field Model 500 Gas Chromatograph Model 700 Gas Chromatograph Model 1000/1000A Gas Chromatograph

4. Practical applications for your GC … Billing and costing accounting for product transfers Measure the quality of the gas to ensure that you’re getting the gas that you’re paying for Measure the quality of the gas to ensure that you’re selling the quality of gas that your customers are asking for Environmental monitoring Ensure that ambient air is within safe levels in the plant Ensure that emissions fall within the standards of environmental regulations Process control Use real-time and archived data to more efficiently control the process

5. Practical applications for your GC … Billing and costing accounting for product transfers Measure the quality of the gas to ensure that you’re getting the gas that you’re paying for Measure the quality of the gas to ensure that you’re selling the quality of gas that your customers are asking for Environmental monitoring Ensure that ambient air is within safe levels in the plant Ensure that emissions fall within the standards of environmental regulations Process control Use real-time and archived data to more efficiently control the process A power plant in New York with a new, low-NOx combustion turbine uses a gas chromatograph to ensure the BTU quality of its natural gas to ensure that liquids don’t get into the expensive turbine and cause corrosion. A refinery in Brazil saved an estimated $1.2M in the first year after installing a new Model 700 GC on its in-bound pipeline, because they realized they were selling a product with a carbon content that was significantly over specified requirements.

6. Practical applications for your GC … Billing and costing accounting for product transfers Measure the quality of the gas to ensure that you’re getting the gas that you’re paying for Measure the quality of the gas to ensure that you’re selling the quality of gas that your customers are asking for Environmental monitoring Ensure that ambient air is within safe levels in the plant Ensure that emissions fall within the standards of environmental regulations Process control Use real-time and archived data to more efficiently control the process A refinery in Louisiana uses a Model 500 to measure trace amounts of H2S, a dangerous gas that is fatal when inhaled, to ensure the safety of plant personnel. Process plants throughout Texas use Model 700s and Model 500s to monitor ethylene, propylene, 1,3 butadiene, butanes, and highly reactive volatile organic compounds (HRVOCs) to meet state regulations.

7. Practical applications for your GC … Billing and costing accounting for product transfers Measure the quality of the gas to ensure that you’re getting the gas that you’re paying for Measure the quality of the gas to ensure that you’re selling the quality of gas that your customers are asking for Environmental monitoring Ensure that ambient air is within safe levels in the plant Ensure that emissions fall within the standards of environmental regulations Process control Use real-time and archived data to more efficiently control the process A new refinery in Saudi Arabia saved $900,000 by using Ff-certified 700XA and 1000XA Gas Chromatographs, which reduced cabling expense and optimized communication with the plant’s DeltaV digital automation system. An aromatics fractionation plant in Texas sends quantitative and qualitative data from its 1000A gas chromatograph to its DCS to determine the most cost-effective parameters for its downstream units.

8. A Typical GC Installation Three-sided shelter GC Oven Wall Mounted Calibration Gas Sample Gas Local Operator Interface ¼ VGA full-color display with infrared touch-keys GC Electronics Sample Conditioning System

9. Three options for GC Installation offers project flexibility Add’t cost per GC: $0 Field-mounted (no shelter) • Rugged, environmentally hardened casing can withstand any climate Add’t cost per shelter: $15k Three-sided shelter • Protect your field technicians from the weather without incurring the expense of utility usage from climate control Add’t cost per shelter: $170k Environmentally controlled shelter • Excellent for installations in extremely hot or cold climates to allow field technicians to work in a comfortable environment, and to protect other, more climate-sensitive instrumentation

10. Shelters have a huge impact on project cost Typical Costs Project example for a major petrochemical plant (12) Conventional GCs $ 504,000 (6) Walk-in shelters $1,033,080 $1,537,080 (12) Field-mount GCs $ 504,000 (6) 3-sided shelter $ 90,000 $ 594,000

11. Features of a three-sided shelter Individual bottle regulators Solid all-welded construction Atmospheric vent with flame arrestor Utility power with GRCI

12. Features of a fully enclosed shelter • Temperature controlled environment for maintenance worker comfort • Not required for most Emerson GC installations • May be required for less rugged 3rd party moisture or single component analyzers • Typically designed to declassify work area for worker safety • Not required for most Emerson GC installations

13. Gas Chromatograph System Components Get rid of the flames – just show a red/orange block

14. Sample Conditioning System • Custom-engineered for your measurement requirements to provide the best protection for your sensitive chromatograph components • Conditions sample to proper pressure and temperature • Filters particulates • Eliminates contaminants even in high-flow, high-moisture samples Liquid with vaporizing regulators and double-block-and-bleed solenoids 4 x gas stream with vacuum pump for low-pressure sample

15. What do we mean when we say “rugged”? • Explosion proof, meeting standards CSA and ATEX and IEC-EX • Tested in a 24-hour hot and cold soak to ensure it will work in any weather Frost accumulation on GC during “cold soak” test Example of analyzer stability during environmental chamber testing

16. Standard Natural Gas Industry Applications • BTU/CV C6+ (4 minute analysis) • Std. C9+ (5 minute analysis) • Std. C9+ and HC Dewpoint • Trace H2S (0-30 ppm) – working on lowering MDL to +/-0.5ppm • Std. C6+ with H2S (percent level) • Std. C6+ and H2S (ppm level) • Std. C6+ with Oxygen (0-1% level) • Std. C6+ with Helium / Hydrogen • Fast CO2 (90 seconds analysis) • Landfill Gas (8 minute analysis with std. columns) • Landfill Gas (3 minute analysis with mole sieve columns) • Turbine Control (BTU/CV C6+ with 2 minute analysis) • Gas Fractionation • LNG

17. Standard Hydrocarbon and Chemical Industry Applications • Ethylene plants (multiple applications) • H2S in fuel gas • Fertilizer plants (ammonia) • Air separation plants (multiple applications) • Biogas facilities (various applications) • Syngas analysis • Refineries (multiple applications) • Gas processing • Light chemicals (various applications) • Polyethylene/propylene plants (multiple applications)

18. Select the GC that fits your specific requirements • 1500XA • Air-bath oven design • 110 /220 VAC • TCD, FID, or FPD • Micro-packed and capillary columns • Capacity for 7 valves & 2 detectors 700XA Ff-enabled 2-minute cycle time for key applications, 4-minute standard • 500 • Field-mount design • 110/220 VAC • TCD only • Micro-packed columns • Isothermal (single/dual) Oven • Integrated or remote controller • Serial/ Modbus /Ethernet communications • MON 20/20 • Latest Workstation Software • Incorporates new features • Improvements based on customer feedback • Windows compatible

19. Gas Chromatograph Communications Network

20. Local Operator Interface (LOI) Option • All common features for process analyzers displayed • LOI is a high-resolution, touch-key color display • Touch-key infrared activation • All core GC operations supported

21. LOI Specifications • LCD with QVGA (320 X 240-pixels) resolution. • ASCII text and graphics modes. • Auto-backlighting • 8 infrared keys and 3 LEDs • Operates in the same ambient temperatures as the base 700XA, Model 1000A, and Model 700 gas chromatographs

22. 700XA specifications • Single-cast design for easier installation • Superior analytical performance • ±0.125 BTU/1000 in stable ambient • Improved sensitivity with the thermal conductivity detector (TCD) – nearly ppb level • Robust ambient temperature range -20°C to 60°C (-4°F to 140°F) • Side access for easier installation and maintenance • Electronic boards are easier to add and remove • Increase stream handling capability (up to 24) • Available in CSA and ATEX/IEC-Ex approved versions

23. Close-up of 700XA oven compartment Sample Loop 6-Port XA Valve 10-Port XA Valve Heat Sink Oven Detectors

24. Efficient oven design allows for maximum capabilities in a small compartment Integral heat sink oven provides constant temperature (better than ± 0.1°C) and contains: Analytical valves Capillary and micro-packed columns Multiple detector options: TCD/TCD TCD/FID TCD/FPD No instrument air required Proven reliable performance in environments ranging from -20 to 60°C

25. Redesigned chromatograph valves • Smaller, more analytically reliable valve design • 6 and 10 port configurations • Sample does not come in contact with internal moving parts • Less carrier and valve actuation gas required • Over 5 million operations per valve • Lifetime warranty on diaphragm valves • Diaphragm replacement takes <10 minutes

26. Unparalleled thermal conductivity detector performance • Combining proven successful thermistor bead detectors and new electronics results in stronger performance • 0-30 ppm H2S with detection limit approaching ppb level • Repeatabilities on natural gas analysis of +/- 0.125 BTU in controlled environments

27. World’s first and only Ff- certified gas chromatograph Easy integration with Ff DCS & AMS Suite Reduced cost of engineering Lower installation and startup costs Reduced cabling requirements 700XA Gas Chromatograph & FOUNDATION fieldbus (Ff)

28. FOUNDATION Fieldbus for Analytical enables: One single protocol across all instruments and analyzers installed base 80+% reduction on variables mapping time during configuration vs. MODBUS mapping Expand plant operators skills to Analytical installed base Less wiring, junction boxes, cable trays, marshalling cabinets, IO cards and respective cabinets Why FOUNDATION Fieldbus for Analytical?

29. Focus your GC on your process Select the stream you need to focus your process with a single click Bring your process under control and go back to normal operation

30. 700XA Alerts Getting the right information to the right person so they can take the rightaction

31. The Information Is Meaningfuland Actionable This GC has an issue clearly visible in AMS A click of a button reveals a sample flow problem Information is delivered to the right person to take action but can be seen anywhere in the plant

32. Seamless integration of MON20/20 • All MON20/20 benefits just a click away!

33. Bring Ff to your Analytical Installed base • One single open communication protocol • One single tool to manage your instrument and analytical installed base • Significantly decrease your variable mapping time during commissioning • The right alerts to the right people

34. 1500XAProcess Gas Chromatograph Maximum analytical flexibility Traditional air-bath oven design for maximum application flexibility Fully compatible with modern Ethernet networks and DCS communication New XA valves, based on the reliable design of our line of superior 6-port chromatograph diaphragm valves. Oven capacity for up to eight chromatograph valves and two detectors Choice of thermal conductivity or flame ionization detectors Thermal conductivity detector (TCD) sensitive down to very low parts-per-million levels Storage of up to 2,500 chromatograms, including sample calibration and validation streams Archives up to 64 item averages and up to 12 sample streams

35. MON 20/20 Gas Chromatograph Software Don’t have time to go out into the plant to check your GC data? No problem with MON 20/20 gas chromatograph software.

36. MON 20/20 Gas Chromatograph Software • Windows based with drop down menus and fill-in-the-blank tables • Access and modify GC analysis settings • Access and display chromatograms • Fully annotated chromatogram • Easily overlay multiple chromatograms • Retrieve archive data • Report displays • Table displays • Trend line displays

37. MON 20/20 Gas Chromatograph Software MON 20/20 offers a more intuitive user experience, easier access to data, and significant productivity enhancements Simple drop down menus Summary of application event status & time Connect to any GC with a mouse click Automatic listing of measured components Quickly add chromatograms to overlay Full-featured chromatogram display

38. MON 20/20 – Chromatograph Viewer Timed events Component retention times Overlay and compare Chromatograms Zoom function for easy set up and diagnostics Results and chromatogram handling Graphing and trending

39. MON 20/20 – Enhanced Zooming Zoom function for easy set up and diagnostics Full chromatogram view (for reference) “Zoomed” view for detailed analysis

40. MON 20/20 –Multiple Windows View multiple diagnostic windows simultaneously

41. MON 20/20 – Resize Windows Resize windows to meet your viewing preferences

42. MON 20/20 Software • Configuration/diagnostic software • Compatible with XA Series of Gas Chromatographs from Emerson Process Management • View chromatograms, reports, alarms.

43. 700XA Gas ChromatographCommunication Options • Choice of communication options: • Analog (4-20 mA) • Serial Modbus (up to 5) • (2) Ethernet multi-drop connections • Modem • Foundation Fieldbus connection • Connect to the 700XA with AMS Suite and receive PlantWeb Alerts

44. Model 700 Process Gas Chromatograph • The Model 700 is a field-mounted gas chromatograph for natural gas pipeline, process, and terminal applications, offering outstanding measurement accuracy and application flexibility

45. Model 700 Gas ChromatographSpecifications • Flame-proof housings • -30°C to 60°C (-20°F to 140°F) ambient rating • -18°C to 55°C (0°F to 130°F) chamber test • 24VDC Std. or 110/240VAC power option • Pipe, wall or stand mounting • Minimal if any shelter needed • No instrument air • Low carrier consumption • Lifetime warrantee on GC valves • Networking for PC access from anywhere in the plant

46. Rotary Valve Types of sample injection valves • Diaphragm Valve • Rotary Valve • Liquid Sample Injection Valve (LSIV) 6 and 10 port diaphragm valves from the Model 700 LSIV

47. Model 500 Process Gas Chromatograph • The Model 500 offers an industry-renowned combination of advanced technology and rugged instrumentation that is even more reliable and easier to use than ever!

48. Model 500 Gas Chromatograph Specifications • Analytical flexibility to handle wide assortment of applications • 1 or 2 TCD detector / oven combinations • Vapor and liquid injection valves available • Each analyzer is custom engineered for the specific application • No instrument air required (for operation or safety) • Up to 12 sample streams • Connectivity to plant control computer via Modbus or OPC

49. Model 2350A GC Controller • Controller used on the Model 500 and Model 1000A GCs • Controls valve timings/stream switching • Processes detector/preamp signals • Performs calculations • Provides analog and serial I/O for transmitting GC data • Analog outputs (4-20 mA) • Serial links (Modbus) • Ethernet (OPC/Modbus) • Analog and digital inputs • Choice of mounting next to GC or remotely • Available in 19” rack or Ex versions • Rack mount version can be up to 2000’ away

50. MON 2000 Windows-Based Gas Chromatograph Software • Windows based with drop down menus and fill-in-the-blank tables • Access and modify GC application settings • Access and display chromatograms • Fully annotated chromatogram • Easily overlay multiple chromatograms • Retrieve archive data • Report displays • Table displays • Trend line displays