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Biofuels: A sober look at the potential. Chris Field Carnegie Institution: Department of Global Ecology Stanford University, Department of Biology www.global-ecology.org. Bioenergy basics Bioenergy options Bioenergy potential. Why biofuels?. Climate protection Offset fossil fuels
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Biofuels:A sober look at the potential Chris Field Carnegie Institution: Department of Global Ecology Stanford University, Department of Biology www.global-ecology.org • Bioenergy basics • Bioenergyoptions • Bioenergy potential
Why biofuels? • Climate protection • Offset fossil fuels • Account for fossil fuels used to produce • Account for site carbon balance • Account for other greenhouse gases • Energy security • Local potential • Diversify sources
How can biofuels be lower carbon? • Photosynthesis • Light + CO2 plant + O2 • Plant combustion • Plant + O2 energy + CO2 • Net • Light + CO2 energy + CO2
How Biomass is Used for Energy In development Mature Semi-mature (Capital intensive ineficient)
Carbon cycle basics • Fossil fuel + oxygen carbon dioxide • Coal: C + O2 CO2 • Oil: C8H16 + 12O2 8CO2 + 8H2O • Natural Gas: CH4 + 3O2 CO2 + 2H2O • How much CO2? • Burning 1 lb of coal produces 3.6 lb of CO2 • Burning 1 gal of gas produces 18 lb of CO2 • The average person produces 30 lb CO2/day • The average American produces 170 lb CO2/day
Setting the scale • Food for 1 person for one year • ~ 250 kg corn • = ethanol for one fill-up • ~ 80 l (20 gal) • At 25 mpg and 10,000 miles/y • The corn required to fuel one car on corn ethanol • Would feed 25 people
1 ZJ KT impact 12 ·1015 J supertanker 1011 J car/yr 450 EJ world energy consump/yr 100 J action 4 ·1022 J World fossil Fuel reserves 1013 J 1 gram E = Mc2 10 MJ 2400 kcal human/day 1 MJ 240 kcal 5 ZJ Solar energy On Earth in 1 year 1017 J biggest nuclear bomb 1 kg matter 4 GJ =ton TNT 6 GJ = barrel crude oil 0.5 MJ speeding car BTU QUAD 1 J 1 kJ 1 MJ 1 GJ 1 TJ 1 PJ 1 EJ 1 YJ 1 ZJ Energy Powers of ten 0 3 6 9 12 15 18 21 24
Global annual plant growth • ~57 x 109 ton C on land • ~57 x 109 ton C in the oceans = 2500 EJ or 5 x global primary energy = 2500 EJ or 5 x global primary energy
Energy in ag and pastures? Global Primary Energy = 450 EJ/y * In ½ biomass (to allow for roots), assume 45% C
Will yields increase dramatically? • Historical trends – a century of success • 1-2%/y for major crops • Will this continue? • Can it accelerate?
Ag yields – a century of successincreases of 1-2% y-1 Lobell and Field ERL 2007
Limiting factors for global NPP Baldocchi et al. 2004 SCOPE 62
Potential yield • Ag in relation to natural NPP • Ag/NPP -- Globally about 65% • Global average crop yields unlikely to exceed natural NPP for at least the next several decades
Burn or Ferment? • If you want energy • Burn • If you want oil independence • Liquid biofuels • Battery technology
Net energy balance ratio(biomass energy out/fossil energy in) • Corn ethanol ~1.2 • Sugarcane ethanol ~ 8 • Soy biodiesel ~ 2 • Palm biodiesel ~ 9 • Cellulosic ~5(?)
Is sugarcane the answer? • High yields in warm, wet climates • Limited need for fossil energy • Burn bagasse for processing energy
Is cellulosic the answer? Yield of 26.5 tons/acre in limited area test plots Courtesy of Steve Long et al
Lignin occludes polysaccharides Cellulose Hemicellulose Lignin
Lignin Effect of lignin content on enzymatic recovery of sugars from Miscanthus cellulose Hemi cellulose Switchgrass composition D Vrije et al (2002) Int J Hydrogen Energy 27,1381
Biofuels and food USDA Amber Waves 2007
Ethanol production cost per tonCO2 equivalent emissions offset(not accounting for land use) Thow & Warhurst, 2007 (divide by 2.2 for break even oil price in $/bbl)
Food – the perfect storm? • Population • Food preferences • Climate change • Biofuels
Bioenergy – the climate protective domain • Increase growth • Increase efficiency of conversion to useful products • Utilize sites where C loss from conversion is small in relation to bioenergy yield • Utilize sites that are not needed for something else
Potential from abandoned land Field, Campbell, Lobell TREE 2008
From available abandoned land 0.8 Pg C x 2 g Plant/g C x 0.5 g top/g plant x 16 EJ/Pg = 13 EJ = 3% of current global energy system
Bioenergy • Climate impact depends on pre-existing ecosystem • Indirect as well as direct paths to carbon loss • Natural NPP reasonable proxy for potential yield under ag management • Available land resource limited • Quantity and quality • Big potential in absolute terms • But a small slice of present or future demand