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METO 637. Lesson 15. Polar meteorology. In the winter months the poles are in perpetual darkness. This causes extremely cold temperatures in the stratosphere (-80 o C). These cold temperatures favor the formation of ice clouds known as polar stratospheric clouds (PSC).
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METO 637 Lesson 15
Polar meteorology • In the winter months the poles are in perpetual darkness. This causes extremely cold temperatures in the stratosphere (-80oC). • These cold temperatures favor the formation of ice clouds known as polar stratospheric clouds (PSC). • It is significant that the years when the temperature was lowest corresponded to the years when the ozone depletion was largest. • In addition a vortex forms around the pole as the cold air descends. Wind speeds of 100 meters per second or more have been observed
Polar Stratospheric Clouds • There are two main classes of PSC. • Type 1 PSC are small (<1mm) HNO3 rich particles. These have a mass mixing ratio of about 10 ppbm. • Type II PSC are larger (from 10 mm to about 1 mm) composed primarily of H2O-ice with minor amounts of HNO3 as hydrates. • They can constitute up to 1000 ppbm of the stratosphere. • As noted before, the primary reaction that can be induced on the surface of the PSC is ClONO2 + HCl → Cl2 + HNO3 • The HNO3 is then retained in the PSC.
Perturbed Chemistry • Most of the chlorine in the stratosphere is bound up in two species, hydrogen chloride and chlorine nitrate: Cl + CH4→ CH3 + HCl ClO + NO2 + M → ClONO2 + M • Normally homogeneous reactions only slowly convert these reservoir species back to chlorine. • However these two species can react on the surfaces of PSC’s: ClONO2 + HCl → Cl2 + HNO3 • The molecular chlorine is released as a gas, and the nitric acid is retained within the PSC (as nitrates – NAT). • The chlorine molecule can then be dissociated easily by visible radiation.
Biogenic volatile organic compounds • Troposphere contains a amazing mixture of VOC’s. • Biogenic (naural) and anthropogenic (man-made) • Natural VOC’s are often hydrocarbons, but also contain partially oxidized VOC’s such as alcohols, aldehydes, ketones and acids. • Methane is by far the most abundant, but the sum of the others are larger • Non-methane hydrocarbons • .Are much more reactive than methane. • Play significant role in tropospheric chemistry