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Learn about point symmetry groups, including improper operations and the relation between 1st and 2nd sort operations. Discover how groups can be formed, decomposed, and transformed while exploring rotoinversion axes and proper point groups.
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Point Symmetry Groups w/ improper operations Any group containing 2nd sort operations also contains 1st sort operations (Aa i) (Ba i) = Aa Ba i i = Aa Ba
Point Symmetry Groups w/ improper operations Any group containing 2nd sort operations also contains 1st sort operations (Aa i) (Ba i) = Aa Ba i i = Aa Ba 1st sort operations in such a group G form a subgroup of index 2 g = 1 a2 …. an Bg = B Ba2 …. Ban B is any 2nd sort operation in G
Point Symmetry Groups w/ improper operations Any group containing 2nd sort operations also contains 1st sort operations (Aa i) (Ba i) = Aa Ba i i = Aa Ba 1st sort operations in such a group G form a subgroup of index 2 g = 1 a2 …. an Bg = B Ba2 …. Ban B is any 2nd sort operation in G (Ba i) ar = (Ba ar) i all 2nd sort operations in Bg 1st sort
Point Symmetry Groups w/ improper operations 1. Any group of 2nd sort contains equal nos. of operations of 1st & 2nd sort 2. In any group of the 2nd sort, 1st sort operations form a subgroup of index 2
Point Symmetry Groups w/ improper operations 1. Any group of 2nd sort contains equal nos. of operations of 1st & 2nd sort 2. In any group of the 2nd sort, 1st sort operations form a subgroup of index 2 3. A group of the 2nd sort can be formed by adding any second sort operation (and its products) to a group such that it transforms that group into itself
Point Symmetry Groups w/ improper operations 1. Any group of 2nd sort contains equal nos. of operations of 1st & 2nd sort 2. In any group of the 2nd sort, 1st sort operations form a subgroup of index 2 3. A group of the 2nd sort can be formed by adding any second sort operation (and its products) to a group such that it transforms that group into itself 4. All groups of the 2nd sort can be formed by starting with all groups of the 1st sort & adding each possible 2nd sort operation (i or m) & products which transforms the group into itself
Point Symmetry Groups w/ improper operations Any rotoinversion axis, except those for which n = 4N, can be decomposed into a combination of rotation axis & inversion or reflection
Point Symmetry Groups not containing i G = g, ng = g, gn (g of index 2…cosets =…n transforms g into itself) For every pt grp G of 1st sort which can be expressed as product of subgroup g of index 2 and operation of 1st sort n (n even), can get a corresponding group G from same subgrp & 2nd sort operation n
Point Symmetry Groups not containing i G = g, ng = g, gn (g of index 2…cosets =…n transforms g into itself) For every pt grp G of 1st sort which can be expressed as product of subgroup g of index 2 and operation of 1st sort n (n even), can get a corresponding group G from same subgrp & 2nd sort operation n 2 (=m) 4 6 (If n odd, order of n = 2x that of n)
Point Symmetry C4 C4 C4 C2 C2 C4 C2 C4 C2 C4 2 3 2 3 C4 C4 C4 m m C4 m C4 m C4 2 3 3 2
Point Symmetry Groups containing i wrt i, any proper point group is of index 2 … i transforms any group into itself So, get new groups by G i
Point Symmetry G G i 1 1 2 2/m 3 3 4 4/m 6 6/m 222 2/m 2/m 2/m 32 3 2/m 422 4/m 2/m 2/m 622 6/m 2/m 2/m 23 2/m 3 432 4/m 3 2/m
Point Symmetry 4 i = 4/m C4 C2 C4 i i C4 i C2 i C4 G G i 1 1 2 2/m 3 3 4 4/m 6 6/m 222 2/m 2/m 2/m 32 3 2/m 422 4/m 2/m 2/m 622 6/m 2/m 2/m 23 2/m 3 432 4/m 3 2/m -1 -1
Point Symmetry 4 i = 4/m C4 C2 C4 i i C4 i C2 i C4 2 i = 2/m C2 i i C2 G G i 1 1 2 2/m 3 3 4 4/m 6 6/m 222 2/m 2/m 2/m 32 3 2/m 422 4/m 2/m 2/m 622 6/m 2/m 2/m 23 2/m 3 432 4/m 3 2/m -1 -1
Point Symmetry 4 i = 4/m C4 C2 C4 i i C4 i C2 i C4 2 i = 2/m C2 i i C2 2' i = 2'/m' C2 i i C2 G G i 1 1 2 2/m 3 3 4 4/m 6 6/m 222 2/m 2/m 2/m 32 3 2/m 422 4/m 2/m 2/m 622 6/m 2/m 2/m 23 2/m 3 432 4/m 3 2/m -1 -1 l l