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Impact of Food Processing on Quality. Paul Nesvadba The Robert Gordon University Aberdeen, Scotland, UK. CHISA 2004, Prague, 23 August 2004. Robert Gordon University St Andrew Street, Aberdeen. Physicist - Food processing - Food Physics. EU project EVITHERM.
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Impact of Food Processing on Quality Paul Nesvadba The Robert Gordon University Aberdeen, Scotland, UK CHISA 2004, Prague, 23 August 2004
Robert Gordon University St Andrew Street, Aberdeen
Physicist - Food processing - Food Physics EU project EVITHERM European Virtual Institute for Thermal Metrology www.evitherm.org
Food processing Significant effect on food properties hence Significant impact on food quality
Food - becoming a global commodity • Legislation • Competition Food - connection to Health • Beneficial v. Detrimental (“Elixir of Life”) • “Functional” foods • “Smart” foods
Food Production - Components Generation of Bio-mass Recycling Human Consumption Products resulting from Agriculture Waste Live-stock Process and transformation Storage Packaging Storage Distribution Quality Control Advertising
Why are most foods processed? • To increase digestibility, nutritive and health value • To attract & satisfy the consumers, to develop the food market • To preserve foods • To maintain or enhance the quality
What is the Food Quality ? -> “Fitness for purpose” Hygienic ( Ex: No salmonella) Chemical ( Ex: No toxin) FOOD QUALITY Sensory ( Ex: Pleasant flavour) Physical ( Ex: Good texture ) Energy, Nutrition, Health Promotion (Ex: Vitamins ) Consumerchoice Convenient (Ex : prepared meals)
Convenience - Ready Meals • Convenience • Less time for preparation • Economical for single person or small families • Reduced wastage • Demographic trend • Use of the Internet
How to ensure Food Quality / Safety? Quality control from “farm” to “fork” • HACCP (Hazard Analysis and Critical Control Point) • Appropriate processing methods • Traceability and labels(Linked to Real-time delivery / inventory control / management)
Meeting the Requirements • Safety and preservation • Pasteurisation, Appertisation and Sterilisation • Screening for physical and chemical contaminants • Adding chemical conservatives • Modification • Novelty, “added” properties • Digestibility, Nutritive value
Modifying Food Properties • Agriculture • Genetic Modification of plants DNA • Food Processing • Production of bio-molecules and bio-polymers by modified genetic organisms; transformation • Incorporation of additives • Enhancing nutritive and health benefits
Benefits of ingesting food Building of body component during growth Energy FOOD Prevention or reduction of RNA / DNA damage – “anti-mutagens” DNA / RNA Repair
What is Preservation ? • Destruction of micro-organisms and spores • Inactivation of enzymes Salmonella • Slowing the rate of chemical reactions such as oxidation Browning of an apple due to oxidation
Other reasons for Food Processing • Other safety reasons • Destruction of toxins • Improving properties • physico-chemical • sensory • aesthetic
How to produce safe foods ? • Thermal processing • Diminution of the water activity by • - Drying and Freezing • - Adding molecules ( e.g: NaCl) • High pressure • Ultraviolet light • Ozone • Electric pulses • Incorporation of additives
Thermal processing • 95% of staple foods require cooking • Processing by heating is “as old as fire” • Domestic cooking • Half of the world’s population uses solid fuel as source of heating for food
Pasteurisation • First time used by Pasteur in the 19th century. • Heating 30 minutes at 63°C or 12 seconds at 72°C • Destruction of the pathogen, food deteriorating floras. • Destruction of deteriorating enzymes • Conservation of the nutritious properties (vitamins, proteins, flavour...) Pasteur
Appertisation Comparison of the protein composition in Fish flesh • Nicolas Appert invented it in 1810 • In general, Heating between 110 and 130 degrees during 20min to an hour, in glass or aluminium cans • The results are the same as for Pasteurisation but the time of conservation is longer
Sterilisation • Long time of conservation • Heating for 3s between 135°C and 150°C • Destruction of all the micro organisms and enzymes • Destruction of some interesting nutritious properties
Quality Retention during sterilisation n = log ( N0 / N ) Time n = 6 n = 9 Vitamin B1 destruction 10% Micro-Organism Inactivation 3% Temperature
COSTHERM, a computer program for the prediction of Thermophysical properties -Temperature range : -40 to 40 degrees -Accuracy: 10% Modelling of the effect of Heating • Input Data • = contents of: • Water • Protein • Fat carbohydrates • Minerals • Density • Initial freezing point Output: Specific Heat, Enthalpy, Thermal Conductivity, Ice fraction Temperature Model Micro- or kinetic model
What happens in a non-packaged product To Refrigerate (4 - 8 C) Slow down the development of • micro organisms • bio-chemical degradation reactions
To freeze (-18 to -40 C) • Decrease the temperature below -18 C in a few minutes, the quickest possible. • Stop food degradation reactions • Prevent the development of micro organisms • Long time of conservation
Cell damage during freezing • high solute concentration (low aw) • membrane shrinkage and damage • intracellular ice (?)
High pressure • Covalent bonds are not strongly affected - vitamins preserved • Inactivation of enzymes • Some enzymes are modified, “hardened” • Inactivation of micro-organisms • Disruption of cell membrane cells - “lysis” • Spores are resistant • Thermodynamic effects • Pressure shift freezing and thawing
Inactivation of micro-organisms Inactivation of enzymes
Ionisation • Creation of ions in the irradiated food, by an gamma or electron beams • Maximum dose: 10 kGy • Destruction of the pathogen, food deteriorating floras. • Destruction of deteriorating enzymes • Conservation of the nutritious properties(vitamins,proteins, flavour, except lipids...) • Consumer resistance Logo of ionized food
Electric pulses • Same action high pressure and heating • Disruption of the cell membrane • Electroporation Schematic configurations of the three most used PEF treatment chambers
Dependence of microbial survival fraction on the A) electric field and B) treatment time. Curves a correspond to resistant micro-organisms and curves b to sensitive micro-organisms S, survival fraction; N, microbial count; E, electric field; b, kinetic constant; t, time. Subscripts: 0, initial; c, critical; t, time; e, electric field
Incorporation of additives • butylated hydroxytoluene (in some potato chips, salted peanuts, breakfast cereals and many other things) • calcium disodium ethylene diamine tetra acetate (in salad dressings and some drinks) • sodium L-ascorbate (a form of vitamin C) • E-numbers
Incorporation of Salt - NaCl • Ubiquitous • natural presence and a major additive • Preservation by lowering Aw • Possible raising of blood pressure • Tendency to decrease salt content • High Pressure Treatments can assist NaCl Structure
Anti Oxidants • Diseases • Cancer • Cardiovascular • Neurological • Antioxidants • L-ascorbic acid • Carotenoids • Flavonoids & other polyphenolic compounds
Anti oxidant properties • Relatively unstable • Processing or storage can improve antioxidant activity – e.g. polyphenols at an intermediate oxidation state can scavenge radicals more than in non-oxidised state
Additive Free Foods • Salt – mainly as a flavour enhancer in western world • Nitrites • Phosphates • Monosodium Glutamate
Packaging • Most foods are packaged • Hygiene • Stability of the product • Storage container • Presentation to the consumer • Discarded packaging • Waste • Recycling
Edible packaging • Film and coatings based on: • Polysaccharides • Cellulose, starches, gums • Lipids • Cocoa butter, waxes • Proteins • From milk, soya, cereals • Functions • barrier for moisture, oxygen, fat (b. layers) volatiles • Can carry antioxidants and antimicrobials
Example of specific packagings • For the food degraded by oxidation (Ex: Fruits) • Packaging with modified atmosphere: • Less oxygen • More carbon dioxide • Well defined humidity • Packaging with controlledatmosphere( All the parameters are well known and are monitored) • Vacuum Packaging( No Oxidation) Modified atmosphere packaging to extend shelf life.
Sensors for Food Quality • Imaging (computer vision) • Classification, Inspection • Density • Viscosity • Spectroscopic Techniques • Biosensors / Immunosensors
Bio-processing – Added Value Products • Functional Foods • Interface to Pharmaceuticals • Bio-separation of biomolecules • Immunoglobulins • Purification of proteins from blood serum
Example - Functional Foods • - Purdue University • By changing chicken feed supplements • developed • Eggs that include more of two”good” fats, • conjugated linoleic acid (CLA) and • docosahexaenoic acid, a type of omega-3 fatty acid.
Conclusions • Food processing • Essential for human well-being and health • Influenced by the state of the society • Driven by • consumer demand • Understanding of the connection between food, nutrition and health • New physico-chemical processes • Genetic modification
Thank you for your attention