Porous Organic Materials

1. Porous Organic Materials Table of Contents Metal-organic Frameworks (MOFs) Materials 5 Indium-based MOFs (In-MOF) 6 Zirconium-based MOFs (Zr-MOF) 7 Copper-based MOFs (Cu–MOF) 9 About Us Aluminum-based MOFs (Al-MOF) 10 Chromium-based MOFs (Cr-MOF) 11 CD Biopar?cles is an established drug delivery company which provides customized solu?ons for developing Cobalt-based MOFs (Co-MOF) 12 and producing new, biocompa?ble drug delivery systems. Nickel-based MOFs (Ni-MOF) 13 CD Biopar?cles has produc?on workshops and a quality control laboratory for a series of porous organic Iron-based MOFs (Fe-MOF) 14 materials. CD Biopar?cles specializes in customizing Metal-organic Frameworks (MOFs) Materials, Covalent Zinc-Based MOFs (Zn-MOF) 15 Organic Framework (COF) Materials, Hydrogen-bonded Organic Framework (HOF) Materials. Widely used in food, drug delivery, gas adsorp?on and separa?on, catalysis, sensors and other areas. Titanium-based MOFs (Ti-MOF) 17 Covalent Organic Framework (COF) Materials 18 Today we offer you: Hydrogen-bonded Organic Framework (HOF) Materials 19 We offer fully cer?fied high-quality porous organic materials. This is an excellent choice for your porous organic materials supply: ● Wide coverage of the porous organic materials ● Keep pursuing higher surface area with op?mized formula?on ● Tailored textural proper?es, uncompromising on porosity ● Feasibility studies under real condi?ons - Metal-organic Frameworks (MOFs) Materials - Indium-based MOFs (In-MOF) Metal-organic Frameworks (MOFs) Materials is a kind of porous material with periodic network skeleton Excita?on Wavelength Emission Wavelength Catalog no Product Name CAS Numbe Structure structure formed by self-assembly through coordina?on between organic ligands and metal ions. It has the advantages of high porosity, low density, large specific surface area, regular pore size, adjustable pore size CDM-CH008 2138292-58-5 298 nm 613 nm MIL-124 (In) and topological structure diversity and clipability. It is widely used in drug delivery, gas and liquid adsorp?on, gas storage, conduc?vity, catalysis and other fields. CD Biopar?cles’ customized Metal-organic Frameworks (MOFs) Materials with various of the material formats and chemical composi?on can help you to solve: The challenges you might meet: Limited MOF op?ons in the market for different applica?ons Restricted surface area Low produc?on yield and low consistency Tedious processing and formula?on Limited facili?es for large produc?on yield with consistent quality control We have: Indium-based MOFs (In-MOF) Cobalt-based MOFs (Co-MOF) Zirconium-based MOFs (Zr-MOF) Nickel-based MOFs (Ni-MOF) Copper-based MOFs (Cu–MOF) Iron-based MOFs (Fe-MOF) Aluminum-based MOFs (Al-MOF) Zinc-Based MOFs (Zn-MOF) Chromium-based MOFs (Cr-MOF) Titanium-based MOFs (Ti-MOF) Proper?es of products: Figure 1. TEM image of MIL-88B-Fe Figure 2. XRD spectrum of MIL-88B-Fe 4 www.cd-biopar?cles.net www.cd-biopar?cles.net 5 - Zirconium-based MOFs (Zr-MOF) - Zirconium-based MOFs (Zr-MOF) Catalog no Product Name CAS Number Pore Volume Pore Size Structure Catalog no Product Name CAS Number Pore Volume Pore Size Structure 0.48 nm; 0.56 nm; 0.74 nm CDM-CH026 1355974-78-5 0.45 cm³/g CDM-CH242 1260119-01-4 -- -- MOF-801 (Zr) NO2-UIO-66 ~0.139 (micropore volume)/0.508 (total pore volume) cm³/g CDM-CH033 1403461-06-2 1.5 cm³/g 3.7 nm; 1.3 nm PCN-222 (H) CDM-CH243 -- <0.7 nm UIO-66-MSA CDM-CH034 1476810-88-4 1.59 cm³/g 1.9 nm PCN-224 (H) CDM-CH244 1072413-85-4 1.8 cm³/g 1.77 nm UIO-68 (Zr) CDM-CH035 2230488-02-3 1.5 cm³/g 3.8/3.5 nm 1.5 nm PCN-128 (Zr) ~0.139 (micropore volume)/0.508 (total pore volume) cm³/g CDM-CH246 2378179-91-8 <0.7 nm MIP-202 (Zr) CDM-CH229 1431375-07-3 -- 1.5 nm MOF-867 CDM-CH263 1403461-00-6 -- -- PCN-222 (Fe) CDM-CH233 UIO-66-COOH 1334722-04-1 -- 0.8 nm; 1.1 nm CDM-CH264 1644161-46-5 2.8 cm³/g 3.8 nm PCN-777 (Zr) CDM-CH234 1260119-00-3 0.5 cm³/g 0.8 nm; 1.1 nm NH2-UiO-66 CDM-CH267 1640226-29-4 0.6 cm³/g 1.2 nm PCN-223 (H) Window size: 0.8 × 1.0 nm; pore size: 3.1 nm and 1.3 nm CDM-CH235 1072413-83-2 1 cm³/g 1 nm; 1.3 nm UiO-67 (Zr) CDM-CH285 1446138-63-1 1.369 cm³/g NU-1000 (Zr) CDM-CH236 1072413-89-8 0.5 cm³/g 0.8 nm, 1.1 nm UiO-66 (Zr) CDM-CH290 1579984-19-2 0.84 cm³/g 0.48 nm; 1.84 nm MOF-808 (Zr) CDM-CH239 1334722-07-4 0.5 cm³/g 0.8 nm, 1.1 nm UIO-66-SO3H CDM-CH240 1356031-63-4 -- -- UIO-66-(OH)2 2COOH-UIO- 66 (Zr) CDM-CH241 1458048-15-1 -- 0.8 nm, 1.1 nm 6 www.cd-biopar?cles.net www.cd-biopar?cles.net 7 - Copper-based MOFs (Cu-MOF) - Aluminum-based MOFs (Al-MOF) Excita?on Wavelength Emission Wavelength Catalog no Product Name CAS Numbe Structure Catalog no Product Name CAS Number Pore Volume Pore Size Structure CDM-CH232 CAU-10 (Al) 1416330-84-1 0.23 cm³/g 0.4 nm; 0.7 nm CDM-CH028 288297-89-2 0.43 cm³/g 1.1 nm SIFSIX-1-Cu 1428136-87- 1 CDM-CH269 DUT-5 1207564-79-1 -- -- CDM-CH029 0.43 cm³/g 1.1 nm SIFSIX-2-Cu 2243781-38- 4 CDM-CH283 MIL-53 (Al) 654061-20-8 0.7 cm³/g 0.8 nm*1.3 nm CDM-CH030 0.43 cm³/g 1.1 nm Cu-THQ Al-MIL-53- NH2 CDM-CH284 1134360-62-5 0.5 cm³/g 0.8 nm; 1.3 nm 2257422-27- 6 CDM-CH036 -- -- Cu-HHTP CDM-CH287 MOF-253 1251862-76-6 0.9 cm³/g 1.0 nm*1.5 nm CDM-CH231 928170-42-7 -- -- (CuI)4 (DABCO)2 Bis (N,N'- dimethylpiperazine)tetra[copper (I) iodide] Window size: 1.2-1.6 nm; pore size: 2.9- 3.4 nm 1401708-91- 5 NH-MIL-101 (Al) CDM-CH237 -- -- CDM-CH288 1404201-64-4 ~1.0 cm³/g CDM-CH238 222404-02-6 0.33 cm³/g 0.9 nm HKUST-1 CDM-CH289 Al-Fum 1370461-06-5 0.65 cm³/g 0.57*0.6 nm 0.4*0.5 nm; 0.5*0.6 nm CDM-CH268 220578-75-6 -- 0.6 nm*0.8 nm CPL-1 CDM-CH031 467-MOF (Al) 1818266-93-1 0.46 cm³/g Window size: 2.6-3.0 nm; pore size: 1.1 nm 3.4 nm 5.5 nm CDM-CH270 701198-24-5 -- 0.6 nm*0.8 nm CPL-5 CDM-CH032 PCN-333 (Al) 1843260-12-7 3.8 cm³/g CDM-CH278 916314-54-0 -- -- DUT-8 (Cu) CDM-CH279 726124-20-5 -- 0.6 nm*0.8 nm CPL-2 1,3,5-Benzenetricarboxylic acid, copper (2+) salt (2: 3) CDM-CH291 309721-49-1 -- -- 8 www.cd-biopar?cles.net www.cd-biopar?cles.net 9 - Chromium-based MOFs (Cr-MOF) - Cobalt-based MOFs (Co-MOF) Excita?on Wavelength Emission Wavelength Catalog no Product Name CAS Numbe Structure Catalog no Product Name CAS Number Structure Window size: 1.2- 1.6 nm; pore size: 2.9-3.4 nm 2.0-2.4 cm³/g CDM-CH247 ZIF-9 (Co) 15933-15-0 CDM-CH230 869288-09-5 MIL-101 (Cr) 1186035-28- 8 CDM-CH248 Co/DOBDC 871658-67-2 CDM-CH245 0.52 cm³/g 0.45 nm; 1.0 nm CAU-1-NH2 (Al) Window size: 0.55-0.88 nm; pore size: 2.5-2.9 nm CDM-CH251 ZIF-67 46201-07-4 CDM-CH256 840523-88-8 0.9 cm³/g MIL-100 (Cr) Window size: 1.2- 1.6 nm; pore size: 2.9-3.4 nm CDM-CH254 DUT-8 (Co) 1376245-95-2 1041469-06- 0 CDM-CH257 ~2.0 cm³/g ED-MIL-101 (Cr) CDM-CH255 [Co (5-NH2-bdc) (bpy) 1177410-74-0 A?er ac?vated 8.6 × 8.6 Å or 9.4 × 11.4 Å CDM-CH258 442912-79-0 -- MIL-53 (Cr) 1425509-24- 5 CDM-CH259 -- 1.5 nm NO2-MIL-101 (Cr) Window size: 1.2- 1.6 nm; pore size: 2.9-3.4 nm 1331961-41- 1 CDM-CH260 ~2.0 cm³/g MIL-101 (Cr)-SO3H Window size: 1.2- 1.6 nm; pore size: 2.9-3.4 nm 1414869-95- 6 CDM-CH261 ~2.0 cm³/g NH2-MIL-101 (Cr) Window size: 1.2- 1.6 nm; pore size: 2.9-3.4 nm 2.0-2.4 cm³/g CDM-CH262 876661-00-6 MIL-101 (Cr) F Free 10 www.cd-biopar?cles.net www.cd-biopar?cles.net 11 - Nickel-based MOFs (Ni-MOF) - Iron-based MOFs (Fe-MOF) Excita?on Wavelength Emission Wavelength Catalog no Product Name CAS Numbe Structure Catalog no Product Name CAS Numbe Structure CDM-CH249 1973399-07-3 KAUST-7 CDM-CH252 PCN-250 (Fe2Co) 2393906-70-0 0.5 cm³/g 1 nm CDM-CH250 882977-00-6 Ni-DOBDC CDM-CH265 PCN-250 (Fe) 1771755-22-6 0.5 cm³/g 1 nm CDM-CH253 1254181-27-5 DUT-8 (Ni) CDM-CH266 PCN-600 (Fe) 1630794-12-5 1.8 cm³/g 3.1 nm Window size: 0.55-0.88 nm; pore size: 2.5-2.9 nm CDM-CH707 F-free MIL-100 (Fe) 1257379-83-1 0.9 cm³/g Window size: 1.2 nm; pore size: 2.3-2.7 nm CDM-CH708 MIL-101 (Fe) 1189182-67-9 1.8 cm³/g Window size: 0.55-0.88 nm; pore size: 2.5-2.9 nm CDM-CH709 MIL-100 (Fe) 1195763-37-1 0.9 cm³/g CDM-CH710 MIL-88B-Fe 1341134-01-7 -- -- Window size: 1.0 nm; pore size: 2.3-2.7 nm CDM-CH711 NH2-MIL-101 (Fe) 1189182-85-1 1.8 cm³/g CDM-CH712 MIL-53 (Fe) 764608-47-1 -- -- CDM-CH713 NH2-MIL-88B (Fe) 1341134-09-5 -- -- CDM-CH714 NH2-MIL-53 (Fe) 1291088-77-1 -- -- 12 www.cd-biopar?cles.net www.cd-biopar?cles.net 13 - Iron-based MOFs (Fe-MOF) - Zinc-Based MOFs (Zn-MOF) Excita?on Wavelength Emission Wavelength Excita?on Wavelength Emission Wavelength Catalog no Product Name CAS Numbe Structure Catalog no Product Name CAS Numbe Structure 1251849-13- 4 CDM-CH271 255367-66-9 -- 1.5 nm CDM-CH715 -- -- MOF-5 MIL-68 (F) 1138446-56- 6 CDM-CH272 473981-31-6 -- 1.5 nm CDM-CH716 -- -- IRMOF-3 MIL-88A (Fe) CDM-CH273 847643-64-5 -- 1.5 nm MOF-74 (Mg) CDM-CH274 676593-65-0 1.6 cm³/g 1.1 nm MOF-177 CDM-CH275 473981-45-2 -- 1.5 nm IRMOF-9 CDM-CH276 473981-43-0 -- -- IRMOF-8 CDM-CH277 2095465-85-1 -- 1.5 nm CAU-21-ODB CDM-CH282 1200358-58-2 -- 1.5 nm MIL-100 (Al) CDM-CH286 908831-43-6 -- 1.5 nm MIL-96 (Al) CDM-CH292 1018477-09-2 -- 1.5 nm ZIF-68 Window size: 0.35 nm; pore size: 1.1 nm CDM-CH293 1062147-37-8 0.4 cm³/g ZIF-90 14 www.cd-biopar?cles.net www.cd-biopar?cles.net 15 - Zinc-Based MOFs (Zn-MOF) - Titanium-based MOFs (Ti-MOF) Excita?on Wavelength Emission Wavelength Excita?on Wavelength Emission Wavelength Catalog no Product Name CAS Numbe Structure Catalog no Product Name CAS Numbe Structure CDM-CH280 MIL-125 (Ti) 1193372-03-0 -- 0.6 nm * 0.8 nm CDM-CH294 ZIF-8 59061-53-9 0.66 cm³/g 0.34 nm; 1.1 nm CDM-CH281 NH2-MIL-125 (Ti) 1309760-94-8 -- 0.6 nm * 0.8 nm 0.43 nm (Aperture: 0.24 nm) CDM-CH295 ZIF-7 909531-29-9 0.18 cm³/g CDM-CH296 Zn-ZIF-62 1446434-44-1 -- -- CDM-CH297 ZIF-14 945215-37-2 -- -- CDM-CH298 ZIF-11 24304-54-9 -- -- CDM-CH299 ZIF-64 17339-44-5 -- 1.5 nm CDM-CH300 ZIF-70 1207355-49-4 -- -- CDM-CH301 ZIF-69 1018477-10-5 -- -- 16 www.cd-biopar?cles.net www.cd-biopar?cles.net 17 - Covalent Organic Framework (COF) Materials - Covalent Organic Framework (COF) Materials Covalent Organic Framework (COF) Materials is a crystalline material with ordered porous structure formed Excita?on Wavelength Emission Wavelength Catalog no Product Name CAS Numbe Structure by reversible polymeriza?on of light elements C, O, N, B and so on, which is constructed by covalent CDM-CH001 COF-42 1314877-67-2 0.31 cm³/g 2.8 nm bonding. Due to the rich designability of organic monomers, the orderness and regularity of crystal materials and the diversity of covalent bond forms, Covalent Organic Framework (COF) Materials have incomparable CDM-CH002 COF-LZU-1 1242082-12-7 -- 1.2-1.8 nm advantages of other tradi?onal porous materials, such as low density, high specific surface area, easy modifica?on and func?onaliza?on, etc. Therefore, Covalent Organic Framework (COF) Materials have been extensively studied in the fields of gas storage and separa?on, heterogeneous catalysis, energy storage CDM-CH027 HCOF-1 1639211-37-2 1.1-1.2 cm³/g 1.18 nm materials, optoelectronics, sensing and drug delivery and have shown excellent applica?on prospects. CDM-CH037 CTF-1 2155822-92-5 0.4 cm³/g 1.2 nm CD Biopar?cles' customized Covalent Organic Framework (COF) Materials with various of the material formats and chemical composi?on. CDM-CH038 PyCOF 2185790-08-1 -- 1.38 nm * 1.59 nm CDM-CH039 TpPa-1 1414350-37-0 0.087 cm³/g 1.8 nm CDM-CH041 IISERP-COF4 1788078-55-6 -- -- 18 www.cd-biopar?cles.net www.cd-biopar?cles.net 19 - Hydrogen-bonded Organic Framework (HOF) Materials - Hydrogen-bonded Organic Framework (HOF) Materials Hydrogen-bonded Organic Framework (HOF) Materials is a class of ordered frame materials constructed Catalog no Product Name Pore Volume Pore Size Structure only by self-assembly of organic building units through intermolecular hydrogen bonds. As a highly ordered 3.0 nm, 2.5 nm; 3.65- 3.71 nm new porous crystalline material, Hydrogen-bonded Organic Framework (HOF) Materials have the unique CDM-CH003 HOF-102 1.35 cm³/g advantages of mild synthesis condi?ons, solvent processability and easy regenera?on. At the same ?me, Hydrogen-bonded Organic Framework (HOF) Materials have the characteris?cs of high specific surface 2.4 nm, 1.8 nm; 3.4-3.6 nm CDM-CH040 PFC-1 1.36 cm³/g area, adjustable aperture and low density. At present, Hydrogen-bonded Organic Framework (HOF) Materials have become one of the new research hotspots in the field of chemistry and materials science, CDM-CH042 HOF-100 -- -- showing good applica?on prospects in gas adsorp?on and separa?on, molecular devices, fluorescent probes, proton conduc?on, drug molecular transfer and other aspects. CD Biopar?cles' customized Hydrogen-bonded Organic Framework (HOF) Materials with various of the material formats and chemical composi?on. 20 www.cd-biopar?cles.net www.cd-biopar?cles.net 21 - Covalent Organic Framework (COFs) Linkers - Metal-organic Frameworks (MOFs) Linkers 2d-Aldehyde COFs Linkers 2d-Carboxylic MOFs Linkers 2d-Alkyne Orgnic COFs Linkers 2d-Hybrid MOFs Linkers 2d-Amine COFs Linkers 2d-Nitrogen MOFs Linkers 2d-Phosphoric Acids COFs Linkers 3d-Carboxylic MOFs Linkers 3d-Aldehyde COFs Linkers 3d-Hybrid MOFs Linkers 3d-Alkyne Orgnic COFs Linkers 3d-Nitrogen MOFs Linkers 3d-Phosphoric Acids COFs Linkers 4d-Carboxylic MOFs Linkers Hybrid COFs Linkers A2B2-Porphyrins Mul?-Aldehyde COFs Linkers A3B1-Porphyrins Mul?-Alkyne Orgnic COFs Linkers A4-Porphyrins Mul?-Amine COFs Linkers Bipyridine Blocks Mul?-Phosphoric Acids COFs Linkers Halide Subs?tuted Aroma?cs Customizable COFs Linkers Isophthalate Other COFs Linkers Metalloporphyrins Mul?-Carboxylic MOFs Linkers Mul?-Hybrid MOFs Linkers Mul?-Nitrogen MOFs Linkers Tetraphenylethylene Triphenylbenzene Customizable MOFs Linkers Other MOFs Linkers Other Organic-Linker Blocks We also provide organic linkers to build MOFs and COFs materials. For more informa?on, please contact us. 22 www.cd-biopar?cles.net www.cd-biopar?cles.net 23 Contact Us Phone:1-631-624-4882 Fax:1-631-938-8221 E-mail: info@cd-biopar?cles.com 45-1 Ramsey Road, Shirley, NY 11967, USA www.cd-biopar?cles.net