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Atomic Structure. Modern Atomic Theory. Atom – smallest particle of an element that retains the properties of the element Subatomic Particles Protons Neutrons Electrons. Protons. Positive Charge (+1) Located in the nucleus Mass = 1 amu (atomic mass unit) 1 amu = 1.66 x 10 -24 grams
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Modern Atomic Theory • Atom – smallest particle of an element that retains the properties of the element • Subatomic Particles • Protons • Neutrons • Electrons
Protons • Positive Charge (+1) • Located in the nucleus • Mass = 1 amu (atomic mass unit) • 1 amu = 1.66 x 10-24 grams • Symbol: p+ or H+
Neutrons • Neutral Charge • Located inside the nucleus • Mass = approximately 1 amu • Symbol: n
Electrons • Negative Charge (-1) • Located outside the nucleus • Mass = 1/1836 of a proton (basically mass less) • Symbol: e- or e-1
Nucleons • Particles located inside the nucleus • Protons and Neutrons • All mass is located in the center of the atom (inside the nucleus), nucleus is very dense
Atomic Number • The number of protons in an atom • Bold number on the periodic table • For a neutral atom: • Number of protons = number of electrons Why???
Atomic Mass/Mass Number • The mass of an atom (expressed in amu) • Equal to the number of protons + the number of neutrons in an atom Why aren’t electrons included in the mass?
Nuclear Symbol • The nuclear symbol consists of three parts • the symbol of the element • the atomic number of the element • the mass number of the specific isotope
Examples Indicate how many protons, neutrons and electrons are in each of the following atoms. • Aluminum-27 • Xe-131 • 56Fe
Gram Atomic Mass • The mass of 1 mole of the element • 1 mole = 6.02 x 1023 particles • Expressed in grams instead of amu
Mass Examples • 1 atom of K = • 1 mole of K = • 1 CO2 molecule = • 1 mole of CO2 =
Isotopes • Same element, same atomic number, number of protons are the same • Different masses, because the number of neutrons varies Example: indicate the number of protons, neutrons, and electrons in carbon-12 and carbon-14
Weighted Average Atomic Mass • Mass found on the periodic table is the weighted average of the naturally occurring isotopes • Accounts for the percent abundance and mass of each of the elements isotopes
How to Calculate • Each exact atomic mass is multiplied by its percent abundance (expressed as a decimal). Then, add the results together and round off to an appropriate number of significant figures. Example: Nitrogen
Examples • Calculate the weighted average atomic mass for Magnesium.
Ions • Occur when a neutral atom gains or loses a electrons • Caused by the transfer of electrons • Results in a charged atom • Protons are never lost or gained
Cation • Positive Ion • Results from the loss of an electron • Elements on the left side of the table (metals) tend to lose electrons to form cations
Anion • Negative ion • Results from the gain of an electron • Elements on the right side of the table (nonmetals) tend to gain electrons to form anions
Ion Examples Indicate the number of protons, neutrons and electrons in each: • 35Cl atom: • 35Cl- ion: • 39K atom: • 39K+ ion: • 40Ca atom: • 40Ca2+ ion: