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Tannins

Tannins. They are high molecular weight phenolic compounds capable of precipitation of animal proteins in hides and converting them into leather. “Tanning Industry” They are widely distributed in plants. They are condensation products of Gallic acid or Flavan-3-ol. Classification of Tannins:.

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Tannins

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  1. Tannins They are high molecular weight phenolic compounds capable of precipitation of animal proteins in hides and converting them into leather. “Tanning Industry” They are widely distributed in plants. They are condensation products of Gallic acid or Flavan-3-ol.

  2. Classification of Tannins: Not hydrolysable, no sugar in mol.

  3. 1) Pyrogallol Tannins • Composed of central sugars with all its OH esterified with Phenolic acids (gallic or ellagic acid). • They can be hydrolyzed by acids or enzymes. • They produce sugars and: • Gallic acid……Gallitannins. (Clove, Hammamelis) • Ellagic acid…….Ellagitannins. (Geranium) • - Produce pyrogallol on dry distillation.

  4. 2) Catechol (Condensed) Tannins - Condensation product of Flavan-3,4-diol. They resist hydrolysis. - Upon prolonged heating they decompose into Phlobaphene (reddish color). - Produce catechol on dry distillation. - Present in Cinchona, Cinnamon, Green tea.

  5. Properties of Tannins: -Soluble in water, polar organic solvents and Alkali solutions. -React with FeCl3 (bluish or greenish color) as they are Phenolic. -Precipitate proteins and Gelatin. -Form complex with alkaloids, heavy metals.

  6. Chemical test for Identification: FeCl3: Hydrolysable tannins Bluish colour. Condensed tannins Greenish colour. Goldbeater’s Skin test (Ox-Intestine): Soak piece of Goldbeater’s skin in 2% HCl, wash with water, soak in test solution, wash with water, finally soak with FeSO4Brown or Black colour. Gelatin test: Tannins + 1% Gelatin solution in NaCl white precipitate

  7. Uses of Tannins: 1) Antioxidant. 2) Antidiarrheal. 3) Antidote for heavy metals poisoning. 4)Treatment of burns, ulcers, inflammations 4) Astringent to stop bleeding (hemorrhage) 5)Treatment of Hemorrhoids. 6) Tanning industry.

  8. Green and Black Tea Green Tea: -Prepared by rapid drying at elevated temperature to deactivate the enzymes. -Contain Catechins with high antioxidant properties. Black Tea: -Undergo slow drying (Fermentation). -Enzyme action results in Hydrolysis and Oxidation (theaflavin). -Antioxidant properties is greatly decreased. (+) catechin theaflavin

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