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Predicting Products. Single Displacement. Use activity series of metals If metal C is more active than A, then it replaces less active metal A. AB + C CB + A If metal F is less reactive than metal D, it cannot bump off D & reaction does not occur DE + F no reaction.
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Single Displacement Use activity series of metals • If metal C is more active than A, then it replaces less active metal A. AB + C CB + A • If metal F is less reactive than metal D, it cannot bump off D & reaction does not occur DE + F no reaction
Activity Series p 148 • General Trends of metal activity (how well they can displace): • Lighter metals bump off heavier metals • Metals with +1 charges will bump metals with +2 charges • How to read table 4-12: the higher up a metal, the more active it is. • Not perfect trends: • Ca2+ displaces Na+
Double Displacement or Metathesis • Use solubility tables p134 – 135 • For rxn to occur, precipitate (ppt) must form
3 ways to write reactions (when they’re in aqueous solutions): (p136) • Formula unit equations 2 AgNO3 (aq) + Cu (s) 2 Ag (s) + Cu(NO3) (aq) • Total Ionic equations 2 [Ag+(aq) + NO3- (aq)] + Cu(s) 2 Ag (s) + [Cu+(aq) + 2NO3- (aq) • Net Ionic equations 2 Ag+ (aq) + Cu (s) 2 Ag (s) + Cu2+ (aq)
NaCl(aq) + KBr(aq) -----> NaBr(aq) + KCl(aq) How is this reaction written? Rewrite as total ionic. Can you rewrite as net ionic? No! Only spectator ions!
Na+ (aq) + Cl- (aq) + K+ (aq) + Br- (aq) -----> Na+ (aq) Br- (aq) + K+ (aq) + Cl- (aq)
DD or Metathesis • Acid-base: • When an acid is combined with a base, the products will be salt & water
Ba(OH)2(aq) + CaCl2(aq)ZnCl2(aq) + K2CrO4(aq)KCl(aq) + Na2SO4(aq)
Combustion • Carbon compound + oxygen yields Carbon dioxide & water
Predict Products & Balance Rxn • CaCl2 + F2 • CaCl2 + Na • CaCl2 + KNO3 • CaCl2 + K2SO4
Predict & Balance • AlBr3 + F2 • AlBr3 + Zn • AlBr3 + Na • AlBr3 + Ba(NO3)2 • AlBr3 + K2SO4
Calculate the mass of solid product formed when 4.16 g of barium chloride is added to 250 ml of 0.40 M potassium sulfate: