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ELEMENTS: CHEMICAL & PHYSICAL PROPERTIES. Remember, what one doesn’t know can hurt. GROUP 1 Alkali Metals. Are not found as elements in nature Stored under kerosene or other hydrocarbon solvent (oil) Can react with water vapor or oxygen in the air
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GROUP 1Alkali Metals • Are not found as elements in nature • Stored under kerosene or other hydrocarbon solvent (oil) • Can react with water vapor or oxygen in the air • Good conductors of electricity and heat • Ductile, malleable, and soft • Silvery luster • Low density • Low melting point • Form: colorless ions with a 1+ charge ionic compounds water-soluble bases Potassium reaction with water Sodium reaction with air
GROUP 2Alkaline Earth Metals • Are not found as elements in nature • Occur most commonly as carbonates, phosphates, silicates, and sulfates • Good conductors of electricity and heat • Ductile and malleable • Silvery luster • Includes naturally radioactive element radium • Form: less reactive than alkali metals rxn with HOH to form bases & hydrogen gas compounds are insoluble or only slightly soluble in water forms primarily ionic compounds ions with a 2+ charge Beryl A source of beryllium
GROUPS 3 – 12Transition Metals • Usually harder, more brittle than Groups 1 & 2 metals • Higher melting & boiling points than Groups 1 & 2 metals • Good conductors of electricity and heat • Malleable and ductile • Silvery luster, except copper & gold • Chemical properties differ from each other • Include radioactive elements 89-112 • Compounds often colored • May form complex ions • 1 or 2 valence electrons • Usually have ≥ 2 common oxidation states • Includes mercury, only metal that is liquid at room temperature Transition metals
GROUP 13 Boron Family • are not found as elements in nature • scarce in nature • metallic solids • soft, low melting points • chemically reactive at moderate temperatures • 3 valence electrons • Exceptions: aluminum:most abundant metallic element which exists as ore bauxite, is self-protecting boron:metalloid, covalent solid, hard, high melting point, not chemically reactive at moderate temperatures
GROUP 14 Carbon Family • nonmetal:carbon metalloids:silicon, germanium metals:tin, lead • large variation in physical & chemical properties • occurs in elemental & combined forms • relatively unreactive • 4 valence electrons • tend to form covalent compounds althoughtinand leadwill form ionic compounds • Tin and lead are self-protecting metals
GROUP 15 Nitrogen Family • nonmetals:nitrogen, phosphorus metalloids:arsenic, antimony metal:bismuth • Most common forms: nitrogen: atmospheric N2 phosphorus:phosphate rock arsenic, antimony, bismuth: sulfides or oxides antimony, bismuth: elements • abundant :nitrogen, phosphorus rare: arsenic, antimony, bismuth • formcovalent compounds, oxidation numbers usually +3 or +5 • atoms have 5 electrons in their outermost energy level • Exist in ≥2 allotropic forms exceptnitrogen & bismuth • Solids at room temperature, except nitrogen
GROUP 16 Oxygen Family • nonmetal: oxygen, sulfur, selenium metalloid: tellurium metal: polonium • occur as elements & in combined states • form covalent compounds, oxidation numbers usually -2 • atoms have 6 electrons in outermost energy shell • often exist as diatomic & polyatomic molecules (i.e. O2, S6) • exist in several allotropic forms (i.e. sulfurcan exist as orthorhombic or monocliniccrystal structure)
GROUP 17 Halogens • all nonmetals • occur in combined form, usually as metal halides • found in rocks of Earth’s crust & dissolved in sea water • At room temperature --- gas: F2 Cl2 liquid: Br2 solid: I2 • all reactive, esp. fluorine • Atoms have 7 electrons in outermost energy level • Usually gain an electron to form a halide, X- ion, but can share electrons & have positive oxidation states
GROUP 18 Noble Gases • inert • essentially demonstrate ideal gas behavior over a wide range of temperatures & pressures • group has highest ionization energy, therefore strongly resist losing electrons • complete octet of electrons in highest energy level • gases at room temperature • 1st noble gas compound prepared in 1962, XeF4 • Neon, Argon, Krypton Xenon used in lighting • Helium used in balloons since less dense than air