770 likes | 976 Views
Energy Resources. Geothermal Energy: A Free Lunch?. Environmental Problems of Geothermal Energy It is Finite Heat Sources Can Be Exhausted (Geysers, California) Sulfur Emissions Disposal of Mineralized Brines . Technical Problems of Geothermal Energy Corrosion Mineral Deposition in Pipes
E N D
Geothermal Energy: A Free Lunch? Environmental Problems of Geothermal Energy • It is Finite • Heat Sources Can Be Exhausted (Geysers, California) • Sulfur Emissions • Disposal of Mineralized Brines Technical Problems of Geothermal Energy • Corrosion • Mineral Deposition in Pipes • Non-Productive gases (Carbon dioxide, methane, etc.) • Low Temperatures • Low Thermodynamic Efficiency
Thermodynamic Efficiency • Eff. = (Ti - Tf)/Ti • T = Degrees Kelvin = Degrees C + 273 • Ti = initial temperature • Tf = final temperature
Thermodynamic Efficiency Automobile Engine • Ti = 1200 C = 1473 K • Tf = 500 C = 773 K • Eff = (1473 - 773)/1473 = 48% Typical Steam Power Plant • Ti = 700 C = 973 K • Tf = 200 C = 473 K • Eff = (973 - 473)/973 = 51%
Thermodynamic Efficiency Geothermal Power Plant • Ti = 150 C = 423 K • Tf = 80 C = 353 • Eff = (423 - 353)/423 = 17% Actual achieved efficiencies • Automobile on Highway: about 5% • Geothermal Plant: 5% or So, Sometimes less than 1%
Nuke-u-lar Energy • U-235 fissions to lighter nuclei • Naturally 0.7% in uranium ore • Must be enriched to 3-4% for reactors • Mining is conventional metal mining • Radium (decay product) is principal problem in mine wastes
Radiation Hazards • Problem in the body is ionization and creation of free radicals • Alpha particles (He nuclei) have +2 charge • Do not penetrate skin • Worst ionization problem if ingested • Beta particles (Electrons) • Weak penetration ability • Moderate ionization problem • Gamma Rays (High Energy photons) • Great Penetrating ability • Lowest ionization ability
Plutonium • Produced in small amounts in civilian reactors • Toxicity of Plutonium is a Myth • Chemically it is comparable to U, Th • Ra and Rn are worse radiation hazards • Chemical plus Radiation hazard high • Main Problem: Long-lived waste product • Security issue: Can be Chemically Separated from Uranium
Nuclear Waste • Contain until radiation decays to negligible levels (Pu = 24,000 years) • Possible Containment Schemes • Yucca Mountain • Crystalline Rock • Salt Domes • Subduction Zones? • Space? • Breeder Reactors? • Security Concerns
Coal • Delta, continental environments • Autochthonous: Grew in Place • Allochthonous: Transported Log Mats • Carbonized Woody Material • Often fossilized trees, leaves present
Petroleum A hydrocarbon molecule What organisms make these? Answer: None
Petroleum • Lots of organisms make these, however • Fatty Acids • Probable source: Marine plankton
Hydrocarbons • Methane = Natural Gas • Propane-Butane = Bottled Gas • Iso-octane (2,2,4 Trimethylpentane) = Gasoline • Cetane (Hexadecane = C16 H34) = Diesel Fuel • Kerosene = 12-15 Carbons • Mineral oil, petroleum jelly, paraffin wax = 20-40 Carbons • Bitumen (Asphalt) ~ 50 Carbons
Abiogenic Petroleum? • 18Mg2SiO4 + 6Fe2SiO4 + 26H2O + CO2 → 12Mg3Si2O5(OH)4 + 4Fe3O4 + CH4 • Olivine + Water → Serpentine + Magnetite + Methane • nCH4 + nFe3O4 + nH2O → C2H6 + Fe2O3 + HCO3 + H+ • Methane + Magnetite → Ethane + Hematite • Minority view in Russia • Resurgence among U.S. Right Wing
Gas Hydrates • Hydrocarbons trapped in cage of water molecules • Freeze above 0 C under moderate pressure • Solid gas hydrates occur in marine sediments (“yellow ice”) • Potentially huge energy resource • Possible role in climate change?
Economics • 2000 WINNEBAGO CHIEFTAIN SERIES M-36LP-DSL • Average Retail Price: $51,600 • Suggested List: $140,851 • Source: NADAGuides.com (23 April 2010) • Ten-Year Cost: $89,251 • @$300/day = 297 days = 30 days/year
Planning for the future has long-term benefits Procrastination pays off Now