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Acid Base Theories. Important Definitions and Ideas. Arrhenius Acids and Bases. States that ALL Acids release a Hydrogen ion (H+) in water Also states that acids react with metals States that ALL BASES MUST have and release OH- ions in water (THIS IS A PROBLEM)
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Acid Base Theories Important Definitions and Ideas
Arrhenius Acids and Bases • States that ALL Acids release a Hydrogen ion (H+) in water • Also states that acids react with metals • States that ALL BASES MUST have and release OH- ions in water (THIS IS A PROBLEM) • Limits his definition of what bases are • States that if a substance does NOT have OH- to give then its not a base
What does AMPHOTERIC Mean? • Amphoteric Substances can be both an acid and a base • Depends on what the reactants are in the reaction • Water is an example of an amphoteric substance but many more exist
Acid Types • 1. Monoprotic----Acids with only one Hydrogen ion to give • Ex: HCl • 2. Diprotic—Acids that have two Hydrogen ions to lose • Must go through 2 rounds of reactions to get rid of both since acids can only lose one Hydrogen per reaction • Ex: H2SO4 • 3. Triprotic—Acids that have 3 Hydrogen ions to lose. • Must go through 3 rounds of reactions to lose all 3 • Ex: H3PO4
Acid Types Continued • The number of Hydrogen ions that can be lost has NOTHING TO DO with Strength • The strongest acids are the ones that the Hydrogen ions the fastest in water • We call this a Ka measurement • Strong Acids have high values and weak acids have low values
Bronsted-Lowry Acids and Bases • Theory that states that acids are any substance that loses at least 1 Hydrogen ion when placed in a reaction • This is the “normal” definition • States that BASES are ANY SUBSTANCE THAT TAKES or GAINS at least ONE HYDROGEN ION. • This is different and is more inclusive and a better definition of what a base is • Substances like Ammonia, and Baking Soda are bases that fit this definition
Bronsted-Lowry Vocabulary • 1. Conjugate Acid-----Substance that the base becomes on the product side of the reaction after it has gained one hydrogen ion • 2. Conjugate Base----Substance that the ACID becomes after it has lost one Hydrogen ion on the product side • If you reverse the reaction you can get back your starting acid/base combination • All Bronsted-Lowry reactions are equilibrium reactions • Shows that acid/base reactions will reach a point of constant concentration
Acid and Base Strength • 1. Strong Acids--- • Ionize completely or nearly to completion • Ionize fast when placed in water or combined with a substance • Create a solution with a high concentration of H+ ions • pH range is typically 1-3 • For every 100 Acid Molecules 95-100 have lost a hydrogen
Weak Acids • Acids that do not ionize completely • This means that some/most of the acid molecules hold onto the Hydrogen that they should be losing • 1 or 2 of every 100 molecules lose a hydrogen when placed into solution • These will be weak and will have a pH of 4---6 • Typically these are organic acids
Strong Bases • Bases that release OH- ions quickly and completely when placed into solution • Or these are bases that aggressively take a hydrogen ion from an acid or from water • pH will be 10-14
Weak Bases • Bases that do not ionize completely (hold onto the hydroxide ions) • OR these bases do not aggressively take hydrogen ions from water or other substances • Most of these bases are molecular substances like Ammonia • pH is from 7.1-10