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Light as a Wave. OBJECTIVES: Describe the relationship between the wavelength and frequency of light. Electrons and Light. After Bohr’s model, the mystery of the atom was the nature of the electron cloud.
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Light as a Wave • OBJECTIVES: • Describe the relationship between the wavelength and frequency of light.
Electrons and Light • After Bohr’s model, the mystery of the atom was the nature of the electron cloud. • The study of light – particularly the wave nature of light – played a critical role in probing the nature of the electron cloud.
Light and Energy are Linked • Energy travels through space as light waves. • These Light waves are known as Electromagnetic Radiation (EMR) • EMR – defined as a form of energy that exhibits wavelike behavior as it travels trough space.
Types of EMR • Visible Light is one type of EMR • Others include x-rays, microwaves, radiowaves, gamma rays, ultraviolet waves, infrared waves. • All electromagnetic radiation travels at this same rate. • This rate is the speed of light (c) • c = 3.0 x 108 m/sec
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Basic Properties of Waves • Wavelength (λ- lambda) – distance between two crests of a wave. Units are usually meters. • Frequency (f or (nu))- the number of wave cycles that pass a given point per unit time (usually seconds) • Units are sec-1 = Hertz
Crest Wavelength Amplitude Trough Parts of a wave Origin
Wavelength and Frequency • Are inversely related • As one goes up the other goes down. • c = or c = f c = speed of light = 3.0 x 108m/s
As frequency decreases, wavelength increases. • As frequency increases, the wavelength decreases.
Different frequencies of light are different colors of light. • There is a wide variety of frequencies • The whole range is called a spectrum
R O Y G. B I V red orange yellow green blue indigo violet EM Spectrum HIGH ENERGY LOW ENERGY
The energy (E ) of electromagnetic radiation is directly proportional to the frequency () of the radiation. Equation:E = hf E = Energy, in units of Joules (kg·m2/s2) (Joule is the metric unit of energy) h = Planck’s constant (6.626 x 10-34 J·s) f = frequency, in units of hertz (hz, sec-1)
Low ENERGY Waves = Long Wavelength = Low Frequency Wavelength Table High ENERGY Waves = Short Wavelength = High Frequency
Low Frequency High Frequency Low Energy High Energy X-Rays Radiowaves Microwaves Ultra-violet GammaRays Infrared . Long Wavelength Short Wavelength Visible Light
Behavior of Light That Supports Wave Theory • Reflection — Waves rebound from a collision with an even substance at the same angle which they approached it.
Refraction — Waves change speed when they enter a new medium (from air to water).
Refraction explains how a prism separates the colors that make up white light. Each color will refract (or bend) to different degrees based on its characteristic wavelength
Diffraction— Waves can interfere with other waves • They create diffraction patterns • Constructive interference—occurs when a crest meets a crest or a trough meets a trough
Destructive interference—occurs when a crest meets a trough For light waves, you see darkness with destructive interference.
Electrons in Atoms: Basic Concepts Topic 9 Calculating Wavelength of an EM Wave • Microwaves are used to transmit information. • What is the wavelength of a microwave having a frequency of 3.44 x 109 Hz? • Solve the equation relating the speed, frequency, and wavelength of an electromagnetic wave for wavelength (λ).
Electrons in Atoms: Basic Concepts Topic 9 Calculating Wavelength of an EM Wave • Substitute c and the microwave’s frequency, n, into the equation. Note that hertz is equivalent to 1/s or s–1.
Examples 2) What is the frequency of red light with a wavelength of 4.2 x 10-5 m? 3) What is the energy of the photon above? c = λf or f = c/λ f = 3.0 x 108m/s 4.2 x 10-5 m = 7.1 x 1012 sec-1 E = hf E = (6.626 x 10-34 J sec) (7.1 x 1012 sec-1) E = 4.73 x 10-21 Joules