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USS Nautilus is Commissioned (1954). Reading for Thursday – Chapter 8 sections 1-4 Homework 7.1 – Due Thursday 10/2/14 Chapter 7 #s 1-8 (all), 13-29 (all), 31-39 (all), 41-44 (all ) Homework 7.2 – Due Tuesday 10/7/14 Chapter 7 # s 45-56 (all), 58, 61, 62, 71, 72, 74
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USS Nautilus is Commissioned (1954) • Reading for Thursday – Chapter 8 sections 1-4 • Homework 7.1 – Due Thursday 10/2/14 • Chapter 7 #s 1-8 (all), 13-29 (all), 31-39 (all), 41-44 (all) • Homework 7.2 – Due Tuesday 10/7/14 • Chapter 7 #s 45-56 (all), 58, 61, 62, 71, 72, 74 • Quiz #3 next Tuesday
Ionic Nomenclature (the words) name to formula Step 1: write the symbol for each ion Step 2: find the least common multiple of the charges Step 3: figure out how many of each ion you need Step 4: write the formula Note: if you need more than one polyatomic ion, you MUST use parenthesis around it!!!
Ionic Nomenclature (the words) formula to name non-VOS cation VOS cation 1) Write the name of the cation 1) Write the name of the cation 1a) Figure out the roman numeral! 2) Write the name of the anion 2) Write the name of the anion 3) The End 3) The End
Ionic Nomenclature (the words) formula to name non-VOS cation VOS cation 1) Write the name of the cation 1) Write the name of the cation 1a) Figure out the roman numeral!
Bi3N5 bismuth (V) (V) nitride Total cation charges + total anion charges = 0 Bi N3- N3- N3- Bi N3- N3- Bi N3- 3 Bi + -15 = 0 Bi = 5 = oxidation state of Bi
NiTeO4 nickel (II) (II) telurate Total cation charges + total anion charges = 0 Ni TeO42- TeO42- Ni + -2 = 0 Ni = 2 = oxidation state of Ni
Co2(CO3)3 cobalt (III) (III) carbonate Total cation charges + total anion charges = 0 CO32- CO32- Co CO32- Co CO32- 2 Co + -6 = 0 Co = 3 = oxidation state of Co
Pb(CrO4)2 lead (IV) (IV) chromate Total cation charges + total anion charges = 0 CrO42- CrO42- Pb CrO42- 1 Pb + -4 = 0 Pb = 4 = oxidation state of Pb
MnO4- Total cation charges + total anion charges = 0 Total atom “A” charges + total atom “B” charges = charge O2- O2- O2- Mn O2- O2- 1 Mn + -8 = -1 Mn = 7 = oxidation state of Mn
Summary of Ionic Nomenclature Rules • Name to formula: • Write the symbol for each ion • Use the LCM of the charges to find the number of each ion needed • Write the formula • no charges should be written in the final formula • use parenthesis if and only if you need more than 1 polyatomic • Formula to name • Write the name of the cation first, then the name of the anion • if and only if cation is VOS, include roman numeral for charge
Name or give the formula for the following: 1) Na2Se 2) lithium nitride 3) SrI2 4) barium sulfide 5) KCl 6) aluminum oxide Did you get it? 1) sodium selenide 2) Li3N 3) strontium iodide 4) BaS 5) potassium chloride 6) Al2O3
More practice on naming: 1) cadmium chlorite 2) titanium (IV) phosphate 3) calcium acetate 4) copper (II) hydride 5) tin (IV) carbonate 6) Al(OH)3 7) AgF 8) Pb(SO3)2 9) Au2Se 10) Ni(BrO)2 1) Cd(ClO2)2 2) Ti3(PO4)4 3) Ca(C2H3O2)2 4) CuH2 5) Sn(CO3)2 6) aluminum hydroxide 7) silver fluoride 8) lead (IV) sulfite 9) gold (I) selenide 10) nickel (II) hypobromite
mercury (I) phosphite (Hg2)3(PO3)2 Ag2CO3 silver carbonate (NH4)3PO4 ammonium phosphate tin (IV) sulfate Sn(SO4)2 iron (II) hydroxide Fe(OH)2 Co2(SO3)3 cobalt (III) sulfite Mn(CrO4)2 manganese (IV) chromate
Na Cl
Na Cl
Na+ Cl-
And Now For Something Completely Different… Co valent Compound • Co – together, shared • valent – having valence • compound -- a pure substance composed of two or more elements whose composition is constant
carbon 6 protons
Nomenclature (the words) • Molecular Compounds • MUST contain only nonmetals • MUST be neutral (no overall charge)
Molecular Nomenclature (the words) name to formula Step 1: write the symbol for first element and the subscript number given by the prefix HUH?!?!? Step 2: write the symbol for second element and the subscript number given by the second prefix Step 3: The End
Molecular Nomenclature (the words) prefixes monorail, monologue dialogue tricycle, triangle think Tetris!!! pentagon, pentagram 1 – mono 2 – di 3 – tri 4 – tetra 5 – penta
Molecular Nomenclature (the words) prefixes hexagon heptathlon octopus, Octamom umm… looks kinda like nine? decade 6 – hexa 7 – hepta 8 – octa 9 – nona 10 – deca
Molecular Nomenclature (the words) formula to name Step 1: write the prefix and name of first element (the prefix “mono” is optional) Step 2: write the prefix and name of second element (ending of second element MUST be changed to ide) Step 3: The End
Summary of Molecular Nomenclature Rules • Name to formula: • Write the symbol for first element and the number of them • Write the symbol for second element and the number of them • has NOTHING to do with charges • Formula to name • Write the prefix and name of the first element • do NOT change name of element • Write the prefix and name of the second element • change end of second element to “ide”
Nomenclature of Covalent Compounds 1) I3Se7 2) SO4 3) NH3 4) SiO2 5) dinitrogen pentoxide 6) xenon hexafluoride 7) nitrogen trioxide 8) carbon tetrachloride
Nomenclature of Covalent Compounds 1) triiodine heptaselenide 2) sulfur tetroxide (NOT sulfate) 3) nitrogen trihydride (ammonia) 4) silicon dioxide 1) I3Se7 2) SO4 3) NH3 4) SiO2 5) dinitrogen pentoxide 6) xenon hexafluoride 7) nitrogen trioxide 8) carbon tetrachloride 5) N2O5 6) XeF6 7) NO3 8) CCl4
Nomenclature (the words) • Aqueous Acids • MUST begin with at least one hydrogen • MUST end with a subscript (aq) • MUST be neutral (no overall charge)
Acid Nomenclature (the words) formula to name Step 1: name the anion Step 2: change the name of the anion HUH?!?!?!?
Acid Nomenclature (the words) The Rules anion acid name stemide hydrostemic acid stemite stemousacid stemate stemicacid I ate something icky at the White House
Acid Nomenclature (the words) formula to name Step 1: name the anion Step 2: change the name of the anion Step 3: The End
HC2H3O2(aq) HNO2(aq) H2CrO4(aq) H2Se(aq) HCN(aq) HBrO(aq) HClO4(aq)
HC2H3O2(aq) 1) cover the H(s) and name the anion HC2H3O2(aq) HC2H3O2-1 acetate 2) change the name of the anion acetate acetic acid
HNO2(aq) 1) cover the H(s) and name the anion HNO2(aq) HNO2-1 nitrite 2) change the name of the anion nitrite nitrous acid
H2CrO4(aq) 1) cover the H(s) and name the anion H2CrO4-2 H2CrO4(aq) chromate 2) change the name of the anion chromate chromic acid
H2Se(aq) 1) cover the H(s) and name the anion H2Se(aq) H2Se-2 selenide 2) change the name of the anion selenide hydroselenic acid
HCN(aq) 1) cover the H(s) and name the anion HCN(aq) HCN-1 cyanide 2) change the name of the anion cyanide hydrocyanic acid
HBrO(aq) 1) cover the H(s) and name the anion HBrO(aq) HBrO-1 hypobromite 2) change the name of the anion hypobromite hypobromous acid
HClO4(aq) 1) cover the H(s) and name the anion HClO4(aq) HClO4-1 perchlorate 2) change the name of the anion perchlorate perchloric acid
acetic acid nitrous acid chromic acid hydroselenic acid hydrocyanic acid hypobromous acid perchloric acid HC2H3O2(aq) HNO2(aq) H2CrO4(aq) H2Se(aq) HCN(aq) HBrO(aq) HClO4(aq)
Acid Nomenclature (the words) name to formula Step 1: write the symbol for the anion Step 2: balance the charge by adding hydrogen(s) in front Step 3: add an (aq) at the end Step 4: The End charge on the anion = # of hydrogens in acid
bromous acid nitric acid periodic acid hydrosulfuric acid permanganic acid hydrofluoric acid phosphorous acid sulfuric acid hypochlorous acid