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News. http://www.boston.com/news/local/articles/2009/11/05/environmental_officials_urge_halving_of_phosphorous_levels_in_upper_middle_charles_river/ http://www.boston.com/news/science/articles/2009/11/05/yellowstone_yields_1200_species_in_1_day_study/
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News • http://www.boston.com/news/local/articles/2009/11/05/environmental_officials_urge_halving_of_phosphorous_levels_in_upper_middle_charles_river/ • http://www.boston.com/news/science/articles/2009/11/05/yellowstone_yields_1200_species_in_1_day_study/ • http://www.boston.com/bostonglobe/editorial_opinion/oped/articles/2009/11/05/with_tax_break_a_big_carbon_footprint/ • http://www.boston.com/business/articles/2009/11/05/clunkers_mileage_impact_queried/ • http://www.cnn.com/2009/TECH/science/11/02/kilimanjaro.glaciers/index.html • http://www.boston.com/lifestyle/green/articles/2009/11/02/5000_years_later_a_new_warming_warning/ • http://www.kansas.com/news/breaking/story/1033346.html
Stratospheric Ozone 2000 m—0.8 bar 5500 m—0.5 bar (18,000 feet) 200-300 nm 75% of Mass below 17 km >390 nm Image courtesy of www.aerospaceweb.org
Light Image courtesy of www.coralnet.ca
Sunlight Spectrum UVA=320-400 nm UVB=280-320 nm UVC=<280 nm
Stratospheric Vs. Tropospheric Ozone Image courtesy of www.aerospaceweb.org
Ozone Depletion • O2 + hv O + O • O + O2 O3 • O3 + hv (<290 nm) O2 + O • O3 + Cl O2 + ClO • ClO + O O2 + Cl • O3 + O 2O2 • Cl can catalyze destruction of O3 100,000 times
Overall ~5% Global Decrease in Stratospheric Ozone Predicted Figure by UMB OpenCourseWare.
Cancer Causing DNA Breakage due to UV rays Image courtesy of www.assh.org
Melanoma Image courtesy of visualsonline.cancer.gov
Carcinomas Image courtesy of www.seattlecca.org
Antarctic Ozone Hole 5% loss in O3 500% increase at 287 nm Image courtesy of NOAA Research
Polar Vortex, Spring Image courtesy of NASA Goddard Space Flight Center
Polar Stratospheric Clouds (PSC) • Antarctic Spring • Polar Vortex • Stratospheric clouds made of ice (nitric acid) • Sunlight initiate reactions • Heterogeneous chemistry (on particles)
Index Card • How can we solve this problem?
Solutions US Clean Air Act: Venting of CFC/HCFC Refrigerants Illegal July1, 1992
Regulations Source: NASA
Solved? By 2050 • Hydro Halocarbons (HFCs) • Single manufacturer (Dupont) • Scientific consensus • Simple chemistry Source: www.sabertec.org