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Acceptance Criteria for Metallic Materials in Contact with Drinking Water Thomas Rapp Section II 3.4 Distribution of Drinking Water. Outline:. Metallic Materials in Contact with DW DWD Requirements Testing Acceptance Criteria Composition List. Metallic Materials in Contact with DW.
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Acceptance Criteria for Metallic Materials in Contact with Drinking WaterThomas RappSection II 3.4Distribution of Drinking Water
Outline: • Metallic Materials in Contact with DW • DWD Requirements • Testing • Acceptance Criteria • Composition List
Metallic Materials in Contact with DW Products: made of materials
Metallic Materials in Contact with DW Pipe-Materials: Stainless Steel: Galvanised Steel: Lead: Copper/ Tinned Copper:
Metallic Materials in Contact with DW Materials for Components: • Brass (Cu-Zn-Pb alloy) • Gunmetal (Cu-Sn-Zn-Pb alloy)
Metallic Materials in Contact with DW Metal Release depends on: • Metal Composition and Surface Characteristics • Composition of the Drinking Water • Design of the Installation • Age of the Installation • Stagnation Time
DWD Requirements Parametric Values: • Pb • Cu • Ni • Sb, As, Cd • Cr, Hg, Se • Al, Fe, Mn, Na Weekly Average
DWD Requirements Weakly Average Value? • No harmonised method available • National interpretation required Germany: UBA Sampling Recommandation http://www.umweltbundesamt.de/wasser-e/themen/downloads/drinking-water/UBA-sampling-recommandation.pdf
DWD Requirements UBA Sampling Recommandation Monitoring Individual Investigation Fully Flushed Sample (1 L) (S0) Random Daytime Sample (1 L) (2h)- 4h Stagnation First Liter Stagnation Sample (S1) Second Liter Stagnation Sample (S2)
Testing Materials
Testing Metals release is caused by corrosion: • long lasting process • depends on water composition
Testing Test Method: EN 15664-1 Test Waters: prEN 15664-2
Testing Test Method: EN 15664-1 22 Flow periods per day (each 1 or 2 min) Flow rate: 5 l/min Total water flow: 145 l/d Operation time: min. 26 weeks Sampling: 8 samples after 0,5; 0,5; 1; 1; 2; 4; 8 and 16 h stagnation
Testing Hygienic Fitness Interaction with a local water General Hygienic Fitness e.g. for copper pipes
Testing Category of Materials Assessment of General Hygienic Fitness Reference Material Material 3 Test waters acc. to prEN 15664-2 Comperative test with 1 test water
Testing Test Waters for Reference Materials(prEN 15664-2): Assessment of General Hygienic Fitness
Testing Products
Testing Characteristics due to the production: • Lead film on surfaces • Nickel on inner surfaces of chromium plated products
Acceptance Criteria 4 MS proposal: Procedure for the Acceptance of Metallic Materials Used in Contact with Drinking Water (21. Nov 2008) Germany: DIN 50930-6 (in revision)
Acceptance Criteria Metallic Corrosion Products in the Test Waters:
Acceptance Criteria Examples for Reference Concentrations:
Composition List e.g. Copper-Zinc-Lead-Alloys (Brass) Reference Material Cu: 57,0-59,0%; Zn: Rest; Pb: 1,9-2,1%; ….. Alloy CW617N, CW612N Cu: 57,0-60,0%; Zn: Rest; Pb: 1,6-2,2%; ….. for products up to 10% contact surface Alloy CW614N, CW603N Cu: 57,0-62,0%; Zn: Rest; Pb: 2,5-3,5%; ….. for products up to 1% contact surface
Composition List Approval / Certification of Products: • Products must be made of materials on the CL => Only testing of composition required • Only for certain characteristics (nickel layers) further testing of metals release is required
Composition List Specific German Acceptance Criteria: • Use of copper pipes is restricted to certain DW: pH ≥ 7,4 or (7,0 ≤ pH < 7,4 and TOC ≤ 1,5 g/m³)
Thank you for your attention!Thomas RappThomas.Rapp@uba.dewww.umweltbundesamt.de