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Groundwater Pilot Treatment System Update May 2017. Agenda. Background for Pilot Treatment System Testing Pilot Treatment System Configuration Pilot Testing Results Observations / Questions Next Steps. Agenda. Background for Pilot Treatment System Testing
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Agenda • Background for Pilot Treatment System Testing • Pilot Treatment System Configuration • Pilot Testing Results • Observations / Questions • Next Steps
Agenda • Background for Pilot Treatment System Testing • Pilot Treatment System Configuration • Pilot Testing Results • Observations / Questions • Next Steps
Background • Feasibility Study Analysis • Option D4 • Extraction and ex-situ treatment of high concentration impacted groundwater with re-infiltration of treated groundwater upgradient of extraction point • Agreed Order No. 2692, Amendment No. 1 • Conduct Pilot Treatability Testing • Construct and operate pilot system under Ecology oversight
Agenda • Background for Pilot Treatment System Testing • Pilot Treatment System Configuration • Pilot Testing Results • Observations / Questions • Next Steps
Pilot System Configuration • System Components • Groundwater extraction well • Extracted groundwater holding tanks • Walnut Shell Filter • Pretreatment metering system • Treated groundwater holding tanks • Filter backwash tanks • Re-infiltration system
Agenda • Background for Pilot Treatment System Testing • Pilot Treatment System Configuration • Pilot Testing Results • Observations / Questions • Next Steps
Pilot Plant Testing • Pilot System Test Program • Initial testing protocol • Fixed flowrate • ~32 gallons /minute (2.7 gpm/ft2) • Impact of pretreatment with castor oil • Two runs – 0 ppm castor oil • Two runs – 8 ppm castor oil • Two runs – 4 ppm castor oil • Process parameter • Bed Volumes (BVs) • Sampling Frequency • Initially every 50 BVs
Pilot Plant Testing • Groundwater PCB Pilot Plant Testing • Testing with 0 ppm castor oil • Run 1 • ~85% PCB removal efficiency through 800 BVs • Linear drop off in efficiency to ~30% by 1,600 BVs • Backwash contained minimal PCB levels, less than 2% of loading • Run 2 • Initial removal efficiency ~80% through 50 BVs • Linear drop off in efficiency to ~30% by 1,600 BVs • Backwash contained slightly higher PCB levels
Pilot Plant Testing • Groundwater PCB Pilot Plant Testing • Testing with 8 ppm castor oil • Run 3 • Dosing system initially overshot set point - ~30 ppm • Initial removal efficiency ~90% through 800 BVs • Drop off in efficiency to ~80% for 800 to 1,600 BVs • Run 4 • Initial removal efficiency ~80% through 250 BVs • Rapid drop off in efficiency to ~45% through 1,600 BVs
Pilot Plant Testing • Groundwater PCB Pilot Plant Testing • Testing with 4 ppm castor oil • Run 5 • Initial removal efficiency ~70% through 200 BVs • Drop off in efficiency to ~40% for 600 to 1,600 BVs • Run 6 • Initial removal efficiency ~60% through 200 BVs • Slow drop off in efficiency to ~45% through 1,600 BVs
Agenda • Background for Pilot Treatment System Testing • Pilot Treatment System Configuration • Pilot Testing Results • Observations / Questions • Next Steps
Observations / Questions • Observations • High oil level in Run 3 may have impacted subsequent runs • Run 3 (~30 ppm) showed fairly consistent removal efficiency between 90% and 80% • Run 4 (8 ppm) started with lower initial removal efficiency, ~80%, but removal efficiency did not remain stable • Run 5 (4 ppm) started with ~70% removal efficiency but removal efficiency did not remain stable • Run 6 (4 ppm) started with ~60% removal efficiency but removal efficiency did not remain stable
Observations / Questions • Observations • Extracted groundwater concentrations are highly variable with single extraction point at about a 50 gpm extraction rate • Extraction system design likely critical for maximizing concentration in extracted groundwater
Observations / Questions • Questions • With oil being continuously added, why did removal efficiency drop off over time for Runs 4, 5, and 6? • Does the excess oil added in Run 3 and the stable removal efficiencies indicate that a significant oil dose rate is required? • At higher oil dose rates is there a risk of oil breakthrough to the treated water side?
Agenda • Background for Pilot Treatment System Testing • Pilot Treatment System Configuration • Pilot Testing Results • Observations / Questions • Next Steps
Next Steps • Groundwater PCB Pilot Plant Testing • Future testing • Castor oil additions based on Run 3 results • 15 ppm castor oil • 30 ppm castor oil • Coagulant additions • Single dose demonstration runs • System flux rate • Increase flux rate to evaluate impact on removal efficiency • Oil breakthrough of filter • Sample treated water for oil/grease
Next Steps • Groundwater PCB Pilot Plant Testing • Backwash water management • Backwash treatment is the second step of the process • Need to transfer PCB to a non-water media for disposal • Backwash water testing • Bench scale testing of algae process for incorporating PCB into biomass for disposal • Awaiting full laboratory results from samples